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        Vapor-phase selective hydrogenation of maleic anhydride to succinic anhydride over Ni/TiO2 catalysts

        Weitao Huo,Chunlei Zhang,Hongjing Yuan,Mingjun Jia,Chunli Ning,Yong Tang,Yi Zhang,Jiahuan Luo,Zhenlu Wang,Wenxiang Zhang 한국공업화학회 2014 Journal of Industrial and Engineering Chemistry Vol.20 No.6

        A series of supported Ni/TiO2 catalysts were prepared by incipient wetness impregnation method underdifferent calcination temperatures, and the as-prepared catalysts were characterized by X-ray diffraction(XRD), hydrogen temperature-programmed reduction (H2-TPR) and X-ray photoelectron spectroscopy(XPS). The catalytic properties of these Ni/TiO2 catalysts were investigated in the vapor phasehydrogenation of maleic anhydride (MA) to succinic anhydride (SA). The results showed that thecatalytic activity and the selectivity of the Ni/TiO2 catalysts were strongly affected by the calcinationtemperature. The catalyst calcined at 1023 K showed a relatively higher SA selectivity of 96% at high MAconversion (96%) under the tested conditions (493 K and 0.2 MPa). The improvement of SA selectivitycould be mainly assigned to the presence of suitable metal–support interaction, which can play a role incatalytic property of active nickel species as electron promoter. Besides, the change of surface propertiesof TiO2 support with the increasing calcination temperatures, e.g., the decrease of Lewis acid sites, mightalso have some positive role in reducing the side-products like g-butyrolacetone (GBL).

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        Improvement of the Microstructure and Microhardness of AQ80 Magnesium Alloy by Repeated Upsetting-Extrusion

        Yutian Fan,Liwei Lu,Tao Zhou,Hua Zhang,Fugang Qi,Min Ma,Zhiqiang Wu,Weitao Jia,Sha Zhang,Weiying Huang 대한금속·재료학회 2023 METALS AND MATERIALS International Vol.29 No.10

        In this work, a novel process of repeated upsetting-extrusion (RUE) was used to fabricate the AQ80 magnesium (Mg) alloy. The effects of deformation passes on the microstructure and microhardness of the RUEed AQ80 Mg alloy were studied. The results showed that {10–12} extension twins appeared in the sample after 1 pass of deformation compared to the initial sample, which divided the coarse grains and achieved the preliminary refinement of the grains. The grains were uniformly refined further with increasing RUE deformation passes, and after 3 passes, the average grain size was reduced from 27.4 to 3.0 μm. The grains were refined mainly by continuous dynamic recrystallization (CDRX), particle-stimulated nucleation (PSN), and discontinuous dynamic recrystallization (DDRX) mechanisms. After RUE deformation, the peak component of the texture was tilted by 0–20° toward the extrusion direction (ED) because of the increased activation of pyramidal < c + a > slip. The microhardness of the 3-pass RUE deformed sample increased by 12.9% compared to the initial sample. This is mainly attributable to fine-grained strengthening and second phase strengthening.

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