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Direct Analysis of Aerosol Particles by Atomic Emission and Mass Spectrometry
Kawaguchi, Hiroshi,Nomizu, Tsutomu,Tanaka, Tomokazu,Kaneco, Satoshi 한국분석과학회 1995 분석과학 Vol.8 No.4
A method for the direct determination of elemental content in each of aerosol particles by inductively coupled plasma atomic emission (ICP-AES) or mass spectrometry (ICP-MS) is described. This method is based upon the introduction of diluted aerosol into an ICP and the measurement of either the flash emission intensities of an atomic spectral line or ion intensities. A pulse-height analyzer is used for the measurement of the distribution of the elemental content. In order to calibrate the measuring system, monodisperse aerosols are used. The potentials of the method are shown by demonstrating the copper emission signals from the aerosols generated at a small electric switch, a study of the relation between the decreasing rate of particle number density and particle size, and measurements of calcium contents in the individual biological cells.
Kunihiro Funasaka,Keiko Masumoto,Daichi Asakawa,Satoshi Kaneco 한국대기환경학회 2020 Asian Journal of Atmospheric Environment (AJAE) Vol.14 No.4
Long-term observational data for the size distributions and particulate chemical components have been summarized to understand the past and current particulate conditions in Osaka City. The positive matrix factorization (PMF) method was also applied to estimate the source changes. The observational data obtained using Andersen cascade impactors reveals that for the 40 years from fiscal year (FY) 1976 to 2015, there was a 70% reduction in PMfine (less than 2.1 μm of the aerodynamic diameter) and 76% reduction in PMcoarse (over 2.1 μm). These correspond to a 71% and 74% reduction in PM2.5 (particulate matter less than 2.5 μm in diameter) and PM10-2.5, respectively. From the continuous chemical measurements made in this study, we observed a more than 50% reduction in coarse particulate elemental carbon (EC), SO42-, NH4+, Zn, Pb, and Cd, commonly in residential and roadside areas, over the last 20 years. Similarly, the level of the fine particulate EC, Ca2+, Cl-, Zn, Mg2+, Pb, and Cd was reduced by more than 50%. Notably, the results of the particulate component analysis of ECfine show a typical reduction of 73%-79% for 20 years, and this is the main component contributing to the reduction of atmospheric particulate concentration. However, there seems to have been no apparent reduction of Vfine concentrations, SO42- fine showed a relatively low reduction of 19% to 26%, and NH4+ fine levels fell by 14% to 21% in 20 years. Since fine sulfate and ammonium have similar behaviors, ammonium sulfate is considered to be a secondary particle aerosol because of long-range transportation. The PMF analysis still estimates a high contribution rate of secondary particles, which is one of the current problems. In contrast, although vanadium is a minor element, it is likely to be generated from harbor areas with ships because they are susceptible to the prevailing sea breeze in summer. Therefore, in the future, it will be necessary to scrutinize and take countermeasures not only for long-range transportation but also for domestic sources.