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Chunyun Hou,Jiangwei Yu,Jin-Rui Ding,Weiqiang Fan,Hongye Bai,Dongbo Xu,Wei-dong Shi 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.104 No.-
The unsatisfactory solar light absorption of WO3 and poor charge separation of BiVO4 are main limits fortheir use in photoelectrochemical (PEC) water oxidation. Coupling WO3 with BiVO4 has been consideredas a feasible way to improve PEC performance by taking complementary advantages of them. In thiswork, we obtained nanoflake-structured WO3 by hydrothermal growth with post-annealing. The effectof process variables on morphology and resultant performance were investigated. Electrodepositiongrowth was utilized to deposit BiVO4 onto WO3 forming WO3/BiVO4 heterojunction thin films. PorousBiVO4 with wormlike morphology was tightly coupled and well-distributed onto WO3 nanoflakes. Theoptimized best-performing WO3/BiVO4 photoanode exhibits higher photocurrent density than that summationof bare WO3 and BiVO4 over entire range of applied potential. This enhancement is mainly attributedto the effective charge separation at WO3/BiVO4 interface, which is confirmed throughelectrochemical impedance spectra (EIS) measurements, respectively. Our work provides a referableapproach for the growth of WO3/BiVO4 heterojunction photoanode with enhanced PEC performance.