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        Cost-Effective Fabrication of Biomorphic Mesoporous Ni-NiO Microtube for Pseudocapacitors

        Binbin Chang,Hang Yin,Zhengyan Gu,Zhikun Li,Baocheng Yang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2016 NANO Vol.11 No.11

        In this paper, a biomorphic mesoporous Ni-NiO microtube was successfully prepared by a facile and cost-effective synthesis strategy using cotton as a biotemplate. The morphology and textural characterization of as-obtained Ni-NiO materials were analyzed by X-ray diffraction patterns, scanning electron microscopy and nitrogen adsorption–desorption technology. The results suggested the as-prepared Ni-NiO samples owned uniform micro-tubular morphology and prominent mesoporous structure. Meanwhile, the effect of annealing temperature on morphology and porosity of Ni-NiO was also investigated. The optimal sample, Ni-NiO-4, exhibited a uniform microtube morphology with an ideal mesoporous structure of a high surface area (15.8 m2 g-1) and suitable mesopore size (9.28 nm). Furthermore, these as-obtained Ni-NiO materials showed enhanced electrochemical property as electrodes for pseudocapacitors. Especially, the Ni-NiO-4 electrode displayed the outstanding capacitive performance, including a high specific capacitance of 98.7 F g-1 at 0.5 A g-1 and satisfactory rate capacity. More importantly, Ni-NiO-4 electrode owned an excellently long-term cycling stability.

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        Numerical investigation of two-phase flow characteristics in multiphase pump with split vane impellers

        Yi Shi,Hongwu Zhu,Binbin Yin,Ruiting Xu,Jiate Zhang 대한기계학회 2019 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.33 No.4

        Multiphase pump is a cost-effective option for subsea oil and gas field development. The ability to handle different inlet gas volume fractions (GVFs) especially high inlet GVF is critical to the development of pump performance. In this study, the two-phase flow characteristics in normal impeller and split vane impeller at different inlet GVFs were investigated by steady numerical simulations. The gas distribution on blade-to-blade plane and meridional flow channel at different inlet GVFs were analyzed and compared. Gas accumulation area and movement characteristics of the gas-liquid flow in impeller flow passage were also pointed out by unsteady simulations. Experimental results of the pump differential pressure were compared with the numerical simulation results, to validate the accuracy of numerical simulation method. The flow characteristics in pump with modified impeller and its performance at different inlet GVFs were both compared with that of the normal impeller. The steady simulation results of normal impeller in different inlet GVFs show that gas concentrating area in the flow passage increases as inlet GVF grows. The unsteady simulation results indicate that gas pocket firstly occurs on the pressure side of impeller, then moves to the suction side in the middle area of blade and finally transfers to outlet of impeller and disappears. The errors between numerical simulation results and experiment data are below 10 %, which validated the feasibility of the numerical simulation method. Simulation results on the split vane impeller demonstrate that the gas accumulation area in flow passage of the modified impeller is dramatically decreased compared to that of the normal impeller. The performance of the modified impeller is generally better than the normal impeller especially in high inlet GVF conditions.

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