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Mxene structure: A key parameter in corrosion barrier performance of organic coatings
Ziyang Zhou,Sepideh Pourhashem,Zhengquan Wang,Jiawen Sun,Xiaohong Ji,Xiaofan Zhai,Jizhou Duan,Baorong Hou 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.116 No.-
In this research, the effects of fresh and oxidized MXene on the surface, adhesion, and corrosion-resistantproperties of waterborne epoxy coatings are considered. The oxidized MXene is prepared through storageof fresh MXene nanosheets in an open vial for 1 month. The results confirm that the waterborne epoxycoating loaded with silane functionalized fresh MXene nanosheets (epoxy/F-MXene) has significantlyhigher barrier performance and anti-corrosion behavior than the sample modified with silane functionalizedoxidized MXene nanosheets (epoxy/F-O-MXene). Indeed, the F-MXene nanosheets (with defectfreeand large two dimensional morphology) are able to effectively inhibit the path of corrosive mediaas well as increment the epoxy matrix compactness compared to the F-O-MXene (with broken nanosheetmorphology composed of TiO2 nanoparticles) due to rapid oxidation of the MXene nanosheets in theenvironment. Besides, the epoxy/F-MXene nanocomposite coating has slightly higher water contact angleand adhesion strength to the metallic substrate compared to the epoxy/F-O-MXene. The results of thisresearch clearly reveal the importance of preventing MXene oxidation before application as nanofillerin the polymer coatings.
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Frequency Regulation Strategy for AC–DC System During Black Start
Chengjun Xia,Jiazheng Xie,Haiwen Lan,Baorong Zhou,Zhaobin Du 대한전기학회 2020 Journal of Electrical Engineering & Technology Vol.15 No.1
High-voltage direct current (HVDC) can speed up the recovery of a power system. However, both rectifer and inverter sides of HVDC are weak systems during a black start. To coordinate frequency characteristics of both sides within the frequency deviation constrain, a frequency regulation strategy for AC–DC system during a black start is proposed. First, the mathematical models of asynchronous interconnected AC–DC system are established, and the optimal HVDC transmission power leading to minimum frequency deviation of both sides is obtained based on the linear quadratic optimal control method. To adapt to the continuously changing parameters and confgurations of the AC power system during a black start, a Narendra adaptive tracking control method is developed to obtain the control law of the target value of governor, which allows the actual system frequency follow the reference system frequency under the optimal HVDC transmission power. Finally, the simulation model is established using PSCAD/EMTDC software to verify the proposed strategy
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