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Ruixue Lv,Faizal Soyekwo,Qiugen Zhang,Runsheng Gao,Jianyang Wu,Yan Qu,Aimei Zhu,Qinglin Liu 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.49 No.-
Polymer mesoporous membranes are widely employed in many membrane processes includingultrafiltration and dialysis, and become more crucial with increasing demand in chemical and lifefields. Here we report a highly-efficient polymer membrane with sub-5 nm pores and highflux frompolyacrylonitrile (PAN) nanoparticles produced from dilute PAN solution via fast freeze-extractionprocess. The25 nm-size PAN nanoparticles forming brad-like chains are dispersed in ethanol solutionand used to prepare the membrane byfiltration-assisted assembly method across a macroporoussupport. Effects of solvents and usage of PAN on membrane formation is studied in detail. The resultantmembranes comprise of the nanoparticles stacked on the support to form a mesoporous separation layerwith a controllable thickness and a cut-off of below 5 nm. They exhibit excellent separation performancesin ultrafiltration of protein and nanoparticle solutions. Typically, the membrane with 94.6% rejection of5 nm gold nanoparticles has a pure waterflux of 823 L m 1 h 1 bar 1 and perfect rejection for ferritinmolecules and 10 nm gold nanoparticles. The newly developed membranes should have wide applicationin chemical, environment and lifefields.