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Agrestini, S.,Kuo, C.-Y.,Moretti Sala, M.,Hu, Z.,Kasinathan, D.,Ko, K.-T.,Glatzel, P.,Rossi, M.,Cafun, J.-D.,Kvashnina, K. O.,Matsumoto, A.,Takayama, T.,Takagi, H.,Tjeng, L. H.,Haverkort, M. W. American Physical Society 2017 Physical review. B Vol.95 No.20
<P>We have investigated the electronic structure of Sr2IrO4 using core-to-core resonant inelastic x-ray scattering. The experimental spectra can be well reproduced using ab initio density functional theory based multiplet ligand field theory calculations, thereby validating these calculations. We found that the low-energy, effective Ir t(2g) orbitals are practically degenerate in their crystal-field energy. We uncovered that Sr2IrO4 and iridates in general are negative charge transfer systems with large covalency and a substantial oxygen ligand hole character in the Ir t(2g) Wannier orbitals. This has far reaching consequences, as not only the on-site crystal-field energies are determined by the long-range crystal structure, but, more significantly, magnetic exchange interactions will have long-range distance dependent anisotropies in the spin direction. These findings set constraints and show pathways for the design of d(5) materials that can host compasslike magnetic interactions.</P>
Rewiring of Genetic Networks in Response to DNA Damage
Bandyopadhyay, S.,Mehta, M.,Kuo, D.,Sung, M.-K.,Chuang, R.,Jaehnig, E. J.,Bodenmiller, B.,Licon, K.,Copeland, W.,Shales, M.,Fiedler, D.,Dutkowski, J.,Guenole, A.,van Attikum, H.,Shokat, K. M.,Kolodner American Association for the Advancement of Scienc 2010 Science Vol.330 No.6009
<P>Although cellular behaviors are dynamic, the networks that govern these behaviors have been mapped primarily as static snapshots. Using an approach called differential epistasis mapping, we have discovered widespread changes in genetic interaction among yeast kinases, phosphatases, and transcription factors as the cell responds to DNA damage. Differential interactions uncover many gene functions that go undetected in static conditions. They are very effective at identifying DNA repair pathways, highlighting new damage-dependent roles for the Slt2 kinase, Pph3 phosphatase, and histone variant Htz1. The data also reveal that protein complexes are generally stable in response to perturbation, but the functional relations between these complexes are substantially reorganized. Differential networks chart a new type of genetic landscape that is invaluable for mapping cellular responses to stimuli.</P>
THE MEGAMASER COSMOLOGY PROJECT. IX. BLACK HOLE MASSES FOR THREE MASER GALAXIES
Gao, F.,Braatz, J. A.,Reid, M. J.,Condon, J. J.,Greene, J. E.,Henkel, C.,Impellizzeri, C. M. V.,Lo, K. Y.,Kuo, C. Y.,Pesce, D. W.,Wagner, J.,Zhao, W. American Astronomical Society 2017 The Astrophysical journal Vol.834 No.1
<P>As part of the Megamaser Cosmology Project, we present VLBI maps of nuclear water masers toward five galaxies. The masers originate in sub-parsec circumnuclear disks. For three of the galaxies, we fit Keplerian rotation curves to estimate their supermassive black hole (SMBH) masses, and determine (2.9 +/- 0.3) x 10(6)M(Theta) for J0437+2456, (1.7 +/- 0.1) x 10(7)M(Theta) for ESO 558-G009, and (1.1 +/- 0.2) x 10(7)M(Theta) for NGC 5495. In the other two galaxies, Mrk 1029 and NGC 1320, the geometry and dynamics are more complicated and preclude robust black hole mass estimates. Including our new results, we compiled a list of 15 VLBI-confirmed disk maser galaxies with robust SMBH mass measurements. With this sample, we confirm the empirical relation of R-out proportional to 0.3M(SMBH) reported in Wardle & Yusef-Zadeh. We also find a tentative correlation between maser disk outer radii and Wide-Field Infrared Survey Explorer luminosity. We find no correlations of maser disk size with X-ray 2-10 keV luminosity or [O III] luminosity.</P>
Kuo, C.T.,Balamurugan, K.,Shiu, H.W.,Park, H.J.,Sinn, S.,Neumann, M.,Han, M.,Chang, Y.J.,Chen, C.H.,Kim, H.D.,Park, J.G.,Noh, T.W. Elsevier 2016 Current Applied Physics Vol.16 No.3
<P>We have studied the electronic structure and interfacial properties of mechanically exfoliated few-layer NiPS3 van der Waals crystals on ZnO/Nb:SrTiO3 substrates using scanning photoelectron microscopy and spectroscopy. The conducting ZnO layer enhances the visibility of few-layer NiPS3 on Nb:SrTiO3 and prevents charging effects in photoemission. We experimentally determined a type-II band alignment at the NiPS3/ZnO interface. The valence band offset (VBO) of few-layer NiPS3/ZnO is 2.8 +/- 0.09 eV, and the conduction band offset is 1.0 +/- 0.09 eV. Moreover, we found an increase of similar to 0.3 eV in VBO as decreasing NiPS3 thickness, suggesting electronic coupling or charge transfer at the NiPS3/ZnO interface. (C) 2016 Elsevier B.V. All rights reserved.</P>
Electronically highly cubic conditions for Ru in α−RuCl3
Agrestini, S.,Kuo, C.-Y.,Ko, K.-T.,Hu, Z.,Kasinathan, D.,Vasili, H. B.,Herrero-Martin, J.,Valvidares, S. M.,Pellegrin, E.,Jang, L.-Y.,Henschel, A.,Schmidt, M.,Tanaka, A.,Tjeng, L. H. American Physical Society 2017 Physical Review B Vol.96 No.16