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      • KCI등재

        Effect of Ba and Ho co-doping on crystal structure, phase transformation, magnetic properties and dielectric properties of BiFeO3

        Jogender Singh, Ashish Agarwal,Ashish Agarwal,Sujata Sanghi,Tanvi Bhasin,Manisha Yadav,Umesh Bhakar,Ompal Singh 한국물리학회 2019 Current Applied Physics Vol.19 No.3

        Multiferroics having composition Bi0.80-xBa0.20HoxFeO3 (BBFO, BBHFO5, BBHFO10, BBHFO15 and BBHFO20 for x=0.0, 0.05, 0.10, 0.15 and 0.20 respectively) were synthesized by method of solid state reaction. The crystal structure has been studied using X-ray diffraction technique. The X-ray patterns show enormous transform in crystal structure at concentration x=0.20. The Rietveld refinement of XRD patterns indicates that at concentration x=0.0 sample have rhombohedral structure with R3c space group while for the concentration x=0.05, 0.10, 0.15 and 0.20, the mixed phase including rhombohedral R3c and triclinic P1 space groups were obtained with best fitting. This phase transformation in crystal structure is observed due to mismatching of ionic radii of doped ions and parent ions. Magnetic properties of all samples were carried out by using vibrating sample magnetometry. M-H hysteresis loops shows that with doping of Ba and Ho antiferromagnetic BiFeO3 (BFO) transforms into ferromagnetic. The dielectric and ferroelectric measurements were carried out which shows that dielectric constant, dielectric loss and ferroelectric properties are enhanced with co-doping of Ho in comparison of the pristine BFO due to structure deformation and decrease in oxygen vacancies with higher concentration of Ho. Significant improvement has been observed in dielectric constant and remnant magnetization values with increasing content of Ho and decrease in the dielectric loss.

      • SCISCIESCOPUS

        Comprehensive adsorption characteristics of a newly synthesized and sustainable anti-corrosion catalyst on mild steel surface exposed to a highly corrosive electrolytic solution

        Kumar, Raman,Kim, Hansung,Umapathi, Reddicherla,Yadav, Ompal Singh,Singh, Gurmeet Elsevier 2018 Journal of molecular liquids Vol.268 No.-

        <P><B>Abstract</B></P> <P>A new environmental-friendly imine compound viz. 4-(2-amino-3-methylphenyl)imino)methyl)benzaldehyde (AMIB) was sustainably synthesized at room temperature utilizing green solvents, reagents and assessed as an anti-corrosion catalyst for the commercially important mild steel (MS) alloy subjected to highly aggressive 0.5 M sulphuric acid (H<SUB>2</SUB>SO<SUB>4</SUB>) solution by several electrochemical methods (polarization techniques and Electrochemical impedance spectroscopy) allied with various surface characterization techniques such as attenuated total reflectance (ATR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and atomic force microscopy (AFM). Furthermore, the experimental results were theoretically supplemented by density functional theory (DFT) treatment. AMIB delivered significant corrosion protection even at very low concentrations and at various temperatures. The findings from electrochemical and surface characterization techniques were also supplemented by temperature kinetics study. The adsorption mechanism of AMIB molecules on metal substrate follow Langmuir's adsorption isotherm. The overall corrosion mitigation mechanism assessed from various techniques and methods was found to be comprehensive in nature. The present study may pave the way for combating corrosion with this cost effective and eco-friendly strategy.</P> <P><B>Highlights</B></P> <P> <UL> <LI> AMIB has been synthesized in green solvents at room temperature. </LI> <LI> Sustainable inhibition behavior has been observed for mild steel (MS) Corrosion. </LI> <LI> Significant inhibition efficiency has been achieved at a very low concentration (1 mM). </LI> <LI> Substantial corrosion mitigation performance has been observed at high temperatures. </LI> <LI> The MS surface has been protected via comprehensive adsorption. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

      • KCI등재

        Key management for blockchain technology

        Om Pal,Bashir Alam,Vinay Thakur,Surendra Singh 한국통신학회 2021 ICT Express Vol.7 No.1

        Public Key Infrastructure (PKI) is used in Blockchain Technology to authenticate the entities and to ensure the integrity of the blockchain. Proper Protection of Bitcoin wallet is required for private keys, seeds and keys stored in external hardware in Blockchain infrastructure. In this paper, overview of Blockchain, analysis of existing PKI for Blockchain and key management for Blockchain wallet are discussed. To achieve the confidentiality of sensitive records over the Blockchain network, a Group Key Management scheme for secure group communication is also proposed.

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