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      • KCI등재

        Multifunctional properties of tin oxide nanoparticles synthesized by green and chemical approach

        Uday Y.S.,Manjunatha H.C.,Vidya Y.S.,Manjunatha S.,Soundar R.,Sridhar K.N. 한국물리학회 2023 Current Applied Physics Vol.55 No.-

        Herein, we report the synthesis of SnO2 nanoparticles by combustion method using two reducing agents. One with urea as a fuel (SnO2U) and another one with Azadirachta indica leaves extract as a reducing agent (SnO2N) and calcined at 500oC for 3 hrs. The synthesized samples are characterized using different techniques. The Bragg reflections confirms the formation of pure tetragonal SnO2 NPs. The surface morphological analysis clearly indicates the formation of irregular shaped agglomerated NPs. The agglomeration and particle size was found to be more in SnO2U NPs. The estimated direct energy bandgap using Tauc's relation was found to be 3.75 and 3.37 eV for SnO2U and SnO2N respectively. Further, Photoluminescence excitation, emission, CIE and CCT analysis was performed. Thus, the present sample might be used as a nanophosphor material in Cool and Warm blue light emitting diodes. The cytotoxic properties against HeLa and MCF7 cells and compared the percentage of viability and cell death with standard chemotherapy drug Cisplatin. Theoretically, X-ray/gamma ray absorption properties such as mass attenuation coefficient (MAC) SnO2U and SnO2N NPs were evaluated which might finds an application in nuclear radiation dosimetry.

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        X-ray/gamma radiation shielding properties of Aluminium-Barium Zinc Oxide nanoparticles synthesized via low temperature solution combustion method

        Sathish K.V.,Sridhar K.N.,Seenappa L.,Manjunatha H.C.,Vidya Y.S.,Chinnappa Reddy B.,Manjunatha S.,Santhosh A.N.,Munirathnam R.,Raj Alfred Cecil,Damodara Gupta P.S.,Sankarshan B.M. 한국원자력학회 2023 Nuclear Engineering and Technology Vol.55 No.5

        For the first time Aluminium-BariumeZinc oxide nanocomposite (ZABONC) was synthesized by solution combustion method where calcination was carried out at low temperatures (6000 C) to study the electromagnetic (EM) (X/g) radiation shielding properties. Further for characterization purpose standard techniques like PXRD, SEM, UV-VISIBLE, FTIR were used to find phase purity, functional groups, surface morphology, and to do structural analysis and energy band gap determination. The PXRD pattern shows (hkl) planes corresponding to spinel cubic phase of ZnAl2O4, cubic BaðNO3Þ2, a and g phase of Al2O3 which clearly confirms the formation of complex nano composite. From SEM histogram mean size of nano particles was calculated and is in the order of 17 nm. Wood and Tauc’s relation direct energy band gap calculation gives energy gap of 2.9 eV. In addition, EM (X/g) shielding properties were measured and compared with the theoretical ones using standard procedures (NaI (Tl) detector and multi channel analyzer MCA). For energy above 356 keV the measured shielding parameters agree well with the theory, while below this value slight deviation is observed, due to the influence of atomic/crystallite size of the ZABONC. Hence synthesized ZABONC can be used as a shielding material in EM (X/g) radiation shielding

      • KCI등재

        X-ray / gamma ray radiation shielding properties of a-Bi 2 O 3 synthesized by low temperature solution combustion method

        B. Chinnappa Reddy,H.C. Manjunatha,Y.S. Vidya,K.N. Sridhar,U. Mahaboob Pasha,L. Seenappa,B. Sadashivamurthy,N. Dhananjaya,K.V. Sathish,P.S. Damodara Gupta 한국원자력학회 2022 Nuclear Engineering and Technology Vol.54 No.3

        In the present communication, pure and stable a-Bismuth Oxide (Bi2O3) nanoparticles (NPs) weresynthesized by low temperature solution combustion method using urea as a fuel and calcined at 500oC. The synthesized sample was characterized by using powder X-ray Diffraction (PXRD), Scanning ElectronMicroscopy (SEM), Energy dispersive X-ray analysis (EDAX), Transmission Electron Microscopy (TEM),Fourier Transform Infrared Spectroscopy (FTIR) and UVeVisible absorption spectroscopy. The PXRDpattern confirms the formation of mono-clinic, stable and low temperature phase a-Bi2O3. The directoptical energy band gap was estimated by usingWood and Tauc's relation which was found to be 2.81 eV. The characterized sample was studied for X-ray/gamma ray shielding properties in the energy range0.081e1.332 MeV using NaI (Tl) detector and multi channel analyzer (MCA). The measured shieldingparameters agrees well with the theory, whereas, slight deviation up to 20% is observed below 356 keV. This deviation is mainly due to the influence of atomic size of the target medium. Furthermore an accuratetheory is necessary to explain the interaction of X-ray/gamma ray with the NPs.The present workopens new window to use this facile, economical, efficient, low temperature method to synthesizenanomaterials for X-ray/gamma ray shielding purpose

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