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Pd 촉매하에서 allylic alcohol과 hypervalent iodine 화합물의 위치 선택적 vinylation에 관한 연구
강석구,이홍우,장수범,김태현,편성재 성균관대학교 기초과학연구소 1995 論文集 Vol.46 No.2
The formation of carbon-carbon bond by palladium-catalyzed coupling of aryl or vinyl halides with olefins, known as the Heck reaction, has become a powerful tool in organic chemistry. In the case of allylic alcohols, palladium-catalyzed reaction of organic halides usually affords β-substituted ketones or aldehydes rether than β-substituted allylic alcohols.
Hypervalent Iodonium Salt와 Organofluorosilane 의 Cross-Coupling과 Carbonylative Cross-Coupling에 관한 연구
강석구,토쿠따로야마구치,김태현,편성재 성균관대학교 기초과학연구소 1996 論文集 Vol.47 No.1
The palladium-catalyzed cross-coupling and carbonylative cross-coupling of aryl-, alkenyl-, and alkynytfluorosilanes promoted by fluoride ion with hypervalent aryl-, alkenyliodonium tetrafluoroborates were achieved at room temperature under an atmospheric pressure of carbon monoxide.