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Mn-doped Zn/Al layered double hydroxides as photocatalysts for the 4-chlorophenol photodegradation
Morales-Mendoza, G.,Tzompantzi, F.,Garcia-Mendoza, C.,Lopez, R.,De la Luz, V.,Lee, S.W.,Kim, T.H.,Torres-Martinez, L.M.,Gomez, R. Elsevier 2015 Applied clay science Vol.118 No.-
Mn-doped Zn/Al layered double hydroxides (LDH) with Mn 0.5-3.0% mol respect to Zn content with improved photocatalytic degradation of 4-chlorophenol (4Clphenol) were studied. The characterization studies showed the isomorphic incorporation Mn as dopant until 1% mol. The 4Clphenol degradation was proposed as result of a combined effect of oxidation by both hydroxyl radicals (OH?) and photogenerated holes (h<SUP>+</SUP>). In a proposed mechanism it is suggested that Mn enhances the charge separation acting as electron e<SUP>-</SUP> (Mn<SUP>3+</SUP>; Mn<SUP>4+</SUP>) or hole h<SUP>+</SUP> (Mn<SUP>2+</SUP>; Mn<SUP>3+</SUP>) traps according to its oxidation state. Exhaustive characterization through EDS, XRD, UV-vis-DRS, TEM-Dark field STEM, fluorescence spectroscopy for OH? detection and XPS, has been done denoting the importance of the Mn content and its different oxidation states in the photophysical and photocatalytic properties of the Mn-doped Zn/Al-based layered double hydroxides.
Improved Neutron Capture Cross Section Measurements with the n_TOF Total Absorption Calorimeter
E. Mendoza,V. Becares,A. Casado,D. Cano-Ott,M. Fernandez-Ordonez,E. Gonzalez-Romero,C. Guerrero,T. Martinez,J. J. Vidriales,J. Andrzejewski,J. Marganiec,J. Perkowski,L. Audouin,B. Berthier,L. Tassan-G 한국물리학회 2011 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.59 No.23
The n_TOF collaboration operates a Total Absorption Calorimeter (TAC) [1] for measuring neutron capture cross-sections of low-mass and/or radioactive samples. The results obtained with the TAC have led to a substantial improvement of the capture cross sections of ^(237)Np and ^(240)Pu [2].The experience acquired during the first measurements has allowed us to optimize the performance of the TAC and to improve the capture signal to background ratio, thus opening the way to more complex and demanding measurements on rare radioactive materials. The new design has been reached by a series of detailed Monte Carlo simulations of complete experiments and dedicated test measurements. The new capture setup will be presented and the main achievements highlighted. KEYWORDS: ND2010, nuclear data, n\textunderscore TOF, background, Monte Carlo, neutron, time of flight, cross section, calorimeter, shielding, simulation, total absorption, gamma ray, neutron capture.
Remote Healthcare Program in Mexico in the Context of the COVID-19 Pandemic
Rodolfo Lehmann Mendoza,Gabriela Yanet Cortés Moreno,Hilario Ascensión Martinez Arredondo,Anaya Aguilar Cynthia Jeanet,Pedro Armando Chaidez Rosales,Ilicia González Mundo,Armando Mejía Nava,Adrian H. 대한의료정보학회 2022 Healthcare Informatics Research Vol.28 No.2
Objectives: Given the challenge of limiting the transmission of coronavirus disease 2019 while simultaneously continuingto provide medical care for other chronic and degenerative diseases and monitor therapy, a remote medical advice and guidanceprogram was created to help individuals receive health services at their homes. Methods: A descriptive, cross-sectional,and observational study was performed from April 13, 2020 to April 19, 2021 among Petroleos Mexicanos (PEMEX) healthservices beneficiaries. Mobile text messages were used to assign patients throughout Mexico to a doctor, who coordinateda video call with the nursing service for advice and remote care. Results: In total, 17,472 calls were registered, with an averageduration of 10.28 minutes. Almost half (49.4%) of the people who requested attention through the remote program wereworkers, 31.5% were workers’ relatives, and 19.1% were retired workers. The average age of the program users was 50.66 ±18.02 years. A total of 144 doctors from 28 different specialties participated. In this program, 7,163 calls were made becauseof respiratory symptoms, 1,514 for therapeutic monitoring (prescriptions), and 8,183 because of other diseases, includingmental health. Conclusions: Remote healthcare programs have shown the potential to support the health system. This programis the first to deploy real-time video calls with a health team utilizing institutional electronic clinical records in Mexico. The implementation of this pandemic management program impacted the number of consultations given remotely, resultingin effective triage.
