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        Melt-crystallization monitoring system for the purification of 10 kg-scale LiCl salt waste

        Choi, Jung-Hoon,Lee, Tae-Kyo,Lee, Ki-Rak,Han, Seung-Youb,Cho, Yung-Zun,Kim, Na-Young,Jang, Seon-Ah,Park, Hwan-Seo,Hur, Jin-Mok Elsevier 2018 Nuclear engineering and design Vol.326 No.-

        <P><B>Abstract</B></P> <P>Salt waste treatment process in the pyrochemical process is under development to separate or concentrate fission products from the LiCl salt waste and to minimize waste volume by recycling the purified LiCl salt into the electrochemical process. In particular, the Cs nuclide in the LiCl salt waste is difficult to separate by chemical method, so that melt-crystallization method has been employed and engineering-scale melt-crystallization system capable of 20 kg/batch treatment has been designed and installed at the PyRoprocess Inactive integrated Demonstration (PRIDE) facility. In this study, in order to evaluate scaled-up design of melt-crystallization process, the preliminary crystallization test was conducted with 10 kg LiCl salt waste having surrogate Cs, Sr, and Ba nuclides. In consideration of temperature gradients generated inside the crystallization vessel owing to the scale-up, melt-crystallization monitoring system was developed. Using the monitoring system, we could obtain purified LiCl crystal with uniform distribution of quantity on 6 crystallization plates and high separation efficiency of over 90% at various cooling conditions.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Engineering scale melt-crystallization monitoring system has been developed. </LI> <LI> Surrogate LiCl salt waste was used for the melt-crystallization test. </LI> <LI> Monitoring system was developed to prevent the formation of over-growing. </LI> <LI> High nuclide separation efficiency was obtained using monitoring system. </LI> </UL> </P>

      • KCI등재

        Recent Progress in Waste Treatment Technology for Pyroprocessing at KAERI

        Geun-Il Park,Min Ku Jeon,Jung-Hoon Choi,Ki-Rak Lee,Seung Youb Han,In Tae Kim,Yung-Zun Cho,Hwan-Seo Park 한국방사성폐기물학회 2019 방사성폐기물학회지 Vol.17 No.3

        사용후핵연료의 효율적 관리를 위하여 한국원자력연구원에서 수행 중인 파이로 공정으로부터 발생되는 폐기물 처리기술에 대한 최근 연구동향을 종합적으로 고찰하였다. 파이로 폐기물 처리기술은 처분 대상 폐기물의 감용 및 포장, 저장과 최종 처분에 적합한 고화체 제조를 목표로 하고 있다. 한국원자력연구원에서 수행 중인 파이로 폐기물 처리 기술개발 접근 방향은 공정 흐름으로부터 발생한 폐기물내 주요 핵종들을 분리하고 회수한 물질 등을 재사용함으로서 폐기물 발생량을 최소로 하며 동시에 분리한 핵종을 별도로 고화처리하는 것이다. 폐기물 처리 주요 기술 특성은 먼저 전해환원용 원료물질 제조를 위하여 전처리 고온 열처리 공정을 사용하며, LiCl 과 LiCl-KCl 염으로부터 핵종을 분리하고 회수염의 재사용 및 핵종 함유량을 증대시킨 최종 고화체 제조 기술을 개발하는 것이다. 따라서 실험실 규모 실험 결과를 토대로 최근에는 공정 용량 증대를 위한 자료 확보를 목적으로 공학규모 시험을 수행 중에 있다. This study comprehensively addresses recent progress at KAERI in waste treatment technology to cope with waste produced by pyroprocessing, which is used to effectively manage spent fuel. The goal of pyroprocessing waste treatment is to reduce final waste volume, fabricate durable waste forms suitable for disposal, and ensure safe packaging and storage. KAERI employs grouping of fission products recovered from process streams and immobilizes them in separate waste forms, resulting in product recycling and waste volume minimization. Novel aspects of KAERI approach include high temperature treatment of spent oxide fuel for the fabrication of feed materials for the oxide reduction process, and fission product concentration or separation from LiCl or LiCl-KCl salt streams for salt recycling and higher fission-product loading in the final waste form. Based on laboratory-scale tests, an engineering-scale process test is in progress to obtain information on the performance of scale-up processes at KAERI.

      • KCI등재

        반복겹침접합압연법에 의해 강소성가공된 무산소동의 미세조직 및 기계적 특성

        이성희,조준,한승전,임차용,Lee Seong-Hee,Cho Jun,Han Seung-Zun,Lim Cha-Yong 한국재료학회 2005 한국재료학회지 Vol.15 No.4

        An oxygen free copper was severely deformed by accumulative roll-bonding (ARB) process for improvement of its mechanical properties. Two copper sheets 1 m thick, 30 mm wide and 300 m long are first degreased and wire-brushed for sound bonding. The sheets are then stacked to each other, and roll-bonded by about $50\%$ reduction rolling without lubrication at ambient temperature. The bonded sheet is then cut to the two pieces of same dimensions and the same procedure was repeated to the sheets up to eight cycles $(\varepsilon-6.4)$. TEM observation revealed that ultrafine grains were developed after the third cycle, and their size was slightly increased at higher cycles. Tensile strength of the copper increased with the strain at low strain levels, but it hardly increased from 3 cycles $(\varepsilon>2.4)$ due to occurrence of dynamic recovery, even if the imposed strain increased.

      • KCI등재

        ARB법에 의해 강소성가공된 무산소동의 어닐링 특성

        이성희,조준,이충효,한승전,임차용,Lee Seong-Hee,Cho Jun,Lee Chung-Hyo,Han Seung-Zun,Lim Cha-Yong 한국재료학회 2005 한국재료학회지 Vol.15 No.9

        An oxygen free copper severely-deformed by eight cycles (an equivalent strain of $\~6.4$) of accumulative roll-bonding (ARB) was annealed at various temperatures ranging from 100 to $300^{\circ}C$. The annealed copper was characterized by transmission electron microscopy (TEM) and tensile & hardness test. TEM observation revealed that the ultrafine grains developed by the ARB still remained up to $150^{\circ}C$, however above $200^{\circ}C$ they were replaced by equiaxed and coarse grains due to an occurrence of the static recrystallization. Tensile strength and hardness of the copper decreased slightly with the annealing temperature up to $150^{\circ}C$, however they dropped largely above $200^{\circ}C$. Annealing characteristics of the copper were compared with those of a commercially pure aluminum processed by ARB and subsequently annealed.

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