전로제강 슬래그(BOF-Slag)를 이용한 고온탈황에 관한 연구

오광중,정덕영,최성원,조상원,손병현 釜山大學校生産技術硏究所 1996 生産技術硏究所論文集 Vol.51 No.-

고온 석탄연료가스의 탈황에 BOF-Slag의 이용가능성을 실험해 보았다. BOR-Slag의 온도, 유량, 탈황제의 특성등이 H₂S 제거효율에 미치는 영향을 조사해 본 결과, 최적의 H₂S 제거효율은 700℃에서 이루어졌고 입자크기가 작을수록 황포집능은 향상되었으나 0.214-0.631mm에서는 큰 영향이 발견되지 않았다. 조업온도 800℃이상에서는 탈황제의 응집으로 내부물질전달저항이 증가하여 탈황제의 반응성이 저하되었다. Experiments have been made to test the practical feasibility of using BOF-Slag to desulfurize hot coal-derived fuel gas. In this study, the effects of particle size, temperature, flow rate and sorbent characteristics on the H₂S removal efficiency of BOF-Slag were investigated. Experimental results showed that the removal efficiency of H₂S was optimum when the temperature was about 700℃ and the smaller sample size, the better sorbent capacity had and the sample size in the range of 0.214∼0.631mm didn't influence. When the temperature was above 800℃, the reactivity of sorbent has lowered because agglomeration of sorbent increased intraparticle transport resistance.

광합성세균 미생물막반응기에 의한 유기성폐수의 처리특성

오광근,이철우,전영중,이재홍 한국미생물생명공학회 ( 구 한국산업미생물학회 ) 1996 한국미생물·생명공학회지 Vol.24 No.6

홍색비유황 광합성세균인 Rhodopseudomonas capsulata를 선택하여 porous ceramic bead를 충진시킨 충진형 반응기(Packed-bed reactor, PBR)와 분말활성탄을 현탁시킨 유동산 반응기(Fluidized-bed reactor, FBR)에서 미생물막을 형성하여 폐수처리를 비교한 결과 PBR이 FBR보다 BOD 부하량 변화에 더 안정적인 처리성을 보였다. 체류시간 (hydraulic retention time, HRT)에 따른 처리성은 유입폐수 농도를 각각 BOD 10,000, 20,000 mg/ℓ로 하였을 때, HRT 1일 이상에서 90% 이상의 처리효율을 가지며, 유출수의 BOD 농도는 각각 350, 800 mg/ℓ이었다. PBR에서 유입수의 BOD 농도변화에 다른 유출수의 농도를 측정하여 단위부피당 기질부하량 상수 (maximum specific BOD loading rate, P) 및 부착미생물 포화기질 제한농도 상수(half saturation constant, K_6)를 구한 결과, 각각 22.2 gBOD/ℓ·day, 1,750 mgBOD/ℓ이었고, 처리효율 90% 이상을 나타내는 BOD 용적부하(volumetric BOD loading rate)는 20 gBOD/ℓ·day 이상으로 표준활성오니법의 0.6 gBOD/ℓ·day에 비하여 30배가 넘는 값을 나타내었다. An efficient packed-bed type biofilm reactor charged with immobilized phototrophs was developed to treat organic wastewater at an extremely high volumetric loading rate. The packed bed reactor (PBR) charged with porous ceramic beads was superior to a fluidized-bed reactor suspended with activated carbon powders in terms of many aspects such as BOD removal efficiency, operational stability, and overall economics. For wastewater with BOD concentration as high as 20,000 mg/l, the BOD removal efficiency was maintained above 90% when the hydraulic retention time (HRT) was longer than 1 day. The allowable volumetric BOD loading rate of this reactor (20gBOD/l·day) is more than ten-folds higher than that of an ordinary activated sludge method. The behaviour of the reactor was represented well by a Monod type kinetic equation with a maximum specific BOD loading rate(P) of 22.2gBOD/l·day and a half saturation constant(K_s) of 1,750 mgBOD/l.

