Cathode Materials LaNi1−xCuxO3 for Low Temperature Solid Oxide Fuel Cells

Juncai Sun,Chengli Wang,Song Li,Shijun Ji 한국세라믹학회 2008 한국세라믹학회지 Vol.45 No.12

New cathode materials LaNi1−xCuxO3 (typically LaNi0.8Cu0.2O3) were synthesized using a co-precipitation method. The structure and morphology of the powders were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The composite material [Ce0.8Sm0.2O2-ä(SDC) and carbonate (Na2CO3,Li2CO3)], NiO and LaNi1−xCuxO3 were used as the electrolyte, anode and cathode, respectively. The electrochemical performance of La-Ni-Cu-O perovskite oxide at low temperatures (400~550oC) was studied. The results showed that LaNi0.8Cu0.2O3 precursor powder prepared through a co-precipitation method and calcined at 860oC for 2 h formed uniform grains with diameters in the range of 400~500 nm. The maximum power density and the short circuit current density of the single cell unit at 550oC were found to be 390 mW/cm2 and 968 mA/cm2, respectively. New cathode materials LaNi1−xCuxO3 (typically LaNi0.8Cu0.2O3) were synthesized using a co-precipitation method. The structure and morphology of the powders were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The composite material [Ce0.8Sm0.2O2-ä(SDC) and carbonate (Na2CO3,Li2CO3)], NiO and LaNi1−xCuxO3 were used as the electrolyte, anode and cathode, respectively. The electrochemical performance of La-Ni-Cu-O perovskite oxide at low temperatures (400~550oC) was studied. The results showed that LaNi0.8Cu0.2O3 precursor powder prepared through a co-precipitation method and calcined at 860oC for 2 h formed uniform grains with diameters in the range of 400~500 nm. The maximum power density and the short circuit current density of the single cell unit at 550oC were found to be 390 mW/cm2 and 968 mA/cm2, respectively.

An Innovative Training Program on Engineering Education

Juncai Sun,Song Li,Shijun Ji 한국공학교육학회 2014 공학교육연구 Vol.17 No.4

From 2010, an “excellent engineer” undergraduate and graduate program had been initiated in higher education of China to promote thedevelopment of industry and social economy. In this circumstance, the engineering education programs in Dalian Maritime Universityare reformed to satisfy the requirements of transportation industries. And the engineering practice, engineering activities, and engineeringcourses are emphasized. In this training program, industrial communities are deeply involved in the engineering education and trainingprocedure; the students are educated and trained in university and enterprise according to the common standards and industrial standards;and the engineering competences and creative ability are emphasized and are to be enhanced in the training schedules and procedure. A joint-training mode has been established already between Dalian Maritime University and enterprises in transportation fields.

Cathode Materials LaNi_1−xCu_xO₃ for Low Temperature Solid Oxide Fuel Cells

Sun, Juncai,Wang, Chengli,Li, Song,Ji, Shijun The Korean Ceramic Society 2008 한국세라믹학회지 Vol.45 No.12

New cathode materials $LaNi_{1-x}{Cu_x}{O_3}$ (typically $LaNi_{0.8}Cu_{0.2}O_3$) were synthesized using a co-precipitation method. The structure and morphology of the powders were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The composite material [$Ce_{0.8}Sm_{0.2}O_{2-\ddot{a}}$(SDC) and carbonate (${Na_2}{CO_3},{Li_2}{CO_3}$)], NiO and $LaNi_{1-x}{Cu_x}{O_3}$ were used as the electrolyte, anode and cathode, respectively. The electrochemical performance of La-Ni-Cu-O perovskite oxide at low temperatures ($400{\sim}550^{\circ}C$) was studied. The results showed that $LaNi_{0.8}Cu_{0.2}O_3$ precursor powder prepared through a co-precipitation method and calcined at $860^{\circ}C$ for 2 h formed uniform grains with diameters in the range of $400{\sim}500\;nm$. The maximum power density and the short circuit current density of the single cell unit at $550^{\circ}C$ were found to be $390\;mW/cm^2$ and $968\;mA/cm^2$, respectively.

An Innovative Training Program on Engineering Education

Sun, Juncai,Li, Song,Ji, Shijun Korean Society for Engineering Education 2014 공학교육연구 Vol.17 No.4

From 2010, an "excellent engineer" undergraduate and graduate program had been initiated in higher education of China to promote the development of industry and social economy. In this circumstance, the engineering education programs in Dalian Maritime University are reformed to satisfy the requirements of transportation industries. And the engineering practice, engineering activities, and engineering courses are emphasized. In this training program, industrial communities are deeply involved in the engineering education and training procedure; the students are educated and trained in university and enterprise according to the common standards and industrial standards; and the engineering competences and creative ability are emphasized and are to be enhanced in the training schedules and procedure. A joint-training mode has been established already between Dalian Maritime University and enterprises in transportation fields.

Effect of porosity gradient in cathode gas diffusion layer on electrochemical performance of proton exchange membrane fuel cells

Yang Guogang,Wang Hao,Su Fengmin,Li Shian,Zhang Guoling,Sun Juncai,Shen Qiuwan,Jiang Ziheng,Liao Jiadong,Chen Pengyu 한국화학공학회 2023 Korean Journal of Chemical Engineering Vol.40 No.7

Proton exchange nembrane fuel cells (PEMFCs) are highly promising energy devices for future transportation and distributed power stations. The electrochemical performance of PEMFCs assembled with gas diffusion layer (GDL) of different porosity gradient distributions has been analyzed using the lattice Boltzmann method. A single-phase multi-component lattice Boltzmann model employing the active approach was developed to investigate the reactive gas flow within the GDL. Two types of GDLs with the same porosity, namely multilayer porosity gradient GDLs and linear porosity gradient GDLs, were generated to investigate the effect of the porosity gradient of the GDL on the electrochemical performance of PEMFC. The results show that the two types of porosity gradient GDL improve oxygen starvation problems and enhance water management, and that the GDLs with smaller porosity gradients can increase the mean current density. This paper develops the study of pore-scale analysis of PEMFC performance and can provide guidance for the design of GDL structures.

Model Test and Numerical Simulation Study on Bearing Characteristics of Pervious Concrete Pile Composite Foundation

Jun Cai,Guangyin Du,Han Xia,Changshen Sun 대한토목학회 2021 KSCE JOURNAL OF CIVIL ENGINEERING Vol.25 No.10

When pervious concrete is used as pile material, both high strength and water permeability will be available. By comparing the strength and permeability of pervious concrete with different aggregate size (3 − 5 mm and 4 − 6 mm) and porosity (20%, 25%, 30% and 35%), the recommended aggregate size (3 − 5 mm) and porosity (30%) can be achieved. To investigate the installation effect and bearing characteristics of the pervious concrete pile composite foundation, the excess pore water pressure, settlement, pile-soil stress ratio and skin friction were recorded in the model test. Results show that, compared with the impervious pile, the pervious pile can significantly accelerate the dissipation of excess pore water pressure after pile installation, and in the loading test can shorten the consolidation time by 30.3%, increase the skin friction 0.12 kPa averagely, reduce the peak value of excess pore water pressure by 30.2%, and increase the characteristic value of bearing capacity by 43.2%. When the linear penalty method is applied, and the friction coefficient is 0.6, compared with the test, the deviation of simulated skin friction is the largest, being about 15%, so in general the model test results are reliable.