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      • Enhancement of the thermoelectric performance of bulk SnTe alloys via the synergistic effect of band structure modification and chemical bond softening

        Wang, Hongchao,Hwang, Junphil,Zhang, Chao,Wang, Teng,Su, Wenbin,Kim, Hoon,Kim, Jungwon,Zhai, Jinze,Wang, Xue,Park, Hwanjoo,Kim, Woochul,Wang, Chunlei Royal Society of Chemistry 2017 Journal of Materials Chemistry A Vol.5 No.27

        <P>SnTe alloys, which have the same crystal structure as PbTe, have attracted increasing attention. Here, we demonstrate that the synergistic effect of band structure modification and chemical bond softening can be realized simultaneously in In & Mn doped SnTe bulk alloys. The Seebeck coefficient and power factor are synergistically improved by co-doping of In and Mn. In doping is known to introduce a resonance level. Mn doping reduces the separation of light- and heavy-valence bands. The combination of these effects significantly enhances the Seebeck coefficient at room temperature owing to around a factor of five times increase in the band effective mass. The reduction of thermal conductivity is from the decrease of both the electronic and phononic parts. The electronic thermal conductivity is decreased by the increase in defect scattering, as can be confirmed by the carrier mobility. The force constant of the bonds around the Te site is decreased due to the co-doping of In & Mn, which indicates that the chemical bonds are softened, which leads to low sound velocity and lower lattice thermal conductivity. As a result, the peak thermoelectric figure of merit,<I>zT</I>= 1.03 has been achieved for Sn0.89In0.01Mn0.1Te at 923 K. This strategy of using the synergistic effect of band structure modification and chemical bond softening could be applicable to other thermoelectric materials.</P>

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        Experimental study on U-shape flat thermosyphon for thermal management of power battery

        Tao Wang,Sicong Tan,Cong Guo,Hongchao Su,Chaohong Guo,Yuyan Jiang 대한기계학회 2021 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.35 No.9

        The paper presents a new type of U-shape flat thermosyphon. The thermosyphon has several unique properties relative to general heat pipe such as compact and simple structure (no wick structure), easily to filling the coolant and flexible plate structure and so on. These properties make it an ideal heat transfer device for battery pack thermal management. In this paper, we experimentally study the thermal management performance of the U-shape flat thermosyphon for a battery module. The temperature of the battery module can be controlled below 50 °C under 1.5 C charge rate (300 W), and below 37 °C under 1 C charge rate (120 W), and the corresponding maximum temperature difference is 3 °C and 7 °C, respectively. And higher power generation is helpful to start-up the U-shape flat thermosyphonand maintain a small temperature difference between different battery cells. The performance of the U-shape flat thermosyphonis evaluated using a thermal resistance network model, which showed that there is uneven distribution of heat transfer in the two side of the heat pipe.

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