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        Recent advances on Pestalotiopsis genus: chemistry, biological activities, structure–activity relationship, and biosynthesis

        Peng Jiang,Xiujuan Fu,Hong Niu,Siwei Chen,Feifei Liu,Yu Luo,Dan Zhang,Hui Lei 대한약학회 2023 Archives of Pharmacal Research Vol.46 No.6

        Strains of the fungal genus Pestalotiopsis are reported as large promising sources of structurally varied biologically active metabolites. Many bioactive secondary metabolites with diverse structural features have been derived from Pestalotiopsis. Moreover, some of these compounds can potentially be developed into lead compounds. Herein, we have systematically reviewed the chemical constituents and bioactivities of the fungal genus Pestalotiopsis, covering a period ranging from January 2016 to December 2022. As many as 307 compounds, including terpenoids, coumarins, lactones, polyketides, and alkaloids, were isolated during this period. Furthermore, for the benefit of readers, the biosynthesis and potential medicinal value of these new compounds are also discussed in this review. Finally, the perspectives and directions for future research and the potential applications of the new compounds are summarized in various tables.

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        Synthesis of CdxZn1-xS@MIL-101(Cr) Composite Catalysts for the Photodegradation of Methylene Blue

        Shipeng Yang,Siwei Peng,Chunhui Zhang,Xuwen He,Yaqi Cai 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.10

        Nanoparticles of the semiconductor catalyst CdxZn1-xS were embedded into the metal organic framework MIL-101(Cr) to obtain CdxZn1-xS@MIL-101(Cr) nanocomposites. These materials not only possess high surface areas and mesopores but also show good utilization of light energy. The ultraviolet-visible diffuse reflectance patterns of CdxZn1-xS@MIL-101(Cr) nanocomposites showed that Cd0.8Zn0.2S@MIL-101(Cr) possessed good visible light response ability among the synthesized nanocomposites. The photocatalytic performance of the CdxZn1-xS@MIL-101(Cr) nanocomposites were tested via degradation and mineralization of methylene blue in neutral water solution under light irradiation using a 300W xenon lamp. As a result, using Cd0.8Zn0.2S@MIL-101(Cr) as a catalyst, 99.2% of methylene blue was mineralized within 30 min. Due to the synergistic effect of adsorption by the MIL-101(Cr) component and photocatalytic degradation provided by the Cd0.8Zn0.2S component, the Cd0.8Zn0.2S@MIL-101(Cr) catalyst displayed superior photocatalytic performance relative to Cd0.8Zn0.2S and MIL-101(Cr). Furthermore, Cd0.8Zn0.2S@MIL-101(Cr) possessed excellent stability during photo-degradation and exhibited good reusability. The remarkable photocatalytic performance of Cd0.8Zn0.2S@MIL-101(Cr) is likely due to the effective transfer of electrons and holes at the heterojunction interfaces.

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