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        Grenville-age orogenic event along the northeastern margin of the Quanji massif, NW China: constraints from ~1.1 Ga migmatite

        Zhouxuan Xiao,Licheng Ma,Wan Jiang,Ran Wang,Yuyan Yao,Jie Cai,Jingyu Lin,Lu Li 한국지질과학협의회 2020 Geosciences Journal Vol.24 No.3

        Detailed petrologic, geochemical and geochronological investigation on migmatites provide key information on the tectonic-magmatic history of the Quanji Massif, NW China. The studied migmatites are mainly composed of granitic gneisses, with lenticular refractory residua spread along its foliation. Zircon U-Pb ages of 1129.2 ± 7.4 Ma (1σ, MSWD = 0.34, N = 31) and 1135.1 ± 9.5 Ma (1σ, MSWD = 0.05, N = 22) were determined for the granitic gneiss and refractory residue, respectively. Garnet grains from the refractory residue show no distinctive intra-crystalline zonation, and are rich in Fe and Mg, but poor in Ca and Mn, akin to those from metapelite. Samples from the granitic gneisses have high contents of SiO2 (from 67.92% to 69.89%), K2O (from 3.94% to 5.00%) and A/CNK (1.11–1.17), with LREE enrichment and distinctly negative Eu anomalies (Eu/Eu* = 0.49–0.53) in the chondrite-normalized REE patterns, and significantly negative Nb, Ta, Ti and Sr anomalies in the primitive mantle-normalized spider diagrams. Granitic gneisses samples have consistent Nd isotope compositions with negative εNd(t) values ranging from –1.06 to –6.04, and TDM model ages ranging from 1.83 to 2.23 Ga. These geochemical features suggest that the granitic rocks belong to the S-type granites, which were predominately derived from a late Paleoproterozoic crustal source. The granitic gneiss was probably formed by partial melting of the sediments which had been suffered graunlite-facies metamorphism. The components with low melting points (e.g., felsic minerals) might replace the sediments to form migmatites and migmatitic granites, and thus preserved the refractory residua. Therefore, the late Mesoproterozoic orogenic event is the coeval response of the global Grenvillian orogeny, indicating an important crustal remelting episode in the Quanji Massif.

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        Evaluation on direct aqueous carbonation of industrial/mining solid wastes for CO2 mineralization

        Zijian Li,Jie Chen,Zongze Lv,Yichao Tong,Jingyu Ran,Changlei Qin 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.122 No.-

        Carbonation of industrial alkaline resources can achieve dual effects of CO2 sequestration and solid wastemanagement, and the carbonated product may act as a potential cementitious backfill material. Based onthis idea, CO2 mineralization characteristics and potential of typical industrial solid wastes, mine tailingsand their mixtures are investigated by direct aqueous carbonation, and effects of reaction parameters,including particle size, reaction temperature, solid-to-liquid ratio, CO2 concentration, are systematicallyexplored. Results show that industrial solid wastes with a high Ca content such as carbide slag have bettercarbonation activity with the maximum CO2 sequestration capacity of 544.6 g-CO2/kg, while the carbonationof mine tailings is very weak. The combination of coal fly ash with tailings has a potentialstimulative effect during carbonation. Moreover, influences of carbonation parameters are revealed inthis study, and optimal reaction parameters are determined to be particle size below 75 lm, temperatureof 60 C, solid-to-liquid ratio of 100 g/L, and CO2 concentration of 15% within mild range. These resultscan provide fundamental knowledge for the integrated CO2 mineralization and goaf backfilling, andaccelerate carbon reduction and waste resource utilization.

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