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Wang, Jun,Jiang, Dongmei,Baeg, Jin-Ook,Lee, Chul Wee 한국공업화학회 2004 Journal of Industrial and Engineering Chemistry Vol.10 No.3
We have prepared Pt-bearing modified USY-supported 12-tungstophosphoric acid catalysts from supports that were treated hydrothermally at various temperatures and time. The catalysts were characterized by XRU, 1R spectroscopy, and NH₃-TPD techniques, and measured for their hydroisomerization of n-heptane in an atmospheric fixed-bed microreactor. We found that the PW-bearing catalysts showed much higher catalytic activity than do the PW-free counterparts, and that the hydrothermal conditions for the USY support could influence the catalytic activity substantially. Hydrothermal treatment at 650℃ for 5 h was the optimum treatment condition; it leads to a high conversion of n-heptane (30.1%) with a very high selectivity for isomerization (98.2%). We discuss the catalytic activities in relation to the physical and chemical properties of the catalysts.
Chen, Lei,Yan, Huiying,Xue, Xiangxin,Jiang, Dayu,Cai, Yuxi,Liang, Dongmei,Jung, Young Mee,Han, Xiao Xia,Zhao, Bing SAGE Publications 2017 APPLIED SPECTROSCOPY Vol.71 No.7
<P>In this work, we designed a process to assemble gold nanoparticles onto a three-dimensional (3D) polymer surface, which can then be monitored using surface-enhanced Raman scattering (SERS). This work is the first demonstration of the assembly of gold nanoparticles on a filter film and in situ measurement with Raman spectroscopy. Herein, a polyhexamethylene adipamide (Nylon66) film embedded in the organic filter film was used as a template to fabricate a tunable SERS-active substrate. A 'hotspot''-rich gold-nanoparticle-decorated polymer substrate for SERS was prepared; this substrate exhibited high sensitivity in trace detection of targets. The study was conducted using 4-mercaptobenzoic acid as a probe molecule with the aim of comparing the scattering efficiency and the homogeneity of the Raman signal on selected substrates. In addition, we used the gold-decorated polymer film to detect a biotin-avidin complex. The most powerful advantage of the proposed microanalytical device is the in situ SERS application. The 3D nanoporous structures described in this work hold strong potential for use in various applications such as environmental monitoring and biomolecule detection.</P>
Single nucleotide polymorphism-based analysis of the genetic structure of Liangshan pig population
Liu, Bin,Shen, Linyuan,Guo, Zhixian,Gan, Mailing,Chen, Ying,Yang, Runling,Niu, Lili,Jiang, Dongmei,Zhong, Zhijun,Li, Xuewei,Zhang, Shunhua,Zhu, Li Asian Australasian Association of Animal Productio 2021 Animal Bioscience Vol.34 No.7
Objective: To conserve and utilize the genetic resources of a traditional Chinese indigenous pig breed, Liangshan pig, we assessed the genetic diversity, genetic structure, and genetic distance in this study. Methods: We used 50K single nucleotide polymorphism (SNP) chip for SNP detection of 139 individuals in the Liangshan Pig Conservation Farm. Results: The genetically closed conserved population consisted of five overlapping generations, and the total effective content of the population (Ne) was 15. The whole population was divided into five boar families and one non-boar family. Among them, the effective size of each generation subpopulation continuously decreased. However, the proportion of polymorphic markers (P<sub>N</sub>) first decreased and then increased. The average genetic distance of these 139 Liangshan pigs was 0.2823±0.0259, and the average genetic distance of the 14 boars was 0.2723±0.0384. Thus, it can be deduced that the genetic distance changed from generation to generation. In the conserved population, 983 runs of homozygosity (ROH) were detected, and the majority of ROH (80%) were within 100 Mb. The inbreeding coefficient calculated based on ROH showed an average value of 0.026 for the whole population. In addition, the inbreeding coefficient of each generation subpopulation initially increased and then decreased. In the pedigree of the whole conserved population, the error rate of paternal information was more than 11.35% while the maternal information was more than 2.13%. Conclusion: This molecular study of the population genetic structure of Liangshan pig showed loss of genetic diversity during the closed cross-generation reproduction process. It is necessary to improve the mating plan or introduce new outside blood to ensure long-term preservation of Liangshan pig.