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      • KCI등재

        Effect of calcination and reaction conditions on the catalytic performance of Co–Ni/Al2O3 catalyst for CO hydrogenation

        Akbar Zare,Mehdi Shiva,Ahad Zare,Ali Akbar Mirzaei 한국공업화학회 2013 Journal of Industrial and Engineering Chemistry Vol.19 No.6

        The Co–Ni/Al2O3 catalysts prepared using impregnation procedure, were used for the Fischer–Tropsch synthesis. The effect of calcination conditions of the catalyst as well as reactor situation was studied. It was found that the catalyst calcined at 550 8C for 6 h in air atmosphere has shown the best catalytic performance for CO hydrogenation. The best operational conditions were obtained as following:T = 350 8C, P = 1 atm and H2/CO = 2/1.

      • KCI우수등재

        Effects of extrusion of rice bran on performance and phosphorous bioavailability in broiler chickens

        Zare-Sheibani, Ali Akbar,Arab, Masoud,Zamiri, Mohammad Javad,Rezvani, Mohammad Reza,Dadpasand, Mohammad,Ahmadi, Farhad Korean Society of Animal Science and Technology 2015 한국축산학회지 Vol.57 No.7

        Background: Rice bran is a by-product of the rice-milling process, which remains largely underutilized; however, efficient processing treatments may improve its feeding value for chickens. This is of great economic and environmental importance, as this can lower the production costs, and offer an opportunity for valorization of a low-quality agricultural by-product, to a high-value feed source. Methods: This experiment was conducted to study the effect of extruded rice bran on performance and phosphorous (P) bioavailability in broiler chickens. In a completely randomized design, 200 seven-day-old broilers (Cobb 500) were allotted to five treatments with five replicates per treatment and 8 chicks per replicate, and fed with their respective diet during the starter (8 to 21 days) and grower (22 to 42 days) periods. Diets were a basal corn-soybean based diet (T1), or diets containing 20 % rice bran (T2), 30 % rice bran (T3), 20 % extruded rice bran (T4), or 30 % extruded rice bran (T5). Results: Birds feeding on T4 and T5 diets had a higher body weight gain and lower feed-to-gain ratio compared to those feeding on T2 and T3 diets (p < 0.05). Birds receiving diets containing extruded rice bran had higher total P availability and tibia ash content, as compared with those receiving diets containing un-extruded rice bran (p < 0.05). Relative weight of the pancreas was higher in birds receiving T2 and T3 diets. Conclusions: The results confirmed the beneficial effect of extrusion treatment of rice bran on performance and P availability in broilers. Up to 30 % extruded rice bran may be included in the broiler diet without apparent adverse effects on the performance.

      • KCI등재

        RESEARCH : Open Access ; Effects of extrusion of rice bran on performance and phosphorous bioavailability in broiler chickens

        ( Ali Akbar Zare Sheibani ),( Masoud Arab ),( Mohammad Javad Zamiri ),( Mohammad Reza Rezvani ),( Mohammad Dadpasand ),( Farhad Ahmadi ) 한국동물자원과학회(구 한국축산학회) 2015 한국축산학회지 Vol.57 No.26

        Background: Rice bran is a by-product of the rice-milling process, which remains largely underutilized; however, efficient processing treatments may improve its feeding value for chickens. This is of great economic and environmental importance, as this can lower the production costs, and offer an opportunity for valorization of a low-quality agricultural by-product, to a high-value feed source. Methods: This experiment was conducted to study the effect of extruded rice bran on performance and phosphorous (P) bioavailability in broiler chickens. In a completely randomized design, 200 seven-day-old broilers (Cobb 500) were allotted to five treatments with five replicates per treatment and 8 chicks per replicate, and fed with their respective diet during the starter (8 to 21 days) and grower (22 to 42 days) periods. Diets were a basal corn-soybean based diet (T1), or diets containing 20 % rice bran (T2), 30 % rice bran (T3), 20 % extruded rice bran (T4), or 30 % extruded rice bran (T5). Results: Birds feeding on T4 and T5 diets had a higher body weight gain and lower feed-to-gain ratio compared to those feeding on T2 and T3 diets (p < 0.05). Birds receiving diets containing extruded rice bran had higher total P availability and tibia ash content, as compared with those receiving diets containing un-extruded rice bran (p < 0.05). Relative weight of the pancreas was higher in birds receiving T2 and T3 diets. Conclusions: The results confirmed the beneficial effect of extrusion treatment of rice bran on performance and P availability in broilers. Up to 30 % extruded rice bran may be included in the broiler diet without apparent adverse effects on the performance.

      • KCI등재

        Development of a kinetic model for Fischer–Tropsch synthesis over Co/Ni/Al2O3 catalyst

        Farhad Fazlollahi,Majid Sarkari,Akbar Zare,Ali Akbar Mirzaei,Hossein Atashi 한국공업화학회 2012 Journal of Industrial and Engineering Chemistry Vol.18 No.4

        In the present research an active Co–Ni/Al2O3 catalyst was prepared by impregnation method for synthesis of light olefins in Fischer–Tropsch synthesis. After studying the effects of using optimized operating conditions on catalyst performance, the kinetic experimental study was performed in a differential micro-fixed-bed-reactor by altering reaction temperature (230–270 8C), pressure (2–12 bar),gas hourly space velocity (2000–7200 h-1) and H2/CO feed molar ratio (1–3). Based on Langmuir–Hinshelwood–Hougen–Watson (LHHW) approach, seven different two-parameter kinetic models were considered. The kinetic data of this study were fitted accurately by a simple form -rCO ¼APCOPH2 =ð1 þ bPCOP0:5H2Þ2 that assumed the following kinetically relevant steps, where CO dissociates via interaction with adsorbed hydrogen; the first hydrogenation step of the surface carbon was reversible and fast, while the second one was slow and rate determining. The kinetic parameters were determined using Levenberg–Marquardt (LM) method and the apparent activation energy and heat of adsorption were 78.70 kJ/mol and -14.16 kJ/mol, respectively.

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