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Asaad. F. Hassan,Laila M. Alshandoudi,Aya M. Awad,Ahmed A. Mustafa,Ghada Esmail 한국고분자학회 2023 Macromolecular Research Vol.31 No.7
In the current study, a novel nanomaterial called nanomagnetite/copper oxide/potassium carrageenan nanocomposite (MKCO) was fabricated to include Fenton (nanomagnetite, NM) and Fenton-like reagent (copper oxide nanoparticles, NCO) in a matrix of potassium carrageenan biopolymer. The prepared solid materials were characterized by different physicochemical techniques, such as TGA, N2 adsorption/desorption, SEM, TEM, XRD, DRS, pHPZC, and FTIR. The prepared MKCO showed unique properties like higher specific surface area of 652.50 m2/g, pore radius of 1.19 nm, pHPZC equals 7.80, and the presence of different surface chemical functional groups. Under various application conditions, comparative experiments between Safranin-O dye (SO) adsorption and Photo-Fenton catalytic degradation were conducted. After 24 h, MKCO had a maximum adsorption capacity of 384.61 mg/g at 42 °C, while the Photo-Fenton oxidation process took only 10 min to totally decompose 93% of SO at 21 °C. Based on the higher values of correlation coefficients, Langmuir’s adsorption model is the best-fitted adsorption model for SO onto all the prepared solid materials. Studies on SO adsorption’s kinetics and thermodynamics show that it is physisorption and that it operates according to endothermic, spontaneous, and PFO model processes. While, PFO, endothermic, and non-spontaneous processes are satisfied by the catalytic decomposition of SO. After five application cycles, MKCO demonstrated good catalyst reusability with a 3.4% decrease in degrading efficiency. For lower contaminant concentrations and shorter application times, Photo-Fenton catalytic degradation of organic pollutants is more effective than adsorption.
El Nemr Ahmed,Amany GM Shoaib,El Sikaily Amany,Ragab Safaa,Mohamed Alaa El-Deen A.,Hassan Asaad F. 한국탄소학회 2022 Carbon Letters Vol.32 No.1
The production of macroalgae-derived adsorbent is of great importance to realize the idea of treating pollutants with invaluable renewable materials. Herein, a novel meso-micro porous nano-activated carbon was prepared from green alga Ulava lactuca in a facile way via chemical activation with zinc chloride. The resultant activated carbon possesses a significant specific surface area 1486.3 m2/g. The resulting activated carbon was characterized and investigated for the adsorption of Direct Red 23 (DR23) dye from an aqueous environment. Batch method was conducted to study the effects of different adsorption processes on the DR23 dye adsorption from water. Isotherms and kinetics models were investigated for the adsorption process of DR23 dye. It was found that the adsorption data were well fitted by Langmuir model showing a monolayer adsorption capacity 149.26 mg/g. Kinetic experiments revealed that the adsorptions of DR23 dye can be described with pseudo-second-order model showing a good correlation (R2 > 0.997). The prepared activated carbon from Ulava lactuca was exposed to a total of six regeneration experiments. The regeneration result proved that the fabricated activated carbon only loses 19% of its adsorption capacity after six cycles. These results clearly demonstrated the high ability of the obtained active carbon to absorb anionic dyes from the aqueous environment.