Israel Lerma-Reyes,German D. Mendoza-Martinez,Rolado Rojo-Rubio,Mario Mejia,J.C. Garcia-Lopez,Hector A. Lee-Rangel 아세아·태평양축산학회 2018 Animal Bioscience Vol.31 No.2
Objective: This experiment was designed to evaluate the effect of supplementation with soybean or canola oil on milk production and the composition of long chain fatty acids as well as weight changes in the goats and their kids. Methods: Thirty nine mulitparous crossed Alpine×Nubian goats (initial body weight [BW] 43.5±1.7 kg) from the day of parturition were assigned to the treatments: grazing control (n = 15); grazing plus 20 mL/goat/d of supplemental soybean oil (n = 12); and grazing plus 20 mL/goat/d of supplemental canola oil (n = 12) from November 26, 2014 to March 7, 2015. The planned contrasts were: CI (control vs supplemented with oils); CII (soybean vs canola oil) to compare the treatment effects. Results: The vegetable oil supplementation reduced weight losses in lactating goats (CI: –0.060 vs 0.090 kg/d; p = 0.03) but did not improve milk production or affect kids’ growth. The content of C4, C6, C8, C10, C11, C14, and C18:1n9t in the milk was increased (p<0.05) with respect to control. However, C12, C14, C16, C18, C18:1n9c, C18:2n6c, and C18:3n3 were reduced (p<0.05) in supplemented goats. Conjugated linoleic acid (CLA) was increased (p<0.05) in goats supplemented with oils compared to the control group. Conclusion: Supplementation with 20 mL/d of soybean or canola oil did not affect milk production or kids’ performance; however, it increased CLA concentration and reduced the reduced weight losses in lactating goats.
Soybean meal substitution by dehulled lupine (Lupinus angustifolius) with enzymes in broiler diets
Fredy Mera-Zuniga,Arturo Pro-Martinez,Juan F Zamora-Natera,Eliseo Sosa-Montes,Juan D Guerrero-Rodriguez,Sergio I Mendoza-Pedroza,Juan M Cuca-Garcia,Rosa M Lopez-Romero,David Chan-Diaz,Carlos M Becerri 아세아·태평양축산학회 2019 Animal Bioscience Vol.32 No.4
Objective: Evaluate the effects of i) dehulling of lupine seed on chemical composition and apparent metabolizable energy (AME) and ii) soybean meal substitution by dehulled lupine seed in broiler diets with enzymes on productive performance, size of digestive organs and welfare-related variables. Methods: Experiment 1, chemical composition and AME were determined in whole and dehulled lupine seed. Experiment 2, two hundred eighty-eight one-day-old male Ross 308 broilers were used. The experimental diets were maize-soybean meal (MS), MS with enzymes (MSE) and maize-dehulled lupine seed with enzymes (MLE). Diets were assigned to the experimental units under a completely randomized design (eight replicates per diet). The body weight (BW) gain, feed intake, feed conversion, digestive organ weights, gait score, latency to lie down and valgus/varus angulation were evaluated. Results: The dehulling process increased protein (25.0% to 31.1%), AME (5.9 to 8.8 MJ/kg) and amino acid contents. The BW gain of broilers fed the MLE diet was similar (p>0.05) to that of those fed the MS diet, but lower than that of those fed the MSE diet. Feed intake of broilers fed the MLE diet was higher (p<0.05) than that of those fed the MS diet and similar (p>0.05) to those fed the MSE diet. Feed conversion of broilers fed the MLE diet was 8.0% and 8.7% higher (p<0.05) than that of those fed the MS and MSE diets, respectively. Broilers fed the MLE diet had the highest (p<0.05) relative proventriculus and gizzard weights, but had poor welfare-related variables. Conclusion: It is possible to substitute soybean meal by dehulled lupine seed with enzymes in broiler diets, obtaining similar BW gains in broilers fed the MLE and MS diets; however, a higher feed intake is required. Additionally, the MLE diet reduced welfare-related variables.