광합성세균에 의한 미생물막의 형성

오광근,이철우,전영중,이재홍 한국미생물생명공학회 ( 구 한국산업미생물학회 ) 1996 한국미생물·생명공학회지 Vol.24 No.6

홍색비유황 광합성세균인 Rhodopseudomonas capsulata를 선택하여 packed-bed reactor에서 미생물막을 형성할 때, porous ceramic bead가 다른 담체에 비해 우수하였고, 일정한 유입농도하에서 체류시간(hydraulic retention tiem, HRT)이 짧을수록 미생물막 형성이 양호하였으며, 그 때 반응기내의 세포농도는 11,400mg/l로 현탁처리시의 세포농도에 비하여 3~8배 증가하였다. PBR에서 미생물막의 형성은 cell attachment, microcolony formation, biofilm formation의 단계를 거쳐 형성되는 것으로 관찰되었으며, PBR이 FBR보다 안정적인 미생물 부착을 보였고 특히 PBR에서는 BOD용적 부하가 15gBOD/ℓ·day 이상이 되어도 미생물막의 부착비율은 90% 이상을 유지하였다. 전자현미경으로 담체의 표면 및 내부에 고정화된 광합성세균을 확인할 수 있었다. The formation of microbial films(biofilm) by a non-sulfur phototrophic bacteria, Rhodopseudomonas capsulata, on inorganic media was studied. Porous ceramic beads(PCB) were superior to other immobilizing media for the biofilm formation in a packed-bed reactor. It was found that the formation of microbial films favored a lower hydraulic retention time, showing a higher ratio of cells attatched to the media to those suspended in the solution. The cell concentration in the biofilm reactor was as high as 11,400 mg/ℓ, which is 8-folds of the cell concentration in a ordinary suspended treatment. It was observed that the formation of microbial film by R. capsulata followed a general serial process of cell attachment, microcolony formation, and biofilm formation. The microbial films thus formed was very stable even for an extremely high volumetric BOD loading rate of 15 gBOD/ℓ·day. The scanning electron micrographs of the microbial films showed that the cells were attached to both the surface and pores of the media.

유동층을 이용한 탈황제의 마모특성에 관한 연구

오광중,김형국,최은화,조기철 부산대학교 환경문제연구소 1999 環境硏究報 Vol.17 No.1

For the efficient energy use and the protection of environmental pollution, attrition characteristics, depending on the component and the condition of sorbent for the purification of fuel gas, were analyzed by a fluidized-bed tester. Results of these studies can be summarized follows. 1) When Mn-based sorbent(M, MT, MFT) prepared with varying addictives and induration conditions was compared in terms of particle size distribution and AI(Attrition Index), MT and MFT possessing TiO2 and Fe203 had much higher attrition resistance than M. Attrition resistance of M, MT and MFT increased as bentonite contents and induration temperature increased, when bentonite contents induration temperature were changed from 2 to 5% and from 1000 to 1100℃, respectively. Therefore when powdery catalysts are prepared, the attrition rate can be considerably affected by the controls of addictive, binder and induration temperature. 2) Attrition tests using MT1100-5 were performed under the conditions that particle size distribution was uniform and had much more over +270mesh and under -325mesh. AI due to attrition was 8.83, 21.54 and 1.67%, respectively. Thus, initial particle size distribution showed a great influence on both produced fines distribution and attrition loss. Therefore, the size distribution of particles injected initially and the particle size that carried over showed be considered to reduce the loss of particulate materials and the replacement cost due to attrition. 3) An experiment using MT1100-5 sorbent was also carried out to predict AI as a function of time and particle size distribution during 23hr. AI of prepared sorbent was 4.54, 7.73, 9.08, 11.35 and 12.48 after 1.5, 3, 5, 9 and 23hr. respectively. Thus, it was shown that the amount of produced fines during the same time was shorten with the increase of time. The operating condition of dust capturing equipment and the rate of powder exchange needs to be considered because most of the fines due to fluidization of particulate material was generated at initial operation.

CXTFIT기법을 이용한 오염토양의 중금속 이동특성에 관한 연구

오광중,김효진,박창웅,오방일 부산대학교 환경문제연구소 2002 環境硏究報 Vol.20 No.-

The sorption and transport characteristics of Cd and Pb is founded by changing of soil concentration and velocity of injected Cd and Pb solution. The results of batch-type experiment indicated that sorption capacity of Pb was stronger than sorption capacity of Cd. Batch-type experiment indicated that the results of Cd and Pb adsorption experiment fitted in the Freundlich isotherm equation well and were highly nonlinear. Results from column experiment showed the retention of the transport of heavy metals at low concentration, low velocity and high pH in soil of different characteristics. The BTCs of the heavy metals were analysed by using a two-site model, and transport parameters were derived by using the CXTFIT curve-fitting program. The model results indicated that the partitoning coefficient(β), forward rate coefficient(Ks) and backward rate coefficient(kd) were in proportion to the concentration, velocity and pH.

