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A. Sanz-Martínez,J. Lasobras,J. Soler,J. Herguido,M. Menéndez 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.113 No.-
Methanol to Gasoline (MTG) process transforms methanol to hydrocarbons within the boiling point rangeof gasoline. The result is a wide spectrum of products (olefins, paraffins, aromatics and naphthenics,among others), with the total conversion of methanol to hydrocarbons and water. Catalyst deactivationby coke is a main problem in this process. This work aims to determine the feasibility of carrying out theproduction of gasoline from methanol in a two-zone fluidized bed reactor (TZFBR). The hypothesis is thatthe formation of carbonaceous deposits (coke) on the catalyst particles can be counteracted by its combustionin the regeneration zone that this novel reactor presents, thus achieving stable and continuousoperation. In this way, both processes (reaction and regeneration) would be being carried out simultaneouslyin the same reactor (process intensification). The comparison of results between a conventional fluidizedbed reactor and a TZFBR shows that the second one actually provides a better stability over time.
Synthesis, morphology and electrochemical applications of iron oxide based nanocomposites
Letti, Camila J.,Costa, Karla A.G.,Gross, Marcos A.,Paterno, Leonardo G.,Pereira-da-Silva, Marcelo A.,Morais, Paulo C.,Soler, Maria A.G. Techno-Press 2017 Advances in nano research Vol.5 No.3
The development of hybrid systems comprising nanoparticles and polymers is an opening pathway for engineering nanocomposites exhibiting outstanding mechanical, optical, electrical, and magnetic properties. Among inorganic counterpart, iron oxide nanoparticles (IONP) exhibit high magnetization, controllable surface chemistry, spintronic properties, and biological compatibility. These characteristics enable them as a platform for biomedical applications and building blocks for bottom-up approaches, such as the layer-by-layer (LbL). In this regard, the present study is addressed to investigate IONP synthesised through co-precipitation route (average diameter around 7 nm), with either positive or negative surface charges, LbL assembled with sodium sulfonated polystyrene (PSS) or polyaniline (PANI). The surface and internal morphologies, and electrochemical properties of these nanocomposites were probed with atomic force microscopy, UV-vis and Raman spectroscopy, scanning electron microscopy, cross-sectional transmission electron microscopy, and electrochemical measurements. The nanocomposites display a globular morphology with IONP densely packed while surface dressed by polyelectrolytes. The investigation of the effect of thermal annealing (300 up to $600^{\circ}C$) on the oxidation process of IONP assembled with PSS was performed using Raman spectroscopy. Our findings showed that PSS protects IONP from oxidation/phase transformation to hematite up to $400^{\circ}C$. The electrochemical performance of nanocomposite comprising IONP and PANI were investigated in $0.5mol{\times}L^{-1}$ $Na_2SO_4$ electrolyte solution by cyclic voltammetry and chronopotentiometry. Our findings indicate this structure as promising candidate for potential application as electrodes for supercapacitors.
Lower Airway Microbiota and Lung Cancer
Sanchez-Hellin, Victoria,Galiana, Antonio,Zamora-Molina, Lucia,Soler-Sempere, Maria J.,Grau-Delgado, Justo,Barbera, Victor M.,Padilla-Navas, Isabel,Garcia-Pachon, Eduardo The Korean Society for Microbiology and Biotechnol 2019 한국미생물·생명공학회지 Vol.47 No.3
This study was aimed at identifying the lower airway microbiota in patients with lung cancer (LC) using protected brush sampling. We enrolled 37 patients undergoing diagnostic bronchoscopy for suspected LC, 26 with LC and 11 with benign diseases. Protected brush specimens were obtained from the contralateral lung and the side of the tumor; these specimens were analyzed by 16S rRNA-based-next-generation sequencing. The results indicated that the biodiversity was not different between groups, and there were no significant differences between the proportion of microorganisms in the tumor and in the contralateral side of patients with LC. In patients with LC, there was a higher abundance of several microorganisms including Capnocytophaga, Haemophilus, Enterococcus, and Streptococcus; whereas, in individuals without LC, Bacteroides, Lactobacillus, or Methylobacterium were more abundant. Malignancy could be determined with an accuracy of 70% by isolating Enterococcus, Capnocytophaga, or Actinomyces. Microbispora indicated benignity with a sensitivity of 55%, specificity of 88%, and accuracy of 78%. Lower airway microbiota in patients with LC is fairly similar in both the tumor and contralateral sites. Endobronchial microbiota is different in patients with and without LC, and these differences may have a potential clinical value as diagnostic or prognostic biomarkers.
Lower Airway Microbiota and Lung Cancer
( Victoria Sanchez-hellin ),( Antonio Galiana ),( Lucia Zamora-molina ),( Maria J. Soler-sempere ),( Justo Grau-delgado ),( Victor M. Barbera ),( Isabel Padilla-navas ),( Eduardo Garcia-pachon ) 한국미생물생명공학회(구 한국산업미생물학회) 2019 한국미생물·생명공학회지 Vol.47 No.3
This study was aimed at identifying the lower airway microbiota in patients with lung cancer (LC) using protected brush sampling. We enrolled 37 patients undergoing diagnostic bronchoscopy for suspected LC, 26 with LC and 11 with benign diseases. Protected brush specimens were obtained from the contralateral lung and the side of the tumor; these specimens were analyzed by 16S rRNA-based-next-generation sequencing. The results indicated that the biodiversity was not different between groups, and there were no significant differences between the proportion of microorganisms in the tumor and in the contralateral side of patients with LC. In patients with LC, there was a higher abundance of several microorganisms including Capnocytophaga, Haemophilus, Enterococcus, and Streptococcus; whereas, in individuals without LC, Bacteroides, Lactobacillus, or Methylobacterium were more abundant. Malignancy could be determined with an accuracy of 70% by isolating Enterococcus, Capnocytophaga, or Actinomyces. Microbispora indicated benignity with a sensitivity of 55%, specificity of 88%, and accuracy of 78%. Lower airway microbiota in patients with LC is fairly similar in both the tumor and contralateral sites. Endobronchial microbiota is different in patients with and without LC, and these differences may have a potential clinical value as diagnostic or prognostic biomarkers.
Solar Science with the Atacama Large Millimeter/Submillimeter Array-A New View of Our Sun
Wedemeyer, S.,Bastian, T.,Brajš,a, R.,Hudson, H.,Fleishman, G.,Loukitcheva, M.,Fleck, B.,Kontar, E. P.,De Pontieu, B.,Yagoubov, P.,Tiwari, S. K.,Soler, R.,Black, J. H.,Antolin, P.,Scullion, E.,Gu Springer-Verlag 2016 Space science reviews Vol.200 No.1
<P>The Atacama Large Millimeter/submillimeter Array (ALMA) is a new powerful tool for observing the Sun at high spatial, temporal, and spectral resolution. These capabilities can address a broad range of fundamental scientific questions in solar physics. The radiation observed by ALMA originates mostly from the chromosphere-a complex and dynamic region between the photosphere and corona, which plays a crucial role in the transport of energy and matter and, ultimately, the heating of the outer layers of the solar atmosphere. Based on first solar test observations, strategies for regular solar campaigns are currently being developed. State-of-the-art numerical simulations of the solar atmosphere and modeling of instrumental effects can help constrain and optimize future observing modes for ALMA. Here we present a short technical description of ALMA and an overview of past efforts and future possibilities for solar observations at submillimeter and millimeter wavelengths. In addition, selected numerical simulations and observations at other wavelengths demonstrate ALMA's scientific potential for studying the Sun for a large range of science cases.</P>