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RISS 인기검색어
- 검색키워드
- 저자 : El Nemr Ahmed (검색결과 6 건)
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El Nemr Ahmed,Amany GM Shoaib,El Sikaily Amany,Ragab Safaa,Mohamed Alaa El-Deen A.,Hassan Asaad F. 한국탄소학회 2022 Carbon Letters Vol.32 No.1
The production of macroalgae-derived adsorbent is of great importance to realize the idea of treating pollutants with invaluable renewable materials. Herein, a novel meso-micro porous nano-activated carbon was prepared from green alga Ulava lactuca in a facile way via chemical activation with zinc chloride. The resultant activated carbon possesses a significant specific surface area 1486.3 m2/g. The resulting activated carbon was characterized and investigated for the adsorption of Direct Red 23 (DR23) dye from an aqueous environment. Batch method was conducted to study the effects of different adsorption processes on the DR23 dye adsorption from water. Isotherms and kinetics models were investigated for the adsorption process of DR23 dye. It was found that the adsorption data were well fitted by Langmuir model showing a monolayer adsorption capacity 149.26 mg/g. Kinetic experiments revealed that the adsorptions of DR23 dye can be described with pseudo-second-order model showing a good correlation (R2 > 0.997). The prepared activated carbon from Ulava lactuca was exposed to a total of six regeneration experiments. The regeneration result proved that the fabricated activated carbon only loses 19% of its adsorption capacity after six cycles. These results clearly demonstrated the high ability of the obtained active carbon to absorb anionic dyes from the aqueous environment.
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El Nemr Ahmed,Aboughaly Rawan M.,El Sikaily Amany,Masoud Mamdouh S.,Ramadan Mohamed S.,Ragab Safaa 한국탄소학회 2022 Carbon Letters Vol.32 No.1
Sugarcane bagasse has been used as a substrate for the development of microporous nano-activated carbons for the treatment and elimination of dissolved materials from aquatic environment. The activated carbon was produced using chemical activation in one-step method with zinc chloride (ZnCl2) as the activating agent at a carbonization temperatures range from 500 to 900 °C. The effects of temperature and time of carbonization on the activated carbon product properties were thoroughly studied. The activated carbons that resulted were characterized using the N2 adsorption/desorption isotherms, Brunauer–Emmett–Teller method (BET), pore property analysis, micropore (MP) surface area, t-plot surface area, TGA, FTIR, SEM, TEM, and EDX analyses. The prepared activated carbon's point of zero charge, Boehm titration process, iodine removal percentage, and methylene blue number were also investigated. The prepared activated carbon's maximum surface area was achieved using a 2/1 impregnation ratio (dried sugarcane bagasse/ZnCl2) at 600 °C temperature of carbonization and 60 min residence time. 1402.2 m2/g, 0.6214 and 1.41 cm3/g, respectively, were the largest surface area, total pore volume, and micropore volume. As the activation temperature increased, the total pore volume increased and the BET study measured a pore diameter of 0.7 nm and a mean pore diameter of 1.77 nm.
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Serag Eman,El-Maghraby Azza,El Nemr Ahmed 한국탄소학회 2022 Carbon Letters Vol.32 No.2
The implanted electronic devices require a stable, continuous, and long-lasting energy source to function correctly. These devices are powered by alkaline batteries and lithium ions. When used in implantable or wearable devices, these batteries can pose a threat to human health and the environment. Because of these factors, implantable and wearable devices using enzyme biofuel cells (EBFCs) are receiving a lot of attention. These EBFCs use human physiological fluid to provide long-term control for these devices. Carbon nanomaterials have successfully been demonstrated in enzymatic biofuel cells to improve applications by increasing current and power density; they have the potential to enhance EBFC efficiency. This review summarizes the fundamental process of EBFC compounds based on carbon nanomaterials before delving into the most recent advancements that have been tested and used as implantable and wearable self-power sources.
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Amany GM Shoaib,El Nemr Ahmed,El Sikaily Amany,Masoud Mamdouh S.,Ramadan Mohamed S. 한국탄소학회 2022 Carbon Letters Vol.32 No.2
By polymerizing acrylonitrile in the presence of ammonium persulfate as an initiator and Pterocladia capillacea-activated carbon (P-AC) as a filler, a composite material polyacrylonitrile/Pterocladia capillacea-activated carbon (PAN/P- AC) was developed. By reacting hydroxylamine with the composite's nitrile groups, the prepared composite was functionalized by amidoximation. FTIR spectrometry, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and Brunauer–Emmett–Teller (BET) analysis were all applied to thoroughly characterize the fabricated adsorbent. For the treatment of Cr(VI) ions from synthetic solutions, the adsorption properties of amidoximated polyacrylonitrile/Pterocladia capillacea-activated carbon (PAO/P-AC) were investigated. The pH effect, uptake kinetics, adsorption isotherms, and thermodynamics studies were used to characterize adsorption properties. As a kinetic model analysis, the data confirmed that the pseudo-second-order rate equation matched well the adsorption process. With coefficients of determination (R2) of 0.9998, the Tempkin isotherm model had the lowest error, suggesting that it is the best fitted model to describe this adsorption mechanism. Thermodynamic parameters demonstrated that Cr(VI) adsorption was endothermic.
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Stromal Modulation and its Role in the Diagnosis of Papillary Patterned Thyroid Lesions
Daoud, Sahar Aly,Esmail, Reham Shehab El Nemr,Hareedy, Amal Ahmed,Khalil, Abdullah Asian Pacific Journal of Cancer Prevention 2015 Asian Pacific journal of cancer prevention Vol.16 No.8
The papillary patterned lesion of thyroid may be challenging with many diagnostic pitfalls. Tumor stroma plays an important part in the determination of the tumor phenotype. CD34 is thought to be involved in the modulation of cell adhesion and signal transduction as CD34(+) fibrocytes are potent antigen-presenting cells. Smooth muscle actin (SMA) positivity could be diagnostic for fibroblast activation during tumorigenesis. We aimed to examine the expression of CD34 and alphaSMA in the stroma of papillary thyroid hyperplasia, papillary thyroid carcinoma and papillary tumors of uncertain malignant potential in order to elucidate their possible differential distribution and roles. A total number of 54 cases with papillary thyroid lesions were studied by routine H&E staining, CD34 and ASMA immunostaining. ASMA was not expressed in benign papillary hyperplastic lesions while it was expressed in papillary carcinoma, indicating that tumors have modulated stroma. Although the stroma was not well developed in papillary lesions with equivocal features of uncertain potentiality, CD34 was notable in such cases with higher incidence in malignant cases. So ASMA as well as CD34 could predict neoplastic behavior, pointing to the importance of the stromal role. Differences between groups suggest that the presence of CD34 + stromal cells is an early event in carcinogensis and is associated with neoplasia, however ASMA+ cells are more likely to be associated with malignant behavior and metastatic potential adding additional tools to the light microscopic picture helping in diagnosis of problematic cases with H&E.
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