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Huiqin Wang,Pengwei Huo,Jinze Li,Mingjun Zhou,Qingfeng Guan,Ziyang Lu,Yongsheng Yan 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.30 No.-
The Ag2O/SWNTs photocatalysts were prepared by precipitated method, the photocatalysts werecharacterized by XRD, SEM, TEM, EDS, BET, UV–vis DRS, XPS, PL and Raman. The photocatalytic activitieswere evaluated by degradation of tetracycline. The results showed that the composited photocatalystswere successfully prepared, the responded light was enhanced with increasing the supported dosage ofAg2O, and the photocatalytic activity was also improved. The enhanced photocatalytic activity wasattributed to the synergy effect of SWNTs and Ag2O, the recycled degradation of tetracycline exhibitedstability of Ag2O/SWNTs composited photocatalysts. Finally, the possible mechanism for transferredprocesses of photoelectrons and photoholes were proposed.
Huiqin Wang,Xiaoqing Yang,Jinzhao Zi,Mingjun Zhou,Zhefei Ye,Jinze Li,Qingfeng Guan,Peng Lv,Pengwei Huo,Yongsheng Yan 한국공업화학회 2016 Journal of Industrial and Engineering Chemistry Vol.35 No.-
Ag/AgCl/activated carbon (AC) plasmonic photocatalysts were prepared by precipitation and photoreduc-tion method. The as-prepared plasmonic photocatalysts were characterized by XRD, SEM, BET, EDS, UV–visDRS, XPS and PL. The results show the composite photocatalysts are successfully obtained and obviouslyexhibit surface plasmon resonance and effectively enhance the separation of h+/e . The photocatalyticdegradation rate of tetracycline (TC) could reach 97.3% in 60 min under visible light irradiation and cycledexperiments show stably photocatalytic activities. The active species analysis displays holes andsuperoxide radicals are the main reactive species. Photocatalytic kinetic indicates that the degradationprocesses obey pseudo first order kinetic equation.
Yuxin Li,Jinhao Nie,Yixin Yang,Peikang Bai,Hongjian Zhang,Zhanyong Zhao,Shouzheng Wei,Jie Cai,Qingfeng Guan 대한금속·재료학회 2022 METALS AND MATERIALS International Vol.28 No.2
To improve the high-temperature resistance of the key hot-end parts of the steam turbine, NiCoCrAlY coatings were depositedon a 304 stainless steel substrate by laser cladding. The microstructure and high-temperature oxidation behavior of theNiCoCrAlY coatings were analyzed. The results showed that the NiCoCrAlY coatings contained γ/γ′ and β phases, and themicrostructure was mainly composed of elongated columnar crystals. In addition, after 100 h of oxidation at three differentoxidation temperatures (750, 850 and 950 °C), the coatings showed a relatively low oxidation rate, which was approximatelya quarter of the oxidation rate of the substrate. At the same time, the protective Cr2O3scales were formed on the coatingsurface. When the oxidation temperature was 850 °C, the FeCr2O4spinel formed and internal oxidation zone appeared,when the oxidation temperature reached 950 °C, the FeCr2O4spinel gathered in the local area on the surface of the Cr2O3scale and the internal oxidation was aggravated. In other words, as the oxidation temperature increased, the Fe element inthe matrix formed the FeCr2O4spinel, which accelerated the consumption of Cr element in the coatings and reduced theoverall oxidation resistance of the NiCoCrAlY coatings.