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P. Mohamed Shameer,K. Ramesh 대한기계학회 2017 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.31 No.3
This study experimentally focuses on finding the optimum blend ratio for Direct injection (D.I) diesel engine fuelled with mahua oildiesel and n-butanol- diesel without any modifications in the engine. Test fuels were prepared by choosing 8 different concentrations as B10 (10 % Biodiesel and 90 % Diesel), B20 (20 % Biodiesel and 80 % Diesel), B30 (30 % Biodiesel and 70 % Diesel), B40 (40 % Biodiesel and 60 % Diesel), BU10 (10 % n-butanol and 90 % Diesel), BU20 (20 % n-butanol and 80 % Diesel), BU30 (30 % n-butanol and 70 % Diesel), BU40 (40 % n-butanol and 60 % Diesel). Experiments were performed at constant speed and variable loads at standard injection timing of 23 Crank angle degree BTDC and standard compression ratio of 16.5:1 to determine the engine performance indicators and exhaust gas emissions such as carbon monoxide, carbon dioxide, hydrocarbon, soot content and oxides of nitrogen. The optimum blend ratio for mahua biodiesel- diesel blend and n-butanol- diesel blend were determined and compared on eco-friendly and economical basis to gain the suitable substitute fuel. The result showed that Mahua biodiesel blend is eco-friendly and economically apt alternative fuel for diesel.
Mohamed Shameer P.,Ramesh K. 대한기계학회 2017 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.31 No.7
‘Storage oxidation stability’ is one of the most significant criteria for appraising the biodiesel quality. Poor oxidation stability is the chief technical blockage related with the commercialization of biodiesel. The present paper investigates the effects of Tert- butyl hydroquinone (TBHQ) antioxidant additive concentrations on the long-term storage stability, thermal stability and accelerated oxidation stability of Calophyllum inophyllum biodiesel. Fourier transform infra-red (FTIR) spectroscopy was used to characterize the biodiesel oxidation variability, following the regions of C-H and O-H bonds in FTIR spectrum for different concentrations of TBHQ. Addition of TBHQ at 1000 ppm concentration (B100A3) with pure biodiesel enhances the oxidation stability by 94.67 %, storage stability by 14.47 % and thermal stability by 69.55 %; whereas further concentration of antioxidant deteriorates the formation of hydrophobic and hydrophilic clusters between biodiesel/antioxidant compounds, which is characterized by FTIR spectrum data. It is concluded that the Calophyllum inophyllum biodiesel could be accumulated for an extensive period by dosing 1000 ppm of TBHQ antioxidant.