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        A Highly Efficient and Selective Nickel/Clay Catalyst for Liquid Phase Hydrogenation of Maleic Anhydride to Succinic Anhydride

        Tian, Weiping,Guo, Shaofei,Shi, Li Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.5

        Three Ni-based catalysts with different clay as support were prepared and tested in the hydrogenation of maleic anhydride, among which Ni/clay1 showed best activity and selectivity. Over Ni/clay1 catalyst prepared by impregnation method, 97.14% conversion of maleic anhydride and 99.55% selectivity to succinic anhydride were obtained at $180^{\circ}C$ under a pressure of 1 MPa. Catalytic activity was greatly influenced by the temperature and weighted hourly space velocity. Catalyst deactivation studies showed that this catalyst have a long life time, the yield of MA still higher than 90% even after a reaction time of 60 h. X-ray diffraction (XRD) and $H_2$ temperature programmed reduction (TPR) were use to investigate the properties of the catalyst. XRD and TPR studies showed that Ni was present as $Ni^{2+}$ on the support, which indicated that there was no elemental nickel ($Ni^0$) and $Ni_2O_3$ in the unreduced samples. The formation of Ni was strong impact on catalytic activity.

      • KCI등재

        A Highly Efficient and Selective Nickel/Clay Catalyst for Liquid Phase Hydrogenation of Maleic Anhydride to Succinic Anhydride

        Weiping Tian,Shaofei Guo,Li Shi 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.5

        Three Ni-based catalysts with different clay as support were prepared and tested in the hydrogenation of maleic anhydride, among which Ni/clay1 showed best activity and selectivity. Over Ni/clay1 catalyst prepared by impregnation method, 97.14% conversion of maleic anhydride and 99.55% selectivity to succinic anhydride were obtained at 180 °C under a pressure of 1 MPa. Catalytic activity was greatly influenced by the temperature and weighted hourly space velocity. Catalyst deactivation studies showed that this catalyst have a long life time, the yield of MA still higher than 90% even after a reaction time of 60 h. X-ray diffraction (XRD) and H2 temperature programmed reduction (TPR) were use to investigate the properties of the catalyst. XRD and TPR studies showed that Ni was present as Ni2+ on the support, which indicated that there was no elemental nickel (Ni0) and Ni2O3 in the unreduced samples. The formation of Ni was strong impact on catalytic activity.

      • KCI등재

        Thermal deformation prediction for spindle system of machining center based on multi-source heterogeneous information fusion

        Yushen Chen,Xiaolei Deng,Xiaoliang Lin,Shupeng Guo,Shaofei Jiang,Jianqiang Zhou 대한기계학회 2023 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.37 No.8

        In order to predict the thermal deformation of CNC machine tool spindle system more accurately, a method based on multi-source heterogeneous information fusion is proposed. Aiming at the problem that it is difficult to obtain the global information of thermal deformation with a single type of information source, the effective prediction of thermal deformation of spindle system in machining center is realized under the fusion of temperature and vibration signals. First, the combined denoising method of empirical mode decomposition (EMD) and wavelet threshold is used to preprocess the vibration data. Then, the time-domain, frequencydomain, and time-frequency features of vibration signals are extracted, and the feature dimension is reduced based on correlation analysis and kernel principal component analysis (KPCA). After dimensionality reduction, the vibration data and temperature information are fused in the eigenmatrix. The nonlinear prediction of thermal deformation is studied by support vector regression for grid search parameter optimization (GS-SVR) and support vector regression for particle swarm optimization (PSO-SVR) methods. In order to realize the information acquisition of multi-channel temperature, vibration, and verify the effectiveness of the prediction model in the case of information fusion, a specific machining center is taken as the research object and experiments are performed based on multi-channel and heterogeneous signal acquisition. Finally, the prediction results based on different information sources are compared and analyzed. The results show that the thermal deformation of the machine tool obtained by the multi-source heterogeneous information fusion method is consistent with the actual test results. As compared with the predicted performance using only temperature information, the mean square error (MSE) decreased by 0.1663 μm. Therefore, the temperature - vibration information fusion model has higher accuracy in terms of predicting the thermal deformation of the spindle system model.

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