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Ping Yin,Rongjun Qu,Mingyu Xu,Wei Liu,Xiguang Liu,Qiang Xu 한국공업화학회 2014 Journal of Industrial and Engineering Chemistry Vol.20 No.2
The novel functional composite silica microspheres encapsulated by organophosphonated polystyrene(SG–PS–N–P) has been successfully synthesized. SG–PS–N–P was employed to adsorb Au(III) fromsimulated wastewater, and it exhibited excellent performance, and the maximum adsorption capacitywas 980.39 mg/g at 35 ℃. The adsorption process optimization was performed using response surfacemethodology (RSM), and the analysis of variance (ANOVA) of the quadratic model demonstrated that themodel was highly significant. Moreover, the regeneration capacities of SG–PS–N–P were investigated,and it has been found that the adsorption capability remains high after several cycles of adsorption–desorption.
Effect of charge type of hydrogel on its dye adsorption capacity and kinetic study
Qiuyu Liang,Mingyu Yin,Shi Feng,Xu Xiang 한국고분자학회 2024 Macromolecular Research Vol.32 No.3
Hydrogel has a wide range of applications in many fields because of its good adsorption capacity. There are many factors affecting the adsorption performance of hydrogels, among which the charge of the gel itself is crucial. This work proposes a method to detect the amount of dye adsorbed by measuring the absorbance of hydrogels. Using this method, polyacrylamide (PAM) hydrogels with different charge types were prepared, and their adsorption performance on Congo red and methylene blue dyes was investigated to elucidate the relationship between the charge carried by the hydrogel itself and the adsorption performance. Experiments show that the adsorption capacity of hydrogel for dyes is closely related to its charge, that is, the hydrogel is more likely to adsorb dye molecules with an opposite charge to the hydrogel and the adsorption behavior conforms to the Freundlich isothermal adsorption model. Taking anionic hydrogel as an example, the adsorption kinetics of methylene blue on anionic hydrogel were further studied, and the kinetic model was in accordance with the pseudo-secondary kinetic model, suggesting that a pseudo-second-order kinetic model is more suitable for the adsorption behavior of anionic hydrogels for methylene blue dye. This work helps researchers better understand the role of the charge of hydrogel in the adsorption process and helps to design more targeted hydrogels.
Biochar-supported nZVI (nZVI/BC) for contaminant removal from soil and water: A critical review
Wang, Shengsen,Zhao, Mingyue,Zhou, Min,Li, Yuncong C.,Wang, Jun,Gao, Bin,Sato, Shinjiro,Feng, Ke,Yin, Weiqin,Igalavithana, Avanthi Deshani,Oleszczuk, Patryk,Wang, Xiaozhi,Ok, Yong Sik Elsevier 2019 Journal of hazardous materials Vol.373 No.-
<P><B>Abstract</B></P> <P>The promising characteristics of nanoscale zero-valent iron (nZVI) have not been fully exploited owing to intrinsic limitations. Carbon-enriched biochar (BC) has been widely used to overcome the limitations of nZVI and improve its reaction with environmental pollutants. This work reviews the preparation of nZVI/BC nanocomposites; the effects of BC as a supporting matrix on the nZVI crystallite size, dispersion, and oxidation and electron transfer capacity; and its interaction mechanisms with contaminants. The literature review suggests that the properties and preparation conditions of BC (e.g., pore structure, functional groups, feedstock composition, and pyrogenic temperature) play important roles in the manipulation of nZVI properties. This review discusses the interactions of nZVI/BC composites with heavy metals, nitrates, and organic compounds in soil and water. Overall, BC contributes to the removal of contaminants because it can attenuate contaminants on the surface of nZVI/BC; it also enhances electron transfer from nZVI to target contaminants owing to its good electrical conductivity and improves the crystallite size and dispersion of nZVI. This review is intended to provide insights into methods of optimizing nZVI/BC synthesis and maximizing the efficiency of nZVI in environmental cleanup.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Aggregation and passivation of nZVI can be alleviated by surfactants and doping methods. </LI> <LI> BC hinders corrosion and improves the dispersion and electron transfer of nZVI. </LI> <LI> Properties of nZVI depend on those of the BC, feedstock and pyrogenic temperature. </LI> <LI> BC enhances electron transfer from nZVI to the contaminants due to the presence of quinone and graphene moieties. </LI> <LI> nZVI/BC shows strong ability to remove HMs, nitrates, and organic contaminants in soil and water. </LI> </UL> </P>
Li Cong,Cai Wentao,Liu Shuli,Zhou Chenghao,Cao Mingyue,Yin Hongwei,Sun Dong-Xiao,Zhang Shengli,Loor Juan J. 아세아·태평양축산학회 2020 Animal Bioscience Vol.33 No.11
Objective: An initial RNA-Sequencing study revealed that UDP-galactose-4-epimerase (GALE) was one of the most promising candidates for milk protein concentration in Chinese Holstein cattle. This enzyme catalyzes the interconversion of UDP-galactose and UDP-glucose, an important step in galactose catabolism. To further validate the genetic effect of GALE on milk protein traits, genetic variations were identified, and genotypes-phenotypes associations were performed. Methods: The entire coding region and the 5’-regulatory region (5’-UTR) of GALE were re-sequenced using pooled DNA of 17 unrelated sires. Association studies for five milk production traits were performed using a mixed linear animal model with a population encompassing 1,027 Chinese Holstein cows. Results: A total of three variants in GALE were identified, including two novel variants (g.2114 A>G and g.2037 G>A) in the 5’-UTR and one previously reported variant (g.3836 G>C) in an intron. All three single nucleotide polymorphisms (SNPs) were associated with milk yield (p<0.0001), fat yield (p = 0.0006 to <0.0001), protein yield (p = 0.0232 to <0.0001) and protein percentage (p<0.0001), while no significant associations were detected between the SNPs and fat percentage. A strong linkage disequilibrium (D’ = 0.96 to 1.00) was observed among all three SNPs, and a 5 Kb haplotype block involving three main haplotypes with GAG, AGC, and AGG was formed. The results of haplotype association analyses were consistent with the results of single locus association analysis (p<0.0001). The phenotypic variance ratio above 3.00% was observed for milk protein yield that was explained by SNP-g.3836G >C. Conclusion: Overall, our findings provided new insights into the polymorphic variations in bovine GALE gene and their associations with milk protein concentration. The data indicate their potential uses for marker-assisted breeding or genetic selection schemes.