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        Surface Kinetics of Bi4-xLaxTi3O12 Films Etched in a CF4/Ar Gas Chemistry

        Dong-Pyo Kim,김창일,Alexander.M.Efremov,Kyoung-Tae Kim 한국물리학회 2004 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.44 No.1

        The surface reactions and the etch rate of Bi4ကxLaxTi3O12(BLT) lms in a CF4/Ar plasma were investigated in an inductively coupled plasma (ICP) reactor in terms of the gas mixing ratio. The variation of relative volume densities for the F and the Ar atoms were measured with optical emission spectroscopy (OES). The maximum etch rate of 803 A/min was obtained in a CF4(20 %)/Ar(80 %) plasma. The presence of a maximum in the BLT etch rate at CF4(20 %)/Ar(80 %) may be explained by the concurrence of two etching mechanisms, physical sputtering and chemical reaction. Ar-ion bombardment played roles of destroying the metal (Bi, La, Ti)-O bonds and assisting the chemical reaction between metal and uorine atoms. The chemical states of BLT were investigated using X-ray photoelectron spectroscopy (XPS), which conrmed the existence of nonvolatile etch byproducts (La- uorides).

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        Model-Based Analysis of the ZrO2 Etching Mechanism in Inductively Coupled BCl3/Ar and BCl3/CHF3/Ar Plasmas

        Mansu Kim,민남기,Sun Jin Yun,Hyun Woo Lee,Alexander M. Efremov,권광호 한국전자통신연구원 2008 ETRI Journal Vol.30 No.3

        The etching mechanism of ZrO2 thin films and etch selectivity over some materials in both BCl3/Ar and BCl3/CHF3/Ar plasmas are investigated using a combination of experimental and modeling methods. To obtain the data on plasma composition and fluxes of active species, global (0-dimensional) plasma models are developed with Langmuir probe diagnostics data. In BCl3/Ar plasma, changes in gas mixing ratio result in nonlinear changes of both densities and fluxes for Cl, BCl2, and BCl2 +. In this work, it is shown that the nonmonotonic behavior of the ZrO2 etch rate as a function of the BCl3/Ar mixing ratio could be related to the ionassisted etch mechanism and the ion-flux-limited etch regime. The addition of up to 33% CHF3 to the BCl3-rich BCl3/Ar plasma does not influence the ZrO2 etch rate, but it non-monotonically changes the etch rates of both Si and SiO2. The last effect can probably be associated with the corresponding behavior of the F atom density.

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