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Degradation of organic light emitting diode: Heat related issues and solutions
Tyagi, P.,Srivastava, R.,Giri, L.I.,Tuli, S.,Lee, C. Elsevier Sequoia] 2016 Synthetic metals Vol.216 No.-
Degradation of organic light emitting diodes (OLEDs) is the most serious obstacle towards their commercialization. OLED degrades due to various internal and external mechanisms. External degradation is mainly caused due to the instability of low work function cathode, pin-hole formation during fabrication which provides a path for oxygen and moisture infiltration. Operation of OLED also leads to degradation with major causes being morphological instability of organic layers, trap formation, indium or oxygen diffusion from anode, interface deterioration etc. Heat generation in the OLED also acts as a source of degradation. Most of the heat is generated instantaneously upon biasing of OLED due to resistive or Joule heating as a consequence of high resistance of organic layers and non-radiative recombination. Generated heat can be reduced by reducing the effects of the generation sources such as improving conductivity of organic layers by doping, using additional layers to improve charge injection, employing emissive layers with low recombination losses etc. However, these ways can only reduce the heat up to a certain amount. To further improve the lifetime of OLED, the generated heat can be dissipated by employing heat sinks using either thermally conducting substrate or encapsulation etc. We present a review on OLED degradation with a particular focus on heat generation, its consequences and ways of reduction.
( Anuj Tyagi ),( D C Sangwan ),( Praveen Kumar Sharma ),( R Sirohi ),( I Y Choi ),( J J Ko ) 전북대학교 농업과학기술연구소 2012 농업생명과학연구 Vol.43 No.1
An extensive in vitro study was conducted to delineate the influence of levels and source of sulfur besides rumen fungi habitat on the degradation of pearl millet stover dry matter and fibrous constituents. The results revealed that degradability of dry matter, organic matter, acid detergent fibre, neutral detergent fibre and cellulose from pearl millet stover was maximized (P<0.05), irrespective of habitat of anaerobic fungi, at 0.3% dietary sulfur level out of four graded levels (0.2, 0.3, 0.4 and 0.5%) besides control. Both organic (DL-Methionine) and inorganic (sodium sulfate) sources of sulfur were equally effective in promoting degradative activity of bovine fungi. Prolonged incubation of cattle or buffalo fungi from 12 to 96 hr accelerated (P<0.05) the fermentative activity of bovine fungi. Cattle excelled (P<0.05) buffalo for fungal degradative activity under both the supplemental form of sulfur.
Huntington’s disease: Neural dysfunction linked to inositol polyphosphate multikinase
Ahmed, Ishrat,Sbodio, Juan I.,Harraz, Maged M.,Tyagi, Richa,Grima, Jonathan C.,Albacarys, Lauren K.,Hubbi, Maimon E.,Xu, Risheng,Kim, Seyun,Paul, Bindu D.,Snyder, Solomon H. National Academy of Sciences 2015 PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF Vol.112 No.31
<P><B>Significance</B></P><P>Huntington’s disease (HD) is a progressive neurodegenerative disorder affecting the striatum. The striatal-enriched transcription factor COUP-TF-interacting protein 2 (Ctip2) is depleted in HD and has been identified as a putative transcription factor for the enzyme inositol polyphosphate multikinase (IPMK). IPMK displays soluble inositol phosphate kinase activity, lipid kinase activity, and several noncatalytic activities including its role as a transcriptional coactivator. We describe severe depletion in IPMK protein in HD patients and several animal and cell models of the disease. IPMK overexpression rescues the metabolic impairments in a cell model of HD. Furthermore, delivery of IPMK in a transgenic HD model improves pathological changes and motor performance. The Ctip2–IPMK–Akt signaling pathway provides a previously unidentified therapeutic target for HD.</P><P>Huntington’s disease (HD) is a progressive neurodegenerative disease caused by a glutamine repeat expansion in mutant huntingtin (mHtt). Despite the known genetic cause of HD, the pathophysiology of this disease remains to be elucidated. Inositol polyphosphate multikinase (IPMK) is an enzyme that displays soluble inositol phosphate kinase activity, lipid kinase activity, and various noncatalytic interactions. We report a severe loss of IPMK in the striatum of HD patients and in several cellular and animal models of the disease. This depletion reflects mHtt-induced impairment of COUP-TF-interacting protein 2 (Ctip2), a striatal-enriched transcription factor for IPMK, as well as alterations in IPMK protein stability. IPMK overexpression reverses the metabolic activity deficit in a cell model of HD. IPMK depletion appears to mediate neural dysfunction, because intrastriatal delivery of IPMK abates the progression of motor abnormalities and rescues striatal pathology in transgenic murine models of HD.</P>
Reduction of noxious Cr(VI) ion to Cr(III) ion in aqueous solutions using H2O2 and UV/H2O2 systems
M.H. Dehghani,B. Heibati,A. Asadi,I. Tyagi,S. Agarwal,V.K. Gupta 한국공업화학회 2016 Journal of Industrial and Engineering Chemistry Vol.33 No.-
Conversion of the toxic Cr(VI) to the less toxic Cr(III) in aqueous solutions by chemical andphotochemical reduction was carried out using H2O2 and UV radiation. The whole mechanism was wellelucidated and investigated using potassium dichromate (K2Cr2O7) as a standard model compound. Theeffects of potential factors affecting the reduction efficiency were well studied and optimized, theoptimized parameters such as concentration of H2O2 (from 0.5 to 1.5 M), pH (from 5 to 9), irradiationtime (0 to 140 min) and reaction time (0 to 120 min). Initial concentration of Cr(VI) in the solution wasvaried from 0.1 to 15 mg/L plays a significant role in the mechanism involves for the reduction of noxiousCr(VI) to less toxic Cr(III).
M. Rajabi,B. Mirza,K. Mahanpoor,M. Mirjalili,F. Najafi,O. Moradi,H. Sadegh,R. Shahryari-ghoshekandi,M. Asif,I. Tyagi,S. Agarwal,Vinod Kumar Gupta 한국공업화학회 2016 Journal of Industrial and Engineering Chemistry Vol.34 No.-
MWCNTs functionalized with the carboxylate group are used as efficient adsorbent for the rapid removaland fast adsorption of malachite green from the aqueous solutions. The optimized contact time and pHwere 10 min and 9, respectively. The effect of temperature revealed that the adsorption capacity ofmalachite green (MG) dye increased with increasing contact time, temperature and pH of the workingsolution. The adsorption equilibrium and kinetic data was well fitted and found to be in good agreementwith the Langmuir isotherm model and pseudo second order kinetic model respectively with highcorrelation coefficient.