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Huiyu Jiang,Yujiao Wang,Heng Quan,Wei Li 한국섬유공학회 2018 Fibers and polymers Vol.19 No.4
Waterborne polyurethane modified by acrylate/nano-ZnO (PUA/ZnO) was synthesized and used to improve the wet rubbing fastness of reactive dyed cotton fabric. The reaction conditions were optimized and the products were characterized by FT-IR, TG, DSC, SEM, and particle size distribution. The dyed cotton fabrics were finished with PUA/ZnO emulsion and the rubbing fastness, ultraviolet resistant property, and wearability of treated fabrics were measured. The wet rubbing fastness of treated fabrics was increased by about 0.5-1 rate to achieve 3-4 rate, and the ultraviolet protection factor (UPF) achieved 50+ level. The whiteness, air permeability, and elongation at break of treated fabric were not decreased significantly. SEM showed that the smooth and reticular coating on the surface of treated fabric reduced the mechanical friction force between dyed fabric and rubbing cloth, and thus improved the rubbing fastness. The decomposition temperature of finished fabric was increased by 50-80 oC.
Xingwang Jiang,Yupeng Hao,Huiyu Wang,Jieyun Tu,Guangyong Liu 한국고분자학회 2022 Macromolecular Research Vol.30 No.4
Three different rubbers, hydrogenated nitrile butadiene rubber (HNBR), ethylene vinyl acetate copolymer (EVM) and ethylene propylene diene rubber (EPDM), and two blends, HNBR/EVM and HNBR/EPDM were compounded both with and without fillers, and were vulcanized with the same peroxide curing system. Peppas- Sahlin model was used to explain the diffusion mechanism of solvents in rubber vulcanizates. Transport parameters including diffusion coefficient, sorption coefficient and permeation coefficient were calculated and correlated with Flory-Huggins interaction parameters (χ). The Peppas-Sahlin model dealing with diffusion behaviors of solvents shows high degree of fitting for both unfilled and filled rubber-solvent systems. With the addition of carbon black, the diffusion coefficient increases while the sorption and permeation coefficients decrease. The sorption coefficient increases linearly with the permeation coefficient. New Flory-Huggins interaction parameter (χN) calculated by threedimensional solubility parameters shows better predictive power in diffusion behaviors than the traditional one (χT). By mathematical fitting, a linear relationship can be obtained between the maximum swelling ratio and χN, while an exponential relationship is gained for the permeation coefficient. The discovery of this rule connects three-dimensional solubility parameters with the swelling of polymer in solvent, which provides experimental basis for the further study of the medium resistance of polymer.
Yahan Cui,Liyan Jiang,Huiyu Li,Di Meng,Yanhua Chen,Lan Ding,Yang Xu 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.96 No.-
The widespread addition of sulfa antibiotics in feeds has long been an environment safety issue. Therefore, it is quite meaningful to constantly propose better solutions for determining the sulfaantibiotics in the environment. Herein, molecularly imprinted electrospun nanofibre membrane (MIM)assisted stir bar sorptive extraction method for the determination sulfonamides (SAs) in feed wasdeveloped. In this study, molecularly imprinted polymers (MIPs) werefirstly prepared via emulsionpolymerization using sulfamonomethoxine as template. Then, the morphology-controllable MIM wasobtained with MIPs-doping electro-spinning solution using electro-spinning technique. Next, MIM arecoated on the magnetic stir bar by heat-sealing. Finally, MIM coated stir bar was used for selectiveenrichment of SAs. The obtained MIM exhibited excellent class selectivity towards SAs (the selectivityfactor β is 2.3–2.7). The MIM coated stir bar can be directly applied to extract SAs from feed samples. Under the optimum extraction conditions, the detection limit of the method could reach 1.5 3.4 ng/g. And satisfactory recoveries ranging from 80 6% to 89 7% were achieved under all three spiked levelsfor determination of four SAs infive different feed samples. The present work not only offers insights todevelop magnetic stir bar using imprinted membrane, but also provides a new method for SAs extraction.
Enhanced Strength-Ductility Synergy in Mg-0.5 wt%Ce Alloy by hot Extrusion
Hui Yu,Yu Liu,Ya Liu,Dongliang Wang,Yuling Xu,Binan Jiang,Weili Cheng,Lixin Huang,Weineng Tang,Wei Yu 대한금속·재료학회 2023 METALS AND MATERIALS International Vol.29 No.7
The microstructure and mechanical properties of micro-alloyed Mg-0.5 wt%Ce alloys are investigated systemically in this study. It shows that Mg-Ce binary system is very sensitive to extrusion temperature. On the one hand, the high tensile yield strength (TYS) of 343 MPa was obtained by extrusion at 250 °C mainly due to the combined effects of profuse nano-precipitation phase, grain refinement, texture strengthening and high-density dislocation; On the other hand, the excellent elongation of 30% was acquired by extrusion at 300 °C resulting from the elimination of dislocations as well as the modification of texture.