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- 저자 : Falamaki, Cavus (검색결과 3 건)
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An Improved Multilayer Compacted Clay Liner by Adding Bentonite and Phosphate Compound to Sandy Soil
Amin Falamaki,Mahnaz Eskandari,Mehdi Homaee,Masoud Gerashi 대한토목학회 2018 KSCE JOURNAL OF CIVIL ENGINEERING Vol.22 No.10
Landfilling of municipal solid waste produces leachate containing heavy metals and different types of organic materials. On the other hand, it has been proven by researchers that dicalcium phosphate (DCP) is applicable for stabilizing of different heavy metals through the contaminated soil. This study aimed to investigate the effect of DCP on the permeability, cohesion and friction angle of a sand-bentonite liner. DCP was added by 0.2% of the dry weight of the base soil. Then, the permeability and shear strength were measured with water and synthetic leachate to assess the compatibility. Permeability coefficient of the sandy soil improved from about 10−4 cm/s to less than 10−7 cm/s. Results imply that DCP increases the compatibility of sand-bentonite mixture, and the leachate has less influence on this type of liner. By increasing the applied bentonite up to 6% in the base material liner, the internal friction angle reduces first and remains almost constant afterwards. For a certain vertical stress, adding 0.2% DCP to the sand-bentonite mixture increased the shear strain at the maximum shear strength and presents a positive effect. Therefore, a multilayer compacted clay liner is proposed that consists of a layer of DCP improved soil to increase the stabilization of heavy metals.
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A novel method for the synthesis of nano-magnetite particles
Syahmazgi, Maryam Ghodrati,Falamaki, Cavus,Lotfi, Abbas Sahebghadam Techno-Press 2014 Advances in nano research Vol.2 No.2
A novel and simple method for the synthesis of nano-magnetite particles is disclosed. In the novel procedure, $Fe^{2+}$ is the only source of metal cation. Carboxymethylcellulose (CMC) is used as the structure directing agent. The phase analysis of the nano-particles was performed using XRD and electron diffraction techniques. Size and morphology analysis was performed using light scattering and TEM techniques. The effect of $NH_4OH$ solution (32 wt. %) at different CMC concentrations on the size distribution of the final magnetite powders is studied. An optimal base concentration exists for each CMC concentration leading to minimal agglomeration. There exists a minimum CMC concentration (0.0016 wt. %), lower than that no magnetite forms. It is shown that using the new method, it is possible to immobilize a lipase enzyme (Candida Rugosa) with immobilization efficiency larger than 98 % with a loading more than 3 times the reported value in the literature. The latter phenomenon is explained based on the agglomerate state of the nano-particles in the liquid phase.
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Reihaneh Pashmineh Azar,Cavus Falamaki 한국공업화학회 2012 Journal of Industrial and Engineering Chemistry Vol.18 No.2
An Iranian clinoptilolite has been modified with MnO2 for the catalytic removal of Fe2+ cations from water in a batch slurry reactor. The modified zeolite was subjected to FESEM, XRD, WDX, XRF and specific surface area analysis. A correlation for the intrinsic catalytic reaction rate incorporating both Fe2+ and dissolved oxygen concentration as a function of reaction temperature has been presented. The effect of the modified zeolite aggregate particle size on the iron removal kinetics has been investigated. It was shown that for particles larger than 150 mm, diffusion through the mesopores of the zeolite aggregate is rate controlling. The effective diffusion coefficient through the particles at RT has been calculated as 2.3 106 cm2 s1. It is shown that liquid phase molecular diffusion within the mesopores is the dominating mass transfer mechanism.
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