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Feifei Shen,Meihong Wang,Lingxiang Huang,Feng Qian 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.93 No.-
In chemical industry, most processes face the challenge of high energy consumption. The approachpresented in this study can reduce the energy footprint and increase efficiency. The energy system of aseparation process in ethylene manufacturing is used to demonstrate the effectiveness of the approach. The chilling train system of the separation process in a typical ethylene plant consumes most cooling andprovides appropriate feed for distillation columns. The steady state simulation of system was presentedand the simulation results were proved accurate. The conventional exergy analysis identifies thatDephlegmator No.1 (a heat exchange and mass transfer device) has the highest exergy destruction(1401.28 kW). Based on advanced exergy analysis, Dephlegmator No.1 has the highest rate of avoidableexergy destruction (89.04 %). Finally, a multi-objective optimisation aiming to maximise system exergyefficiency and to minimise operational cost was performed and the Pareto frontier was obtained. Themulti-objective optimized exergy efficiency is 79.53 % (improved by 0.61 %) and the operational cost is0.02031 yuan/kg (saved by 11.19 %). This study will guide future research to reduce energy consumptionin process manufacturing.
Steering Coacervation by a Pair of Broad-Spectrum Regulators
Yang, Shenyu,Li, Bo,Wu, Chunxian,Xu, Weiwei,Tu, Mei,Yan, Yun,Huang, Jianbin,Drechsler, Markus,Granick, Steve,Jiang, Lingxiang American Chemical Society 2019 ACS NANO Vol.13 No.2
<P>Coacervation is liquid-liquid phase separation ubiquitous in industrial applications and cellular biology. Inspired by cellular manipulation of coacervate droplets such as P granules, we report here a regulatory strategy to manipulate synthetic coacervation in a spatiotemporally controllable manner. Two oppositely charged small molecules are shown to phase separate into coacervate droplets in water as a result of electrostatic attraction, hydrophobic effect, and entropy. We identify a down regulator, β-cyclodextrin, to disrupt the hydrophobic effect, thus dissolving the droplets, and an up regulator, amylase, to decompose β-cyclodextrin, thus restoring the droplets. The regulation kinetics is followed in real time on a single-droplet level, revealing diffusion-limited dissolution and reaction-limited condensation, respectively, taking ∼4 s and 2-3 min. Versatility of this strategy to manipulate the coacervation is demonstrated in two aspects: spatially distributed coacervation in virtue of amylase-grafted hydrogel frameworks and coacervate transportation across membranes and hydrogel networks <I>via</I> a disassemble-to-pass strategy. The current regulatory pairs and strategies are anticipated to be general for a wide variety of synthetic self-assembly systems.</P> [FIG OMISSION]</BR>