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El Nemr Ahmed,Aboughaly Rawan M.,El Sikaily Amany,Masoud Mamdouh S.,Ramadan Mohamed S.,Ragab Safaa 한국탄소학회 2022 Carbon Letters Vol.32 No.1
Sugarcane bagasse has been used as a substrate for the development of microporous nano-activated carbons for the treatment and elimination of dissolved materials from aquatic environment. The activated carbon was produced using chemical activation in one-step method with zinc chloride (ZnCl2) as the activating agent at a carbonization temperatures range from 500 to 900 °C. The effects of temperature and time of carbonization on the activated carbon product properties were thoroughly studied. The activated carbons that resulted were characterized using the N2 adsorption/desorption isotherms, Brunauer–Emmett–Teller method (BET), pore property analysis, micropore (MP) surface area, t-plot surface area, TGA, FTIR, SEM, TEM, and EDX analyses. The prepared activated carbon's point of zero charge, Boehm titration process, iodine removal percentage, and methylene blue number were also investigated. The prepared activated carbon's maximum surface area was achieved using a 2/1 impregnation ratio (dried sugarcane bagasse/ZnCl2) at 600 °C temperature of carbonization and 60 min residence time. 1402.2 m2/g, 0.6214 and 1.41 cm3/g, respectively, were the largest surface area, total pore volume, and micropore volume. As the activation temperature increased, the total pore volume increased and the BET study measured a pore diameter of 0.7 nm and a mean pore diameter of 1.77 nm.
Nagi M. El-Shafai,Mohamed E. El-Khouly,Maged El-Kemary,Mohamed S. Ramadan,Aly S. Derbalah,Mamdouh S. Masoud 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.69 No.-
Graphene oxide–titanium dioxide (GO@TiO2) nanocomposite with mean diameter size of 14 nm has been fabricated, characterized, and used as photocatalyst for degradation of two highly toxic insecticides, namely carbaryl and imidacloprid. Characterizations of GO@TiO2 have been carried out using various analytical and spectroscopic techniques. Compared to TiO2NPs, the fabricated GO@TiO2 nanocomposite has advantage of its smaller band gap. The finding that the photocatalytic degradation of the examined insecticides by the fabricated GO@TiO2 is more efficient compared to that of TiO2NPs suggests the superiority for using the fabricated GO@TiO2 nanocomposite for degradation of the examined toxic insecticides.
Amany GM Shoaib,El Nemr Ahmed,El Sikaily Amany,Masoud Mamdouh S.,Ramadan Mohamed S. 한국탄소학회 2022 Carbon Letters Vol.32 No.2
By polymerizing acrylonitrile in the presence of ammonium persulfate as an initiator and Pterocladia capillacea-activated carbon (P-AC) as a filler, a composite material polyacrylonitrile/Pterocladia capillacea-activated carbon (PAN/P- AC) was developed. By reacting hydroxylamine with the composite's nitrile groups, the prepared composite was functionalized by amidoximation. FTIR spectrometry, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and Brunauer–Emmett–Teller (BET) analysis were all applied to thoroughly characterize the fabricated adsorbent. For the treatment of Cr(VI) ions from synthetic solutions, the adsorption properties of amidoximated polyacrylonitrile/Pterocladia capillacea-activated carbon (PAO/P-AC) were investigated. The pH effect, uptake kinetics, adsorption isotherms, and thermodynamics studies were used to characterize adsorption properties. As a kinetic model analysis, the data confirmed that the pseudo-second-order rate equation matched well the adsorption process. With coefficients of determination (R2) of 0.9998, the Tempkin isotherm model had the lowest error, suggesting that it is the best fitted model to describe this adsorption mechanism. Thermodynamic parameters demonstrated that Cr(VI) adsorption was endothermic.