漢語動詞の自他同形に関する研究 –「自動詞寄りの自他同形型」を中心に–

Inui Hiroshi 한국외국어대학교 일본연구소 2014 日本硏究 Vol.0 No.59

The purpose of this study is to find the conditions that a intransitive Chinese loanword verb “VNする(suru)” is also used as a transitive Chinese loanword verb “VNする(suru)” in place of “VNさせる(saseru)”. The condition is “when X(agent) and Y(object) become one”=“Transitivity from X to Y become weak”. In order to consider in detail, I classified the condition under following three conditions. a. When Y is a part of the body of the X b. When X moves with Y c. When X is the owner of Y (Fig.1) is a figure putted a intransitive verb “VNする(suru)” on the right side, and putted a prototypical transitive verb “VNさせる(saseru)” on the left side. In terms of “closeness of X and Y”, the closeness become weaker as move from “a” to “c”. And in terms of “transitivity from X to Y”, the transitivity become stronger as move from “a” to “c”. With the weakening of transitivity, prototypical transitive verb “VNさせる(saseru)” begins toward the side of intransitive verb “VNする(suru)”. As a result, “VNさせる(saseru)” and “VNする(suru)” will be exchangeable. (Fig.1)

Formation of a supramolecular assembly between a Na⁺-templated G-quartet and a Ni(<small>II</small>)–porphyrin complex

Inui, Yuji,Fukuzumi, Shunichi,Kojima, Takahiko The Royal Society of Chemistry 2013 Dalton transactions Vol.42 No.11

<P>Formation of a π–π stacked assembly between a Na<SUP>+</SUP>-templated G-quartet and octaethylporphyrinatonickel(<SMALL>II</SMALL>) was observed by spectroscopic methods in methanol/chloroform and the formation dynamics of the assembly was elucidated.</P> <P>Graphic Abstract</P><P>The direct interaction between a G-quartet and octaethylporphyrinatonickel(<SMALL>II</SMALL>) was observed in organic solvents by spectroscopic measurements. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c3dt33034f'> </P>

A triangular prismatic hexanuclear iridium(<small>III</small>) complex bridged by flavin analogues showing reversible redox processes

Inui, Yuji,Shiro, Motoo,Kusukawa, Takahiro,Fukuzumi, Shunichi,Kojima, Takahiko The Royal Society of Chemistry 2013 Dalton transactions Vol.42 No.8

<P>[Ir<SUB>6</SUB>(μ-alloCl<SUB>2</SUB><SUP>2−</SUP>)<SUB>3</SUB>(Cp*)<SUB>6</SUB>(OH)<SUB>3</SUB>](PF<SUB>6</SUB>)<SUB>3</SUB> (<B>1</B>) having 7,8-dichloroalloxazine dianion (alloCl<SUB>2</SUB><SUP>2−</SUP>) as bridging ligands was synthesized and characterized by X-ray crystallography, spectroscopic and electrochemical measurements. The alloxazine ligands showed unprecedented coordination modes to link the six Ir(<SMALL>III</SMALL>) centres. The complex exhibited remarkable stability and reversible six-electron redox processes at the bridging alloxazine ligands in organic solvents. The first reversible reduction process occurred on each of three alloxazine ligands in <B>1</B> to produce a three-electron-reduced species, [Ir<SUP>III</SUP><SUB>6</SUB>Cp*<SUB>6</SUB>(μ-alloCl<SUB>2</SUB>&z.rad;<SUP>3−</SUP>)<SUB>3</SUB>(OH)<SUB>3</SUB>], and was observed as an apparent one-step reduction process at −0.65 V (<I>vs</I>. Fc<SUP>0/+</SUP>). The second reversible reduction process on each of the three alloxazine ligands in <B>1</B> was recorded at almost the same potential, −0.78 V (<I>vs</I>. Fc<SUP>0/+</SUP>), to afford the six-electron-reduced form, [Ir<SUP>III</SUP><SUB>6</SUB>Cp*<SUB>6</SUB>(μ-alloCl<SUB>2</SUB><SUP>4−</SUP>)<SUB>3</SUB>(OH)<SUB>3</SUB>]<SUP>3−</SUP>. The radical anion of the alloxazine derivative was detected by EPR measurements at room temperature. After the six-electron reduction of <B>1</B> with cobaltocene, the backward oxidation processes of reduced forms with <I>p</I>-chloranil were traced by UV-Vis spectroscopy to confirm the recovery of the original spectrum of <B>1</B>.</P> <P>Graphic Abstract</P><P>An alloxazine-bridged hexanuclear Ir(<SMALL>III</SMALL>) complex was synthesized and characterized. The complex exhibited two-step reversible reduction processes in CH<SUB>3</SUB>CN solution. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c2dt32535g'> </P>

Glenoid osteotomy for atraumatic posteroinferior shoulder instability associated with glenoid dysplasia

Inui H,Nobuhara K 대한견주관절의학회 2018 대한견주관절학회 학술대회논문집 Vol.2018 No.3

Quartet formation of a guanine derivative with an isopropyl group: crystal structures of “naked” G-quartets and thermodynamics of G-quartet formation

Inui, Yuji,Shiro, Motoo,Fukuzumi, Shunichi,Kojima, Takahiko The Royal Society of Chemistry 2013 Organic & biomolecular chemistry Vol.11 No.5

