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Preparation of Polyurethane Silicon Oxide Nanomaterials as a Binder in Leather Finishing
Hamed Elsayed,Rasha Attia,Ola Mohamed,Ahmed Haroun,Nabil El-Sayed 한국섬유공학회 2018 Fibers and polymers Vol.19 No.4
Leather finishing processes using toxic organic solvent based produce volatile organic compounds (VOC), chronic exposure to this chemicals effect on workers' health causing many diseases especially lung cancer. So, polyurethane waterbased was synthesized for application in leather finishing instead of organic solvent based because it’s economic and safety for industry and workers. Preparation of water-based polyurethane (PU) depends on the reaction of polyethylene glycol (PEG, 300) with isophorone diisocyanate (IPDI) and the reaction of IPDI-1,4-butanediol (BDO) together with dimethylolpropionic acid (DMPA), was synthesized by poly-addition polymerization reaction. PU was then modified with different amounts of silicon dioxide nanoparticles (1-5 % SiO2), used as a binder in leather finishing. Leather coated was characterized physically, chemically and thermally by FTIR, GPC, DLS, TEM, SEM and TGA. The results revel that, water vapor permeability (WVP) of leather coated with PU modified with SiO2 showed improvement due to the existence of SiO2 particles which increases the interspaces of the polyurethane coating. SEM showed that when the amount of SiO2 nanoparticles increases, there is uniform nanoparticles accumulated can be observed. EDX prove the presence of Si and O2 elements and the formation of SiO2 nanoparticles. Mechanical properties discussed that tensile strength; tear strength and elongation at break % increase with increase SiO2 concentration until 3 % SiO2 nanoparticles. TGA showed an improvement of thermal stability of coated leather modified with SiO2. Therefore, this study succeeded in preparation of safe, ecofriendly of water-based polyurethane binders which modified with SiO2 for using in leather finishing.
Arbuscular mycorrhizal symbiosis and abiotic stress in plants: A review
Arafat Abdel Hamed Abdel Latef,Abeer Hashem,Saiema Rasool,Elsayed Fathi Abd_Allah,Alqarawi A.A,Dilfuza Egamberdieva,Sumira Jan,Naser A. Anjum,Parvaiz Ahmad 한국식물학회 2016 Journal of Plant Biology Vol.59 No.5
Abiotic stresses (such as salinity, drought, cold, heat, mineral deficiency and metals/metalloids) have become major threats to the global agricultural production. These stresses in isolation and/or combination control plant growth, development and productivity by causing physiological disorders, ion toxicity, and hormonal and nutritional imbalances. Some soil microorganisms like arbuscular mycorhizal fungi (AMF) inhabit the rhizosphere and develop a symbiotic relationship with the roots of most plant species. AMF can significantly improve resistance of host plants to varied biotic and abiotic stresses. Taking into account recent literature, this paper: (a) overviews major abiotic stresses and introduces the arbuscular mycorrhizae symbiosis (b) appraises the role and underlying major mechanisms of AMF in plant tolerance to major abiotic stresses including salinity, drought, temperature regimes (cold and heat), nutrient-deficiency, and metal/metalloids; (c) discusses major molecular mechanisms potentially involved in AMF-mediated plant-abiotic stress tolerance; and finally (d) highlights major aspects for future work in the current direction.
Cortical lag screw fixation for the management of mandibular injuries
Shadia Abdel-Hameed Elsayed 대한구강악안면외과학회 2020 대한구강악안면외과학회지 Vol.46 No.6
Objectives: Here, we present cases of mandibular fracture that were managed with the cortical lag screw fixation technique (CLSFT) in order to critically evaluate technique indications and limitations of application at various fracture sites. Materials and Methods: This was a retrospective cohort study. The study sample was composed of patients suffering from mandibular fractures that were treated by the CLSFT. The outcome variables were fracture type, duration of surgery, number of screws, and pattern of application. Other study categories included patient demographics and causes of injury. Chi-square tests were used to assess descriptive and inferential statistical differences, and the P-value was set at 0.05. Results: Thirty-three patients were included in the study sample, with a mean age of 30.9±11.5 years and a male predominance of 81.8%. The technique was applied more frequently in the anterior mandibular region (51.5%) than in other sites. Double CLSFT screws were required at the symphysis and parasymphysis, while single screws were used for body and angle regions. No intraoperative and postoperative variables were significantly different except for surgical duration, which was significantly different between the sites studied (P=0.035). Conclusion: We found that CLSFT is a rapid, cost-effective technique for the fixation of mandibular fractures yielding good treatment results and very limited complications. However, this technique is sensitive and requires surgical expertise to be applied to mandibular fractures that have specialized characteristics.