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Wenwei Yu,Faying Lai,Jinbao He,Kaiyun He,Rong Wang,Danping Li,Quanyuan Chen 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.118 No.-
Catalytic performances and leaching behavior of 9 natural iron minerals as heterogeneous electro-Fentoncatalysts for the treatment of imidacloprid wastewater were studied. The results showed that magnesioferriteexhibited the best catalytic ability among these minerals with UV absorbance at 270 nm (UV270)removal of 83.59% and COD removal of 49.11% within 4 h using graphite cathode and Ti/(RuO2)0.88-(IrO2)0.12 anode at initial pH 3 with a catalyst dose of 5 g/L, a current density of 40 mA/cm2 and an electrodespacing of 2 cm. The instantaneous current efficiency (ICE) at 4 h and energy consumption (EC)reached 2.30% and 2.20 kWh/gCOD respectively. It was found that the components contained in naturaliron minerals, such as Al, alkali metal (K) and alkaline earth metals (Mg, Ca, Ba), would dissolve into theelectrolyte solution, raising the final pH to 6.5–8.5 and ultimately reducing the reaction efficiency. Exceptmagnetite and magnesioferrite, other minerals, such as ilmenite and V-Ti magnetite, were likely to causesecondary pollution. The subsequent adjustment to alkaline state for chemical precipitation of leachedMn was needed. Pyrite showed relatively high leachability in hazardous elements (especially Pb), whichshould be carefully evaluated before its actual application in electro-Fenton process.
Numerical and experimental buckling of segmented spiral pressure hulls
Jian Zhang,Rui Wang,Yongsheng Li,Weibo Wang,Wenwei Wu 대한기계학회 2022 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.36 No.4
To optimally coordinate the operational safety, manoeuvrability, positioning reliability, and space expansibility of deep-sea stations, this study proposed a segmented spiral pressure hull with reference to the geometry of worm snails. The design addresses the disadvantages of existing ring-stiffened cylinder, segmented sphere, and circular toroid structures. This study numerically and experimentally examined the buckling performance of segmented spiral pressure hulls. The numerical, experimental, and analytical data exhibited satisfactory agreement. The proposed pressure hulls exhibited a favourable space expansibility and buckled in a nonlinear manner. The buckling loads varied slightly after the threshold number of segments. All the post buckling modes were local dents. The current findings may serve as a reference for the research and development of original deep-sea stations.