<P>The formation of guanine quartets with 9-isopropylguanine (<SUP>i</SUP>PG) is discussed in organic solvents. Crystal structures of the <SUP>i</SUP>PG quartets were determined by X-ray crystallography with template cations (Na<SUP>+</SUP> and Ca<SUP>2+</SUP>) and the structure without a template cation was also obtained by virtue of the stabilization by intermolecular hydrogen bonding with water molecules of crystallization. The difference in the quartet formation of <SUP>i</SUP>PG in the presence and absence of a template cation was clearly demonstrated by <SUP>1</SUP>H NMR measurements in CDCl<SUB>3</SUB>–CH<SUB>3</SUB>OH mixed solvents. The quartet formation is mainly governed by the enthalpy gain due to the electrostatic interaction between the O6 oxygen in <SUP>i</SUP>PG and the template cations in the presence of the cations rather than the intermolecular hydrogen bonding, while desolvation of <SUP>i</SUP>PG is the dominant factor for the formation in the absence of cations. In the presence of Na<SUP>+</SUP> and Ca<SUP>2+</SUP>, Δ<I>H</I> and Δ<I>S</I> values in the formation of <SUP>i</SUP>PG-4–Na<SUP>+</SUP> and <SUP>i</SUP>PG-4–Ca<SUP>2+</SUP> complexes were determined to be Δ<I>H</I> = −8.4 kcal mol<SUP>−1</SUP> and Δ<I>S</I> = +50 cal mol<SUP>−1</SUP> K<SUP>−1</SUP> for Na<SUP>+</SUP> and Δ<I>H</I> = −12.9 kcal mol<SUP>−1</SUP> and Δ<I>S</I> = +34 cal mol<SUP>−1</SUP> K<SUP>−1</SUP> for Ca<SUP>2+</SUP> on the basis of van't Hoff plots attained from the results of temperature-dependent UV-Vis spectroscopic measurements.</P> <P>Graphic Abstract</P><P>Formation of ‘naked’ G-quartets was elucidated on the basis of crystal structures and thermodynamic analysis. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c2ob26877a'> </P>

漢語動詞における他動詞寄りの自他同形型について

Inui Hiroshi 한국외국어대학교 일본연구소 2014 日本硏究 Vol.0 No.61

The purpose of this study is to find the conditions that a transitive Chinese loanword verb “VNする(suru)”is also used as a intransitive Chinese loanword verb “VNする(suru)”in place of “VNされる(sareru)”. The condition is “when Y(object) is separated from X(agent)”=“Transitivity from X to Y become weak”. A transitive Chinese loanword verb “VNする(suru)” with characteristics of “Y is separated from X” is weaker than a prototypical transitive verb. So a passive verb “VNされる(sareru)” corresponding to the “VNする(suru)” become weak in affectedness. With the weakening of affectedness, a passive verb “VNされる(sareru)” begins toward the side of a intransitive verb “VNする(suru)”. As a result, a passive verb “VNされる(sareru)” and a intransitive verb “VNする(suru)” will be exchangeable.

Development of a New Tooth Profile Designed for High Efficiency P/M Internal Gear Pump Rotors

Inui Naoki,Ogata Daisuke,Sasaki Harumistu 한국분말야금학회 2006 한국분말야금학회 학술대회논문집 Vol.2006 No.1

We developed a new tooth profile designed for P/M internal gear pump rotors. The theoretical discharge volume of the new tooth profile internal gear rotors is more than 10% higher than that of the same size conventional rotors. Our new profile rotors can achieve a decrease in torque, and fuel-efficiency will also be improved.

Automatic detection of the optimal ejecting direction based on a discrete Gauss map

Inui, Masatomo,Kamei, Hidekazu,Umezu, Nobuyuki Society for Computational Design and Engineering 2014 Journal of computational design and engineering Vol.1 No.1

In this paper, the authors propose a system for assisting mold designers of plastic parts. With a CAD model of a part, the system automatically determines the optimal ejecting direction of the part with minimum undercuts. Since plastic parts are generally very thin, many rib features are placed on the inner side of the part to give sufficient structural strength. Our system extracts the rib features from the CAD model of the part, and determines the possible ejecting directions based on the geometric properties of the features. The system then selects the optimal direction with minimum undercuts. Possible ejecting directions are represented as discrete points on a Gauss map. Our new point distribution method for the Gauss map is based on the concept of the architectural geodesic dome. A hierarchical structure is also introduced in the point distribution, with a higher level "rough" Gauss map with rather sparse point distribution and another lower level "fine" Gauss map with much denser point distribution. A system is implemented and computational experiments are performed. Our system requires less than 10 seconds to determine the optimal ejecting direction of a CAD model with more than 1 million polygons.

Visualizing sphere-contacting areas on automobile parts for ECE inspection

Inui, Masatomo,Umezun, Nobuyuki,Kitamura, Yuuki Society for Computational Design and Engineering 2015 Journal of computational design and engineering Vol.2 No.1

To satisfy safety regulations of Economic Commission for Europe (ECE), the surface regions of automobile parts must have a sufficient degree of roundness if there is any chance that they could contact a sphere of 50.0 mm radius (exterior parts) or 82.5 mm radius (interior parts). In this paper, a new offset-based method is developed to automatically detect the possible sphere-contacting shape of such parts. A polyhedral model that precisely approximates the part shape is given as input, and the offset shape of the model is obtained as the Boolean union of the expanded shapes of all surface triangles. We adopt a triple-dexel representation of the 3D model to enable stable and precise Boolean union computations. To accelerate the dexel operations in these Boolean computations, a new parallel processing method with a pseudo-list structure and axis-aligned bounding box is developed. The possible sphere-contacting shape of the part surface is then extracted from the offset shape as a set of points or a set of polygons.

일본 산업보건의 최신동향

Inui, Shunen 대한산업보건협회 1996 산업보건 Vol.103 No.-