http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Highly efficient adsorption of arsenite from aqueous by zirconia modified activated carbon
Pham Ngoc Chuc,Nguyen Quang Bac,Dao Thi Phuong Thao,Nguyen Trung Kien,Nguyen Thi Ha Chi,Nguyen Van Noi,Vo Thang Nguyen,Nguyen Thi Hong Bich,Dao Ngoc Nhiem,Dinh Quang Khieu 대한환경공학회 2024 Environmental Engineering Research Vol.29 No.2
Nguyen Van Hung,Bui Thi Minh Nguyet,Nguyen Huu Nghi,Nguyen Minh Luon,Nguyen Ngoc Bich,Le Van Thanh Son,Nguyen Trung Kien,Dao Ngoc Nhiem,Nguyen Thanh Tuoi,Dinh Quang Khieu 대한환경공학회 2024 Environmental Engineering Research Vol.29 No.4
In the present work, ZnO/g-C₃N₄/biochar was prepared, and it was used for visible-light driven photocatalytic degradation of some colorants (methylene blue, rhodamine B, methyl orange) and some antibiotics (doxycycline, ciprofloxacin, amoxicilline). Biochar was prepared by pyrolysing Phragmites australis biomass. The ZnO/g-C₃N₄/biochar composite was synthesized with the alkaline hydrolysis method. The obtained materials were characterized by X-ray diffraction, scanning electron microscopy, transition electron microscopy, energy dispersive X-ray/elemental mapping, ultraviolet-visible-diffuse reflectance spectroscopy, photoluminescence spectroscopy, nitrogen adsorption/desorption isotherms and X-ray photoelectron spectroscopy. The results show that ZnO nanoparticles with a large surface area are highly dispersed on the g-C₃N₄ particle surface and biochar. The composite exhibits superior photocatalytic degradation ability toward doxycycline, a broad-spectrum antibiotic of the tetracycline compared with individual components (ZnO or g-C₃N₄) and satisfies stability after six treatment cycles. The kinetics and degradation mechanisms of doxycyline were also addressed. In addition, the present catalyst also exhibits the photocatalytic degradation of methylene blue, rhodamine B, methyl orange, ciprofloxacin and amoxicillin in visible-light regions.
Nguyen Van Hung,Bui Thi Minh Nguyet,Nguyen Huu Nghi,Nguyen Mau Thanh,Nguyen Duc Vu Quyen,Vo Thang Nguyen,Dao Ngoc Nhiem,Dinh Quang Khieu 대한환경공학회 2023 Environmental Engineering Research Vol.28 No.3
In this study, longan seeds - an agricultural by-product was used to fabricate activated carbon (LSAC) through two-step pyrolysis with pre-carbonization at low temperature in the first step and then activation by H3PO4. LSAC with large surface area and porous structure exhibits an excellent capacity of absorption towards both cationic dyes (methylene blue (MB), rhodamine-B (RhB)) and anionic dyes (methyl orange (MO), congo red (CR)). Experimental data can be described well by the pseudo-second kinetic model. The maximum adsorption capacity based on Langmuir isotherm model was found as 502.84; 397.77; 464.66 and 350.64 mg.g−1 for MB, RhB, MO and CR, respectively. The adsorption of MB, RhB and CR on LSAC is spontaneous and endothermic, while that for MO is spontaneous but exothermic. Furthermore, the adsorption mechanism of dyes on LSAC was also studied showing that it can occur by electrostatic interaction, hydrogen bonding, the filling of pores involving the interaction between dye ions with specific functional groups such as –OH, –COOH, –NH2 and –PO43− on the LSAC surface. These results suggest that LSAC material may be envisaged as a promising adsorbent for treatment of wastewater in textile industries.