Correlation between pr1 and pr2 Gene Content and Virulence in Metarhizium anisopliae Strains
( Ninfa M Rosas Garcia ),( Osvaldo Avalos De Leon ),( Jesus M Villegas Mendoza ),( Maribel Mireles Martinez ),( J E Barboza Corona ),( J C Castaneda Ramirez ) 한국미생물 · 생명공학회 2014 Journal of microbiology and biotechnology Vol.24 No.11
Metarhizium anisopliae is a widely studied model to understand the virulence factors that participate in pathogenicity. Proteases such as subtilisin-like enzymes (Pr1) and trypsin-like enzymes (Pr2) are considered important factors for insect cuticle degradation. In four M. anisopliae strains (798, 6342, 6345, and 6347), the presence of pr1 and pr2 genes, as well as the enzymatic activity of these genes, was correlated with their virulence against two different insect pests. The 11 pr1 genes (A, B, C, D, E, F, G, H, I, J, and K) and pr2 gene were found in all strains. The activity of individual Pr1 and Pr2 proteases exhibited variation in time (24, 48, 72, and 96 h) and in the presence or absence of chitin as the inductor. The highest Pr1 enzymatic activity was shown by strain 798 at 48 h with chitin. The highest Pr2 enzymatic activity was exhibited by the 6342 and 6347 strains, both grown with chitin at 24 and 48 h, respectively. Highest mortality on S. exigua was caused by strain 6342 at 48 h, and strains 6342, 6345, and 6347 caused the highest mortality 7 days later. Mortality on Prosapia reached 30% without variation. The presence of subtilisin and trypsin genes and the activity of these proteases in M. anisopliae strains cannot be associated with the virulence against the two insect pests. Probably, subtilisin and trypsin enzyme production is not a vital factor for pathogenicity, but its contribution is important to the pathogenicity process.
D. Cano-Ott,F. Alvarez-Velarde,E. Gonzalez-Romero,C. Guerrero,T. Martinez,E. Mendoza,D. Villamarin,M. C. Vicente,U. Abbondanno,N. Colonna,M. H. Meaze,S. Marrone,G. Tagliente,R. Terlizzi,F. Belloni,K. 한국물리학회 2011 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.59 No.23
The successful development of advanced nuclear systems for sustainable energy production and nuclear waste management depends on high quality nuclear data libraries. Recent sensitivity studies and reports [1][2][3] have identified the need for substantially improving the accuracy of neutron cross-section data for minor actinides. The n_TOF collaboration has initiated an ambitious experimental program for the measurement of neutron capture cross sections of minor actinides. Two experimental setups have been constructed for this purpose: a Total Absorption Calorimeter (TAC) [4] for measuring neutron capture cross-sections of low-mass and/or radioactive samples and a set of two low neutron sensitivity C_6D_6 detectors for the less radioactive materials.
Study of Photon Strength Function of Actinides: the Case of ^(235)U, ^(238)Np and ^(241)Pu
C. Guerrero,F. Alvarez-Velarde,D. Cano-Ott,T. Martinez,E. Mendoza,D. Villamarin,N. Colonna,M. H. Meaze,S. Marrone,G. Tagliente,R. Terlizzi,F. Belloni,U. Abbondanno,K. Fujii,P. M. Milazzo,C. Moreau,G. 한국물리학회 2011 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.59 No.23
The decay from excited levels in medium and heavy nuclei can be described in a statisticalapproach by means of Photon Strength Functions and Level Density distributions. The study of electromagnetic cascades following neutron capture based on the use of high eciency detectors has been shown to be well suited for probing the properties of the Photon Strength Function of heavy (high level density) and/or radioactive (high background) nuclei. In this work we have investigated for the first time the validity of the recommended PSF of actinides, in particular ^(235)U, ^(238)Np and ^(241)Pu. Our study includes the search for resonance structures in the PSF below S_n and draws conclusions regarding their existence and their characteristics in terms of energy, width and electromagnetic nature.
Alejandra Mina Rosales,Elena Aznar,Carmen Coll,Ruben A. Garcia Mendoza,A. Lorena Urbano Bojorge,Nazario Felix Gonzalez,Ramon Martinez-Manez,Francisco del Pozo Guerrero,Jose Javier Serrano Olmedo 한국자기학회 2016 Journal of Magnetics Vol.21 No.3
Magnetic hyperthermia mediated by superparamagnetic particles is mainly based in sinusoidal waveforms as excitation signals. Temperature changes are conventionally explained by rotation of the particles in the surrounding medium. This is a hypothesis quite questionable since habitual experimental setups only produce changes in the magnetic module, not in the field lines trajectories. Theoretical results were tested by changing the waveform of the exciting signal in order to compare non-sinusoidal signals against sinusoidal signals. Experiments were done at different frequencies: 200 ㎑, 400 ㎑, 600 ㎑, 800 ㎑ and 1 ㎒. Superparamagnetic Iron Oxide samples (SPION), made of magnetite (Fe3O4) and suspended in water (100 ㎎/ml), were used. Magnetic field strength varies from 0.1 ± 0.015 KA/m to 0.6 ± 0.015 KA/m. In this study was observed that the power loss depends on the applied frequency: for 1 to 2.5 RMS current the responses for each signal are part of the higher section of the exponential function, and for 3.5 to 8 RMS current the response is clearly the decrement exponential function’s tale (under 1 × 10³ LER/gr).