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- 저자 : Hamza Abdulghani (검색결과 2 건)
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Microwave-assisted synthesis of novel porous organic polymers for effective selective capture of CO2
Ahmed M. Alloush,Hamza Abdulghani,Hassan A. Amasha,Tawfik A. Saleh,Othman Charles S. Al Hamouz 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.113 No.-
Performing carbon dioxide (CO2) capture in an environmentally benign and cost-effective way is challengingowing to several factors including selectivity. Thus, the development of polymers that providehigh capacity and selectivity for the removal of CO2 gas is important. N-based porous polymers arepromising for CO2 capture due to their abundant porosity, variable surface characteristics, and great stability. Herein, porous organic polymers were synthesized by microwave-assisted Freidel-Crafts alkylationof 2,20-bipyridine and pyrrole with dimethoxymethane as a cross-linker. The synthesized polymers werecharacterized by Fourier transform infrared, nuclear magnetic resonance, thermogravimetric analyzers,and surface analyzers based on Brunauer–Emmett–Teller theory (BET). The porous polymers exhibitedhigh surface areas of 580 – 930 m2/g. The polymers showed high ideal adsorbed solution theory (IAST)selectivity of 53 – 63 toward CO2 over N2 at 1 bar and 298 K under flue gas composition. Whereas theselectivity toward CO2 over CH4 at 1 bar and 298 K under natural gas composition was 12 – 18. The synthesizedpolymers achieved exceptional H2O adsorption capacity at P/P0 = 0.9 and 293 K of 35 – 45 mmol/g. The results reveal the polymers provide promising candidates for the CO2 capture from various mixtures,such as flue gas and natural gas.
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Irshad, Mohammad,Mandal, Raju Kumar,Al-Drees, Abdulmajeed,Khalil, Mahmoud Salah,Abdulghani, Hamza Mohammad Asian Pacific Journal of Cancer Prevention 2015 Asian Pacific journal of cancer prevention Vol.16 No.14
Background: Earlier studies on the association between p53 codon 72 Arg>Pro polymorphism and cancer risk were inconclusive and conflicting for the Saudi population. Therefore, we performed a meta-analysis to investigate the relationship between the codon 72 Arg>Pro polymorphism and overall cancer risk in Saudi Arabia. Materials and Methods: We searched all eligible published studies and data were pooled together to perform the meta-analysis. Pooled odds ratios (ORs) and 95% confidence intervals (95% CIs) were calculated for homozygous, heterozygous, dominant and recessive genetic models. Results: A total of five eligible published studies covering 502 cancer cases and 784 healthy controls were included in the meta-analysis. No publication bias was detected in this study. The results suggested that the variant (Pro vs Arg: p=0.960; OR=1.004, 95% CI=0.852-1.183), homozygous (Pro.Pro vs Arg.Arg: p=0.970; OR=1.006, 95% CI=0.729-1.390), heterozygous (Arg.Pro vs Arg.Arg: p=0.473; OR=0.783, 95% CI=0.402-1.527) carriers were not associated with overall cancer risk. Similarly, dominant (Pro.Pro+Pro.Arg vs Arg.Arg: p=0.632; OR=0.886, 95% CI=0.540-1.454) and recessive (Pro.Pro vs Pro.Arg+Arg.Arg: p=0.269; OR=1.163, 95%CI=0.890-1.521) models also did not indicate increased risk of cancer. Conclusions: The current meta-analysis suggests that the codon 72 Arg>Pro polymorphism of the p53 gene might not contribute to cancer susceptibility in Saudi population. Future well designed large case control studies are needed to validate our findings.
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