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        Visible-light-driven photocatalyst of La–N-codoped TiO2 nano-photocatalyst: Fabrication and its enhanced photocatalytic performance and mechanism

        Junjing Li,Bo Li,Jiejing Li,Junliang Liu,Liang Wang,Hongwei Zhang,Zhaohui Zhang,Bin Zhao 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.25 No.-

        In this study, La, N codoped TiO2 (La–N–TiO2) nano-photocatalyst was fabricated through simple sol–gel method. The resulting samples were characterized through X-ray diffraction (XRD), scanning electrons microscope (SEM), transmission electrons microscope (TEM), X-ray photoelectron spectroscopy (XPS) and UV–visible light diffuse reflection spectroscopy (UV–vis DRS). Results revealed that La elements were not implanted into the structure of TiO2 but existed as the form of Ti–O–La bonds in the interstitial site, while N dopants were incorporated into the lattice of TiO2 and coexisted in the substitutional N (N– Ti–O) and interstitial N (Ti–O–N) in the La–N–TiO2 catalyst, thereby resulting in the formation of new impurity energy level between the forbidden band and greatly enhancement of light absorption ability in visible light region. The enhanced visible light driven (VLD) photocatalytic (PC) performance for the degradation of phenol aqueous solution could be attributed to the intense light absorbance in visible light region and high separation efficiency of photogenerated charge carriers.

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        Childhood Trauma and Depressive Level Among Chinese College Students in Guangzhou: The Roles of Rumination and Perceived Stress

        Junjing Wang,Qian Liang,An Yang,Yueqi Ma,Yi Zhang 대한신경정신의학회 2024 PSYCHIATRY INVESTIGATION Vol.21 No.4

        Objective Although previous studies have validated the effect of childhood trauma on depressive level, few studies have utilized the diathesis-stress theory to investigate the specific roles of perceived stress and rumination in the pathway between childhood trauma and depression in Chinese college students. This study aims to demonstrate the mediation effect of perceived stress and the moderation effect of rumination in the pathway between childhood trauma and depressive level in Chinese college students.Methods A total of 995 Chinese college students in Guangzhou were included in this study by recruitment advertisement from October to December 2021. And they were asked to finish four self-report questionnaires, including Childhood Trauma Questionnaire-Short Form, Perceived Stress Scale, the 22-item Ruminative Response Scale, and Beck Depression Scale-II. Then the data were analyzed with Mplus 8.3.Results Results revealed significant correlations among childhood trauma, perceived stress, rumination and depressive level. Further analyses revealed that perceived stress played a mediation role between childhood trauma and depressive level (estimate=0.09, standard error [SE]=0.02, t=5.93, 95% confidence interval [CI]=0.06–0.12), and rumination played a moderation role between childhood trauma and perceived stress (estimate=-0.17, SE=0.06, t=-2.86, 95% CI=-0.28– -0.05]) as well as between childhood trauma and depressive level (estimate=0.10, SE=0.04, t=2.74, 95% CI=0.03–0.16).Conclusion These results revealed the mediation effect of perceived stress and the moderation effect of rumination in the pathway between childhood trauma and depressive level in Chinese college students, which helped us to understand how the childhood trauma influenced the depressive level and gave us multi-dimensional indications for reducing the effect of childhood trauma on depressive level.

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        Novel Method for Calculating the Effective Stress Coefficient in a Tight Sandstone Reservoir

        Yinghao Shen,Guohua Luan,Haiyong Zhang,Qian Liu,Junjing Zhang,Hongkui Ge 대한토목학회 2017 KSCE JOURNAL OF CIVIL ENGINEERING Vol.21 No.6

        Determining the influence of effective stress on rock deformation is essential for geotechnical stability analysis in oil and gas production. There is no universal effective stress coefficient for all rock properties, and different values of effective stress coefficient apply for different physical quantities (Gurevich, 2004). Although the effective stress law and its application is not new, frequently overlooked or misapplied. Hence, a novel method was proposed for measuring and calculating the effective stress coefficient in this work. Firstly, pore compressibility under different confine pressure values was measured using reservoir fluid or experimental fluid. Secondly, effective stress was calculated by comparing pore compressibility under different confine pressure and then, the range of effective stress coefficients was determined eventually. Finally, the reliability of the proposed method was validated via the stresssensitive curves of tight sandstone core samples and by comparing the results with those of two other calculation methods for the effective stress coefficient. This work suggests that the stress-sensitive curves of the two core samples from the same location and with similar physical properties have given similar effective stress coefficient (η = 0.201) calculated using the proposed method, which indicates that the calculation is reasonable. The comparison of the proposed method with other methods also indicate that the proposed technique is reliable.

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