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Zhu Wenjun,Zuo Xiaohua,Deng Xiangyi,Zhang Xinhao,Yao Chuang,Wang Xiaobo 한국탄소학회 2023 Carbon Letters Vol.33 No.2
Core–shell ZIFs wrapped CuO hybrid materials (CuO@ZIF-67(Co)) were designed, synthesized, characterized, and employed as peroxymonosulfate (PMS) activators to degrade methylene blue (MB). It demonstrated outstanding catalytic activity on account of the unique structure and the synergistic effect between CuO cores and ZIF-67(Co) shells, resulting in complete degradation of MB (10 mg/L) in 1 min. Reactive oxygen species (ROSs) research showed that both SO4− and OH were responsible for the removal of MB. The synergistic activation mechanisms in the CuO@ZIF-67(Co)/PMS system were investigated, which mainly involved the effective electron transfer of CuO and ZIF-67(Co) for accelerating the cycle of CuII/CuI and CoIII/CoII. This study broadens the application of MOF-derived materials for wastewater treatment.
Effects of rolling-cutting processing parameters on micro-grooved strips forming
Baoyu Zhang,Xianqi Fan,Guocheng Shi,Yang Zhou,Di He,Wenjun Deng 대한기계학회 2021 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.35 No.1
High heat flux density in the micro-electronics field urges the demand for functional surface for heat transfer. Micro-grooved surface is the classical heat transfer surface because of the larger specific area and better inducement of turbulence. A novel micro-grooved surface manufacturing process, the rolling-cutting process, is proposed to produce microgrooved strips. Experiments are conducted to analyze the influence of processing parameters on the strips forming. The optimal combination of processing parameters is given to attain the micro-grooved strips with higher fins height and thinner base thickness. Additionally, the obtained strips are of three-dimensional structures with serrated bulges at the top. The difference between the material flow of serrated bulges and strip base is discussed, and the forming of serrated bulges is mainly due to inhomogeneous sinuous material flow.