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      • Anticorit Prelube oils for sheet metal forming

        A. LOSCH,F. KUBICKI 한국트라이볼로지학회 2004 한국트라이볼로지학회 학술대회 Vol.39 No.-

        The pressing of car body parts is one of the most important sheet metal drawing processes. The corrosion protection oil applied by the steel mills plays a part in every sheet metal forming operation and also makes up the largest proportion of lubricants used. The idea to combine the corrosion protection properties of a corrosion preventive oil with the lubricity of a drawing oil lead to the development of the Anticorit prelubes. Applied at the finishing lines of the steel mills, they finally serve as lubricant in the press shops. A prerequisite for the suitability of a prelube-type oil is the absolute compatibility with all single processes from the coil to the Body in White. The use of prelubes in steel mills reduces the number and quantity of spot lubricants for additional press shop oiling dramatically. But their true benefits can only be fully achieved if the compatibility principle is applied throughout the manufacturing chain. Therefore, modem prelubes systems are modular, even different viscosities can be part of the same concept. This results in a far-reaching multi-functionality of the Anticorit prelube system for all applications.

      • Unraveling Direct Formation of Hierarchical Zeolite Beta by Dynamic Light Scattering, Small Angle X-ray Scattering, and Liquid and Solid-State NMR: Insights at the Supramolecular Level

        Castro, Maria,Losch, Pit,Park, Woojin,Haouas, Mohamed,Taulelle, Francis,Loerbroks, Claudia,Brabants, Gert,Breynaert, Eric,Kirschhock, Christine E. A.,Ryoo, Ryong,Schmidt, Wolfgang American Chemical Society 2018 Chemistry of materials Vol.30 No.8

        <P>A case study on the understanding of the formation of hierarchical Beta zeolites using gemini-type piperidine based multiammonium surfactant (N<SUB>6</SUB>-diphe) is reported. Complementary techniques were used to investigate N<SUB>6</SUB>-diphe’s structure-directing effect at the molecular level. Combining characterization of the resulting zeolite materials with the toolboxes herein developed for studying clear solutions and dense gels discloses self-assembly processes that govern the growth (and growth inhibition) of nano-Beta zeolite crystals. In clear solution, small-angle X-ray scattering and liquid-state NMR provide insights about the formation of nanoparticles and their degree of order. <SUP>14</SUP>N and <SUP>1</SUP>H-DOSY NMR probe the dynamics and mobility of soluble species. In a dense gel, on the other side, <SUP>27</SUP>Al- and <SUP>29</SUP>Si-(MAS) NMR elucidate the varying local connectivity between initial nano-objects and the final solid products. It has been found that cylindrical micelles control the transformation of solubilized silica and alumina during the formation of zeolite nuclei and guide their crystal growth to nano-Beta rods with bimodal mesoporosity. The predominant smaller mesopores (6 to 8 nm) originate from the template’s hydrophobic alkyl chains, while larger mesopores (10 to 30 nm) are supposed to result from a spinodal decomposition-type segregation of phases consisting of as-formed hydrophobic zeolite rods and an aqueous solution.</P> [FIG OMISSION]</BR>

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        Ab-Initio Studies of Electronic and Spectroscopic Properties of MgO, ZnO and CdO

        A. Schleife,C. R¨odl,J. Furthmuller,F. Bechstedt,P. H. Jefferson,T. D. Veal,C. F. McConville,L. F. J. Piper,A. DeMasi,K. E. Smith,H. Losch,R. Goldhahn,C. Cobet,J. Zuniga-Perez,V. Munoz-Sanjose 한국물리학회 2008 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.53 No.5

        We present ab-initio calculations of excited-state properties within single-particle and two-particle approaches in comparison with corresponding experimental results. For the theoretical treatment of the electronic structure, we compute eigenvalues and eigenfunctions by using a spatially nonlocal exchange-correlation potential. From this starting point, quasiparticle energies within the fully frequency-dependent G0W0 approximation are obtained. By solving the Bethe-Salpeter equation, we evaluate optical properties, including the electron-hole attraction and the local-field effects. The results are compared with experimental spectra from soft X-ray emission, as well as from X-ray photoelectron spectroscopy or ellipsometry measurements. In more detail, we compute the valenceband densities of states, bound excitons, and the dielectric function. For the latter, we discuss both the absorption edge and higher critical points.

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