[논문]비소로 오염된 토양의 고형화에 관한 연구

오방일,노경환,조기철,정영헌,오광중 부산대학교 환경문제연구소 2004 環境硏究報 Vol.22 No.-

A Study on the Solidification of Soi1 Contaminated by Arsenite

제강 전로 Slag 복토재의 중금속 흡착 특성 연구

손병현,조용말,오광중,정종현 부산대학교 환경문제연구소 1995 環境硏究報 Vol.13 No.-

It has been known that blast furnace slag has abilities to remove heavy metal ions like Cd??,Cr??, and Cr?? in wastewaters and leachate. However the removal efficiency by basic oxygen furnace process slag has not been reported. The removal chcracteristics of heavy metals on BOF-Slag were investigated to develop the landfill leachate attenuation process by the slag cover soil. Specific surface area and pore volume of the BOF-Slag were in the range of 20.27-41.43㎡/g and was increased with decreasing of the particle size. The removal rates of Cr??, Zn??, and Pb?? were affected by reaction temerature, slag particle size, and pH of various heavy metal solution but the effect of temperature was negligible. Freundlich isotherm data indicated that BOF-Slag provided better sorptive for Cr??, Zn??, and Pb?? than BF-Slag did. These results were utilized in developing suggestions for the disposal of industrial waste sludges and dusts in sanitary landfills and for the use of BOF-Slag cover soil.

부산·경남지역의 토양오염물질간의 상관도에 관한 연구

주유연,조상원,오광중,손병현 부산대학교 환경문제연구소 1994 環境硏究報 Vol.12 No.-

It appeared over all regions expect common life area that the pollutants level of soil heavy metals in Pusan and kyoung-Nam Province, was higher than the standard on in agriculture area. Especially, Atmosphere and waste area appeared much high and it necessitates monitoring these areas continually. Where we analyzed pollutants level of heavy metals in paddy soils in correspondence with Pusan, Ulsan, and Yangsan region, the order of Pb and Cd concentration were Yangsan 〉 Pusan 〉 Ulsan, the order of Cu and Zn were Yangsan 〉 Ulsan 〉 Pusan, the order of Hg and As were Ulsan 〉 Yangsan 〉 Pusan respectively. It appeared the whole concentration of heavy metals expect Hg and As were the highest ones in Yangsan. So, it was thought that special management should be needed. The analysis of correlation between heavy metals in soil showed that the correlation level between Cd and Pb, Cu and Pb and Zn, Hg and As was high in agricultural area and the correlation level between Zn and Pb, Cd and Hg, Cd and Cu was high but the one between Cd and As was low in atmosphere area. And the correlation between Pb and Cd, Hg and Zn, Hg and Cu was high but the one between Hg and Cu was low in waste area and the correlation level between As and Pb, As and Zn was slightly high but the one between Cd and Cu is low in water area.

음식물 쓰레기 퇴비화 공정시 발생하는 악취가스중 CH₃CHO 제거에 대한 연구

황재동,정덕영,오광중 부산대학교 환경문제연구소 1997 環境硏究報 Vol.15 No.1

Pseudomonas sp. TPP 63을 이용한 PVA 폐수의 생물학적처리에 관한 연구

김영식,조상원,오광중,임주원 부산대학교 환경문제연구소 1994 環境硏究報 Vol.12 No.-

The purpose of this study is increasing the microbiological treatment efficiency of PVA wastewater using selected bacteria. The bacteria which showed high decomposition rate of PVA was separated as TPP 63 bacteria decomposing PVA of 91.3% when the bacteria have cultured at 0.5% PVA minimum culture medium for 5 days. This bacteria was identified as Pseudomonas putida. It showed a maximum decomposition rate of PVA at culture temperature of 37℃ and pH 7.5-7.8. In case 0.2% PVA wastewater was treated with this culture of 3500 mg/L MLSS, the efficiency was improved with increasing HRT. At HRT of 5 days and 0.4% PVA concentration, the treatment efficiency was dropped down more seriously when the culture medium was not supplied.