http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Jinghong Zhou,Long Zhao,Hong Chen,Mingguang Zhang,Zhijun Sui,Xinggui Zhou 한국화학공학회 2010 Korean Journal of Chemical Engineering Vol.27 No.5
Carbon nanofiber (CNFs) supported Ru catalysts for sorbitol hydrogenolysis to ethylene glycol and propylene glycol were prepared by incipient wetness impregnation, calcination and reduction. The effect of calcination on catalyst properties was investigated using thermal gravimetry analysis, temperature-programmed reduction, X-ray diffraction,X-ray photoelectron spectroscopy, transmission electron microscopy and N2 physisorption. The results indicated that calcination introduced a great amount of surface oxygen-containing groups (SOCGs) onto CNF surface and induced the phase transformation of Ru species, but slightly changed the texture of Ru/CNFs. The catalytic performance in sorbitol hydrogenolysis showed that Ru/CNFs catalyst calcined at 240 oC presented the highest glycol selectivities and reasonable glycol yields. It was believed that the inhibition and confinement effect of SOCGs around Ru particles as well as the high dispersion of Ru particles was the key factor for the catalytic activity.
Dynamic Unloading Instability Mechanism of Underground Cavern Based on Seepage-Damage Coupling
Li-Ping Li,Wenfeng Tu,Zongqing Zhou,Shao-shuai Shi,Mingguang Zhang,Yuxue Chen 대한토목학회 2020 KSCE Journal of Civil Engineering Vol.24 No.5
The seepage-damage coupling effect will aggravate the instability of the surrounding rock during the unloading process of underground cavern excavation. Considering this coupling effect and excavation disturbance, the theoretical solution of the stress state of surrounding rock is derived by using the elastic-brittle damage model. The dynamic criterion of the instability and water inrush is presented. Based on the theoretical derivation, the calculation program for the seepage-damage analysis of the surrounding rock under dynamic unloading is programmed, and the seepage flow and the radius of the damage zone of the surrounding rock are calculated. By analysing the variation of radius of the damaged zone with pore water pressure and excavation radius under different calculation conditions, the influence of dynamic unloading disturbance on the damaged zone of the surrounding rock is discussed. The radius of the damaged zone increases with the pore water pressure and excavation radius. Considering the effect of dynamic unloading, the calculation result of the damaged zone radius and seepage discharge of underground cavern are much larger than the theoretical calculation and coupling calculation of seepage-damage without dynamic unloading. Research methods and results can provide guidance and reference for similar engineering research.