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Silent Discharge와 TiO₂광촉매 산화반응을 이용한 VOCs 처리
박석출,정창훈,서정민,최금찬 동아대학교 환경문제연구소 1999 硏究報告 Vol.22 No.2
This study has been carried out for evaluation of VOCs treatment let out at the industrial field using a silent discharge process through process approvement and TiO₂ photocatalytic oxidation. And it was presented experimental results on the silent discharge plasma and TiO₂ photocatalytic oxidation processes at atmospheric pressure gas streams containing diluted concentrations of benzene, toluene, and xylene out of VOCs. It has shown that each concentration, background gas, flowrate, and applied power have effected on three materials decomposition and byproduct distribution. Analyses of benzene, toluene, xylene and byproduct concentration was carried out by GC-FID.
플라즈마를 이용한 VOCs 중 트리클로로에틸렌의 처리에 관한 연구
이일락,박석출,서정민,조정구,최금찬 동아대학교 환경문제연구소 1998 硏究報告 Vol.21 No.2
This study has carried out for evaluation of Trichloroethylene treatment let out at the working place using a silent discharge, one out of methods to control Volatile Organic Compounds. 1. Comparative test for Ozone creation as a function of whether Trichloroethylene included or not, both of them were increased by 270ppm when the electric field intensity goes up(~30kV/cm) and dry air condition included Trichloroethylene were high more or less. It is expected that Trichloroethylene has an influence on Ozone creation as Ozone presecution substance. 2. Input Trichloroethylene concentration and flow rate related to electric field intensity had effect on decomposition efficiency. Trichloroethylene decomposition efficiency increased with rising of applied voltage. But, Treatment efficiency were lower than N₂ condition, in case of using dry air as diluted gas, due to dissipation of electron energy by triplet oxygen molecules. 3. The more increased concentration(100, 200 and 300ppm1, the lower decreased removal efficiency(96, 93.6, 90.3% at N₂ and 86, 84, 90% at dry air) and these tendencies were released at the flow rate(1, 2 and 3 ℓ / min) similarly. 4. Byproducts generated by oxidation of Trichloroethylene-Carbon monooxide, Ozone, Methyl Chloride, Chlorofom, l,l,l-Trichloroethane and Tetrachloroethylene were found out.