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        Synthesis of silver/silver chloride/exfoliated graphite nano-photocatalyst and its enhanced visible light photocatalytic mechanism for degradation of organic pollutants

        Jianfeng Gou,Xiaohui Li,Huixuan Zhang,Ruonan Guo,Xiaoyong Deng,Xiuwen Cheng,Mingzheng Xie,Qingfeng Cheng 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.59 No.-

        Silver/silver chloride/exfoliated graphite (Ag/AgCl/EG) nano-photocatalyst was synthesized through precipitation and photoreduction processes. Afterwards, physicochemical properties of Ag/AgCl/EG were systematically studied by series of techniques. Results indicated that spherical-like Ag0 and AgCl with a diameter of 18.6 nm were deposited onto the surface of EG, resulting in the large surface area, strong visible absorbance and high charge separation efficiency. In addition, Ag/AgCl/EG exhibited high visible light photocatalytic (PC) activity for degradation of RhB (99.5%) and phenol (89.1%) solution. Also, the enhanced visible light PC mechanism was proposed and confirmed. Furthermore, Ag/AgCl/EG nano-photocatalyst performed good reusability even after six recycles utilization.

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        Fabrication of Cu2O/TiO2 nano-tube arrays photoelectrode and its enhanced photoelectrocatalytic performance for degradation of 2,4,6- trichlorophenol

        Qiuling Ma,Huixuan Zhang,Yuqi Cui,Xiaoyong Deng,Ruonan Guo,Xiuwen Cheng,Mingzheng Xie,Qingfeng Cheng 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.57 No.-

        Cu2O decorated TiO2 nano-tube arrays (Cu2O/TiO2 NTAs) photoelectrode was fabricated throughelectrodeposition strategy. Meanwhile, physicochemical properties of the resulting photoelectrode weresystematically studied by series of measurements. Results indicated that Cu2O/TiO2 NTAs photoelectrodeperformed a significantly enhanced light absorbance in the visible region between 400 and 800 nm,transient photocurrent density of 0.162 mA Cm 2, photogenerated charge separation efficiency and 99.9%of photoelectrocatalytic efficiency for decomposition of 2,4,6-trichlorophenol within 120 min Xenonillumination with the help of +1.0 V (vs. SCE) potential. Furthermore, the enhanced visible lightresponsible photoelectrocatalytic mechanism was proposed and discussed.

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        Dewatering of a 32.55 m Deep Foundation Pit in MAMA Under Leakage Risk Conditions

        Jianxiu Wang,Xiaotian Liu,Jiaxing Liu,Linbo Wu,Qingfeng Guo,Qian Yang 대한토목학회 2018 KSCE JOURNAL OF CIVIL ENGINEERING Vol.22 No.8

        A 2,250 mm whirlpool foundation pit is located in Donghai Island, Zhanjiang City, Guangdong Province, China. The layers of theisland are composed of multi-aquifers and multi-aquitards (MAMA). The aquifers are intersected by partial aquitard lenses. A largeconfined aquifer is frequently interbedded and separated into several sub-confined aquifers by partial aquitards. In the 2,250 mmfoundation pit, the water level of two confined aquifers was reduced to satisfy excavation requirements and prevent water inrush. Construction of the 32.55 m deep foundation pit encountered MAMA and potential defects of the diaphragm wall. The pumpingwells in the second confined aquifer were used to reduce the water level to ensure the safety of bottom excavation. The pumpingwells in the first confined aquifer were used to reduce the water level under emergency conditions to prevent potential water inrushand piping from the defects of the diaphragm wall. Field pumping tests and numerical simulations were performed to determine therisk of leakage and verify the capability of the pumping wells to reduce the water level. Quicksand occurred during shallowexcavation because of leakage although the confined aquifer had been cut off and pumped for a long time. Three pumping wells wereinstalled to reduce the water level. When the foundation pit was excavated to a depth of 24 m, water inrush occurred at the middle ofthe pit bottom although the water level of the dewatered aquifer had been reduced to below the excavation face. A 90 m deepborehole was found where the underlying confined aquifer below the first aquifer induced the water inrush. Although the upper waterlevel was reduced, the high water level in the deep part still induced water inrush. The pumping wells in the second aquifer were allopened, and the water level of the underlying confined aquifer was reduced. After the water level was reduced to below the pitbottom, the borehole was filled, and the water inrush stopped. However, water inrush occurred on the cracks of the diaphragm wall aspredicted. The pre-installed pumping wells were opened to control the water inrush. The deepest foundation pit on the island wasconstructed successfully after dealing with the water inrush and leakages.

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