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Study on the Mechanical Characteristics of Urban Sludge Solidified by Industrial Waste
Liuyan Wu,Qiang Wang,Dandan Ge,Huangrui Xu,Guojun Cai 대한토목학회 2023 KSCE Journal of Civil Engineering Vol.27 No.7
Urban sludge is an extensive volume with a prominent environmental impact. The researchexplored an application technology for converting urban sludge into a usable improved soilresource by using industrial waste, providing a new reference for the reuse of industrial waste. In this study, three industrial wastes, namely ground granulated blast slag, calcium carbideresidue, and desulfurized gypsum, were used as curing agents to solidify the urban sludge. Based on the unconfined compressive strength (UCS) test and chamber analysis, the effects ofcuring agent dosing and maintenance age of sludge-cured soil on the UCS and stress- strainwere studied. The results showed that with the increase of curing agent, the UCS of cured soilfirst increased and then decreased, and the breaking strain showed a decreasing trend. Theoptimum ratio of materials was sludge: calcium carbide residue: ground granulated blast slag:desulfurization gypsum = 100:15:15:5, record this material ratio as C15G15D5. Moreover,trials showed that C15G15D5 cured the sludge soil better than the cement alone, whichachieved the purpose of reusing the three industrial wastes and urban sludge. It was analyzedthat the hydrated calcium silicate (C-S-H), calcium aluminate (C-A-H) and ettringite (AFt) inthe hydration products were produced to make the soil skeleton stronger and enhance thestrength of the sludge-cured soil.
Zhang Liuyan,Wang Xiujin,Wu Huishu,Mai Yongjin,Liu Cansen,Jie Xiaohua 한국탄소학회 2020 Carbon Letters Vol.30 No.5
In this paper, graphene-coated Al powders prepared by in situ reduction method were directly used for cold spraying, obtain�ing a graphene-reinforced Al matrix composite coating with more compact structure and better performance. Cross-sectional analysis revealed that compared with the pure Al powders, the graphene-coated Al powders were more severely deformed, and the resulting coating was denser and its porosity was reduced by over 80%. The hardness of the graphene-coated Al coating was increased by 40%, and its brine immersion time was prolonged by nearly three times. However, the graphene increases the pitting sensitivity of the Al coating; so, the enhanced corrosion resistance of the graphene-coated Al coating is mainly attributed to the improvement of its structure densifcation.
Qiang Wang,Dandan Ge,Guojun Cai,Man Li,Liuyan Wu,Huangrui Xu 대한토목학회 2023 KSCE Journal of Civil Engineering Vol.27 No.2
The solidification/stabilization effect of heavy metal contaminated soils in frozen soil regions may be weakened. A novel binder comprising calcium carbide residue, metakaolin, and desulfurization gypsum was used to solidify and stabilize copper-contaminated soil subjected to freeze-thaw (F-T) cycles. The unconfined compressive strength (UCS), F-T cycles, scanning electron microscope (SEM), X-ray diffraction (XRD), and pH tests were conducted to investigate the characteristics of UCS, deformation, pH value, and microscopic mechanism of contaminated soils. The results demonstrated that the UCS of contaminated soils decreased with the increasing F-T cycles and Cu2+ concentration; the strength loss rate increased first and then decreased as the F-T cycles increased. The failure strain rose first and then reduced with the increase of F-T cycles, and increased with the rise of Cu2+ concentration. There was a considerable correlation between UCS, failure strain, and deformation modulus E50. The pH value decreased with the increasing F-T cycles and Cu2+ concentration. The microscopic characteristics indicated that the formation of hydrated calcium silicate and ettringite was the fundamental reason for the enhanced UCS. Besides, heavy metals could be solidified and stabilized by chemical precipitation, physical encapsulation, and ion exchange. The effect of F-T cycles could significantly damage the internal structure of contaminated soils, and the frost heaving force could loosen the soil skeleton structure, leading to the deterioration of the mechanical properties.