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        Magnetic Anisotropies in Cobalt-Nickel Ferrites (NixCo1-xFe2O4)

        Binghai Liu,Jun Ding,Jiabao Yi,Jianhua Yin,Zhili Dong 한국물리학회 2008 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.52 No.5

        This work presents a detailed study on the various magnetic anisotropies of NixCo1..xFe2O4 prepared by using a mechanochemical process. The results indicated that the magnetic anisotropy of NixCo1..xFe2O4 was strongly correlated with the Co2+ concentration. The Ni2+ substitution readily led to a decrease in the magnetocrystalline anisotropy and coercivity. While a large uniaxial anisotropy was induced in CoFe2O4 by magneto-annealing, the uniaxial anisotropy decreased with the Ni concentration in NixCo1..xFe2O4 and disappeared in the pure NiFe2O4. A short-time mechanical milling was found to signicantly increase the coercivity in NixCo1..xFe2O4 samples and high coercivities of 5.1 kOe and 2.8 kOe were achieved in the CoFe2O4 and the Ni0:5Co0:5Fe2O4 samples respectively. The microstructure and magnetic studies indicated that the milling-induced high coercivity could be ascribed to milling-induced stress anisotropy and to the pinning eects of defects. This work presents a detailed study on the various magnetic anisotropies of NixCo1..xFe2O4 prepared by using a mechanochemical process. The results indicated that the magnetic anisotropy of NixCo1..xFe2O4 was strongly correlated with the Co2+ concentration. The Ni2+ substitution readily led to a decrease in the magnetocrystalline anisotropy and coercivity. While a large uniaxial anisotropy was induced in CoFe2O4 by magneto-annealing, the uniaxial anisotropy decreased with the Ni concentration in NixCo1..xFe2O4 and disappeared in the pure NiFe2O4. A short-time mechanical milling was found to signicantly increase the coercivity in NixCo1..xFe2O4 samples and high coercivities of 5.1 kOe and 2.8 kOe were achieved in the CoFe2O4 and the Ni0:5Co0:5Fe2O4 samples respectively. The microstructure and magnetic studies indicated that the milling-induced high coercivity could be ascribed to milling-induced stress anisotropy and to the pinning eects of defects.

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