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Yan Wang,Yong Zhang,Xiaolin Liu,Sen Sun,Shiyi Qin,Jiaqi Huang,Bowei Chen 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.127 No.-
To obtain a green, low-cost and efficient adsorbent, polydopamine (PDA) and b-cyclodextrin (b-CD) wereadopted to modify coal fly ash (CFA) to prepare polydopamine/b-cyclodextrin/coal fly ash composite(PDA/b-CD/CFA). The successful introduction of PDA and b-CD was proved by FT-IR, XRD and XPS. Theuranium extraction efficiency on PDA/b-CD/CFA reached 95.6% (pH = 5.0, T = 298 K, C0 = 10 mg/L andm/V = 0.2 g/L) and the whole adsorption process was perfectly fitted by the Pseudo-second-order model(R2 = 0.999), illustrating that uranium was extracted via chemisorption. The correlation coefficient R2 ofLangmuir model was 0.999, which was higher than other models, meaning that uranium extractionbehavior on PDA/b-CD/CFA was uniform monolayer adsorption. The maximum extraction capacity of uraniumon PDA/b-CD/CFA calculated by Langmuir model was 537.6 mg/g, which was larger than most ofreported adsorbents, indicating that PDA/b-CD/CFA was a potential candidate for uranium extractionfrom water environment. Moreover, PDA/b-CD/CFA performed excellent uranium extraction propertieswith the existence of coexisting ions and the desorption efficiency of uranium by PDA/b-CD/CFA washigher to 95.8% at the fifth cycles, fully suggesting that PDA/b-CD/CFA possessed good selectivity andcycle stability. Characterization results demonstrated that uranium was immobilized on PDA/b-CD/CFAthrough chelation, complexing action, electrostatic interaction and hydrogen bonding.