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        Tung Oil Anhydride Modified Hemp Fiber/Polypropylene Composites: The Improved Toughness, Thermal Stability and Rheological Property

        Hongming Wu,Dinghong Xu,Ying Zhou,Chengtao Gao,Jianbing Guo,Weidi He,Yong He,Shuhao Qin 한국섬유공학회 2020 Fibers and polymers Vol.21 No.9

        Natural fibers reinforced composites (NFCs) have renewable and low cost advantages. In this paper, the tung oilanhydride (TOA) modified polypropylene (PP)/hemp fiber composites have been prepared by a melt-blended process. Thereaction between the tung oil anhydride and the as-treated hemp fiber make the TOA molecules to accumulate on the surfaceof hemp fiber and to form a TOA layer on the surface of hemp fibers, which is confirmed by the FT-IR and SEM analyses. The TOA layer improves the compatibility between PP matrix and hemp fibers. The elongation at break (EB) and impactstrength of the PP/hemp fiber/TOA composites are twice more than the PP/hemp fiber composites. Thermal analysis showsthe Toneset and Tmax of the composites increasing that reflects the thermal stability of the composites improved. The crystallineproperty reveals that the Tc moves to high temperature with the TOA or hemp fiber added in the blends. The DMA andrheology properties analysis indicate that the TOA layer improved molecular mobility of the composites and show a shearthinning effect.

      • SCIESCOPUSKCI등재

        Ginseng-derived type I rhamnogalacturonan polysaccharide binds to galectin-8 and antagonizes its function

        Yi Zheng,Yunlong Si,Xuejiao Xu,Hongming Gu,Zhen He,Zihan Zhao,Zhangkai Feng,Jiyong Su,Kevin H. Mayo,Yifa Zhou,Guihua Tai The Korean Society of Ginseng 2024 Journal of Ginseng Research Vol.48 No.2

        Background: Panax ginseng Meyer polysaccharides exhibit various biological functions, like antagonizing galectin-3-mediated cell adhesion and migration. Galectin-8 (Gal-8), with its linker-joined N- and C-terminal carbohydrate recognition domains (CRDs), is also crucial to these biological processes, and thus plays a role in various pathological disorders. Yet the effect of ginseng-derived polysaccharides in modulating Gal-8 function has remained unclear. Methods: P. ginseng-derived pectin was chromatographically isolated and enzymatically digested to obtain a series of polysaccharides. Biolayer Interferometry (BLI) quantified their binding affinity to Gal-8, and their inhibitory effects on Gal-8 was assessed by hemagglutination, cell migration and T-cell apoptosis. Results: Our ginseng-derived pectin polysaccharides consist mostly of rhamnogalacturonan-I (RG-I) and homogalacturonan (HG). BLI shows that Gal-8 binding rests primarily in RG-I and its β-1,4-galactan side chains, with sub-micromolar K<sub>D</sub> values. Both N- and C-terminal Gal-8 CRDs bind RG-I, with binding correlated with Gal-8-mediated function. Conclusion: P. ginseng RG-I pectin β-1,4-galactan side chains are crucial to binding Gal-8 and antagonizing its function. This study enhances our understanding of galectin-sugar interactions, information that may be used in the development of pharmaceutical agents targeting Gal-8.

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        Simulation Research of Multi-morphological Microstructures Chaining Mechanism of Nano-magnetic Fluid

        Lei Yang,Yibiao Chen,Yao Yao,Shuaikang Wei,Yuhui Xie,Decai Li,Jun Yu,Hongming Zhou,Yiping Feng 한국자기학회 2024 Journal of Magnetics Vol.29 No.1

        For nano-magnetic fluid(NMF), the magnetic nano-particle(MNP) kinematic behavior in a magnetic field and the chain-like microstructure evolution are important to study the NMF properties at the microscopic level. However, the chain structure formation mechanism and the effects of multiple environmental factors on microstructural morphology remain unclear. In this paper, the interaction of a two-particle system, chain structure formation process, microstructure evolution and response time simulation of NMF is investigated by the discrete element simulation method. The results show that the magnetic dipole and repulsive forces dominate the chain structure formation and evolution under a uniform magnetic field. MNPs assemble into chain-like structures and various complex structures along the magnetic f ield direction. The volume fraction, magnetization intensity and particle size significantly affect the microstructure and the response time. The above study can obtain the specific morphology of the microstructure at different working conditions and broaden the application of NMF in practical engineering.

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