http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Yu Juxin,Ma Li,Duan Tigang,Xin Yonglei,Lv Yanzhuo,Zhang Haibing 한국탄소학회 2022 Carbon Letters Vol.32 No.2
One-step hydrothermal reduction method was used to prepare three-dimensional carbon fiber brush-based graphene–platinum (CFB/Pt–G) composites to improve the electrocatalytic oxygen reduction activity of cathode materials for seawater oxygen-dissolved battery. Characterization results show that the reduced graphene oxide of as-prepared graphene–platinum composite displays the few-layer folded structure. In addition, Pt nanoparticles with the polycrystalline structure dispplay a preferential growth along the crystal plane of (111) and are mainly distributed around the defect cavities of folded graphene. Electrochemical results show that the diffusion-limited current density of CFB/Pt–G composite tested with 1600 rpm/min in 3.5% NaCl solution reaches 5 mA/cm2, while that of CFB/G is only 2.64 mA/cm2. Battery discharge results show that the maximum volume power density of CFB/Pt–G–Mg battery with a stable open voltage of 1.73 V is 81 times as much as the commercial seawater battery SWB1200.
Pan, Yu,Wang, Wenjun,Zhu, Yuhan,Xu, Haibing,Noh, Hyeon Mi,Jeong, Jung Hyun,Liu, Xiaoguang,Li, Ling Elsevier 2018 CERAMICS INTERNATIONAL Vol.44 No.7
<P><B>Abstract</B></P> <P>Eu-doped MAlSi<SUB>2</SUB>O<SUB>6</SUB> (M = Li, Na, K, Rb, Cs) phosphors were synthesized by solid-state reaction in air. The crystal structure and optical properties of the phosphors were investigated by X-ray powder diffraction and photoluminescence. Their emission spectra are composed of some broad bands coming from the 5d-4f transition of Eu<SUP>2+</SUP> and some sharp emission peaks coming from the f-f transitions of Eu<SUP>3+</SUP>. The co-existence of Eu<SUP>3+</SUP> and Eu<SUP>2+</SUP> cations is detected in MAlSi<SUB>2</SUB>O<SUB>6</SUB>:2%Eu, which shows that the unusual Eu<SUP>3+</SUP>→Eu<SUP>2+</SUP> reduction process occurs in MAlSi<SUB>2</SUB>O<SUB>6</SUB>. The preferential occupancy of Eu<SUP>3+</SUP> or Eu<SUP>2+</SUP> in MAlSi<SUB>2</SUB>O<SUB>6</SUB> can be calculated to be M<SUP>+</SUP> sites by the bond-energy method. The deviation of the Eu<SUP>3+</SUP>–O<SUP>2-</SUP> bond energy is closed to that of the Eu<SUP>2+</SUP>–O<SUP>2-</SUP> bond energy, which means that Eu<SUP>3+</SUP> and Eu<SUP>2+</SUP> can coexist in air. The abnormal reduction of Eu<SUP>3+</SUP> to Eu<SUP>2+</SUP> can be explained by charge compensation model. The doped Eu<SUP>3+</SUP> was induced to M<SUP>+</SUP> and the vacancy (<I>V</I> <SUB> <I>M</I> </SUB>) may be formed. The vacancy(<I>V</I> <SUB> <I>M</I> </SUB>) acted as a donor of electrons, and the Eu M ∙ ∙ defect acted as an acceptor of electrons. The theoretical result is consistent with the experimental phenomenon.</P>
Simultaneous Impact of Multiple Droplets on Liquid Film
Gangtao Liang,Tianyu Zhang,Haibing Yu,Hongliang Chen,Shengqiang Shen 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.65 No.-
Multiple droplets impinging on a thin liquid film simultaneously is numerically studied using a three-dimensional model with an implement of a random disturbance subjected to Gaussian distribution. This model is very effective to predict droplet splashing under relatively high impingement momentum. Interface evolutions and field distributions are addressed after droplets impact. Besides, a geometric model is built up to demarcate the impact region into two semicircular regions and a series of rectangular regions during simultaneous impact, further to discuss the variations of area and residual film thickness in each region as well as the total area and average film thickness.
Yaping Sheng,Qigu Huang,Haibing Huang,Mengshan Yu,Xinli Zhang,Lu Cheng,Zhi Liu,Wei Liu,Jianjun Yi,Wantai Yang 한국공업화학회 2014 Journal of Industrial and Engineering Chemistry Vol.20 No.2
The copolymerization of MMA with ethylene was promoted by metallocene complex in the presence ofinitiator tetra(2,3-epoxy propoxy)silane (Is), reducing agent Zn and cocatalyst MAO, combining freeradical polymerization with coordination polymerization via sequential monomer addition strategy inone-pot to produce 4-arms hydroxy-functionalized PMMA-b-PE. The effects of polymerizationconditions such as temperature, time, ethylene pressure and Al/Ti molar ratio on the polymerizationperformance were investigated. 4-Arms hydroxy-functionalized PMMA-b-PE was obtained by solventextraction and determined by GPC, MALLS, DSC, FT-IR, WAXD and 1H(13C) NMR. The DSC result indicatedthat the 4-arms hydroxy-functionalized PMMA-b-PE had one Tg at 87.0 ℃ and one Tm at 117.0 ℃ whichattributed to Tg of PMMA segment and Tm of PE segment, respectively. The microstructure of 4-armshydroxy-functionalized PMMA-b-PE was further confirmed by WAXD, FT-IR, and 13C NMR analysis. These results demonstrated that the obtained 4-arms block copolymer consisted of PMMA segment andcrystalline PE segment.