비보강받침접합의 용접강도와 설계도표

최선규,유정한,이강민,박재우,Choi, Sun-Kyu,Yoo, Jung-Han,Lee, Kang-Min,Park, Jai-Woo 한국강구조학회 2012 韓國鋼構造學會 論文集 Vol.24 No.2

Unstiffened seated connections (USC) ensure easy installation and safety during erection, thereby making the process more economical. USCs consist of a seat angle for carrying the beam's reactions and a top angle to provide beam stability. These angles are bolted or welded to the beam and supporting member. This paper sought to propose a design table for the weld strength of such connections obtained from the elastic vector method (EVM) and the instantaneous center-of-rotation method (ICM) in terms of calculating the eccentricity. Also, the proposed design table is compared with both AISC and KBC specifications. 비보강받침접합(Unstiffened Seated Connection, USC)은 시공의 편의성과 설치시의 안정성 및 경제성이 있는 단순접합의 한 종류이다. 비보강받침접합은 하부ㄱ형강과 상부ㄱ형강으로 구성되며 하부ㄱ형강은 보의 단부반력전체를 지지하며, 상부ㄱ형강은 보의 안정을 위하여 설치한다. 상부와 하부ㄱ형강은 볼트 또는 용접에 의해 보와 지지부재에 접합된다. 본 연구에서는 비보강받침접합의 용접강도에 대한 실용적인 설계절차와 함께 용접부의 편심계산시 탄성벡터법(EVM)과 순간회전중심법(ICM)으로 소요지압길이에 근거한 설계도표를 제안하였다. 또한 제안한 설계방법에 의한 용접강도를 AISC와 KBC기준에 따라 비교하였다.

충청도(忠淸道) 동북부(東北部) 태창(泰昌)·보연(寶蓮), 금왕(金旺) 광산(鑛山)의 금은광화작용(金銀鑛化作用)

최선규,박노영,박성원,Choi, Seon Gyu,Park, No Young,Park, Sung Won 대한자원환경지질학회 1986 자원환경지질 Vol.19 No.no.spc

A number of auriferous veins occur in the Precambrian metamorphic terrain from Chungju to Mugeug district. These gold (-silver) deposits consist mainly of the fissure-filling quartz veins intruding the Precambrian gneiss or schist and Jurassic or Cretaceous granite. These gold (-silver) deposits can be 'divided into two mineralization epochs, (a) gold-rich veins related to Daebo igneous activity, and (b) gold-silver veins related to Bulgugsa igneous activity. These two groups of ore deposits with different generation can be characterized by the mode of occurrence of ore vein and the ore mineral associations. The auriferous quartz veins of Taechang and Boryeon mines associated with late Jurassic igneous activity are massive in character, and show the simple mineral assemblages and low Ag/Au ratio in the ores, representing a single mineralization system. The ore minerals are predominantly quartz containing minor or trace amonts of pyrrhotite, sphalerite, galena, pyrite, chalcopyrite and electrum. Electrum is closely associated with pyrrhotite and has chemical compositions from 61.4 to 78.5 atomic % Au. Fluid inclusion data suggest that ore minerals were deposited at temperatures between 238 and $390^{\circ}C$ from $CO_2$-rich fluids. The gold and/or silver-bearing quartz veins of Geumwang mine related to middle Cretaceous igneous activity are characterized by the multistage history, diverse mineral assemblages with high Ag/Au ratio in the ores. The ores of Geumwang mine have two contrasting mineral assemblages (1) pyrite+galena+sphalerite+arsenopyrite+electrum+argentite, representing the higher gold mineralization, and (2) pyrite+chalcopyrite+ galena +sphalerite+ arsenopyrite+silver sulfosalts+ electrum+ native silver+argentite, representing the higher silver mineralization. Electrum is closely associated with pyrite and has chemical compositions from 11.2 to 49.9 atomic % Au. The depositional environment during the higher gold mineralization can be estimated as the range of both temperature and sulfur fugacity, T= $200{\sim}300^{\circ}C$, log f ($S_2$) = $10^{-10}{\sim}10^{-15}$. The higher silver mineralization may be interpreted to have formed a range of falling temperature ($150{\sim}200^{\circ}C$) and low sulfur fugacity($10^{-10}{\sim}10^{-15}$). These temperature data are consistent with homogenization temperatures of fluId inclusions in quartz. Thus, the gold veins related to the Daebo igneous activity may be formed by the environment of higher temperature and pressure than the gold-silver veins associated with the Bulgugsa igneous activity.

충청북도(忠淸北道) 영동지역(永同地域) 금은광상(金銀鑛床)의 금은광화작용(金銀鑛化作用)에 관한 연구(硏究)

최선규,지세정,박성원,Choi, Seon Gyu,Chi, Se Jung,Park, Sung Won 대한자원환경지질학회 1988 자원환경지질 Vol.21 No.4

Most of the gold (-silver) vein deposits at Yeongdong District are mainly distributed in the precambrian metamorphic rocks. Based on the Ag/Au total production and ore grade ratios, the chemical composition of electrum and the associated sulfides, the gold(-silver) deposits at Yeongdong District may be classified into 4 classes: pyrrhotite - type gold deposits( I), pyrite - type gold deposits (IT A; massive vein), pyrite - type gold deposits (II B; nonmassive vein) and argentite - type gold - silver deposits(III). The chemical study on electrum(including native gold) revealed that Au content (2.8 to 92.4 atomic%) of electrums varies very widely for different classes of deposits. The Au content of electrum associated with pyrrhotite (Class I), ranging from 47.1 to 92.4 atomic% Au, is clearly higher than that associated with pyrite (Classes IIA, IIB and III). In contrast, classes I, II, and III deposits do not show clear differences in Au content of electrum. In general, pyrrhotite - type gold deposits(I) are characterized by features such as simply massive vein morphology, low values in the Ag/Au total production and ore grade ratios, the absence or rarity of silver - bearing minerals except electrum, and distinctively simple mineralogy. Although the geological and mineralogical features and vein morphology of pyrite - type gold deposits(IIA)are very similar to those of pyrrhotite - type gold deposits (I), Class II A deposits reveal significant differences in the associated iron sulfide (i. e. pyrite) with electrum and Au content of electrum. The Ag/Au total production and ore grade ratios from Class II A deposits are relatively slightly higher than those from Class I deposits. Pyrite - type gold deposits(II B) and argentite - type gold - silver deposits (III) have many common features; complex vein morphology, medium to high values in the Ag/Au total production and ore grade ratios and the associated iron sulfide (i. e. pyrite). In contrast to Class II B deposits, Class III deposits have significantly high Ag/Au total production and ore grade ratios. It indicates distinct difference in the abundance of silver minerals (i. e. native silver and argentite). The fluid inclusion analyses and mineralogical data of electrum tarnish method indicate that the gold mineralization of Classes I and II A deposits was deposited at temperatures between $230^{\circ}$ and $370^{\circ}C$, whereas the gold (-silver) mineralization of Classes ITB and ill formed from the temperature range of $150^{\circ}-290^{\circ}C$. Therefore, Classes I and IT A deposits have been formed at higher temperature condition and/or deeper positions than Classes IIB and III.

Compositional Variations of Arsenopyrite from Gold-Silver Deposits in Korea

최선규,최인식,Choi, Seon-Gyu,Choi, In-Sik The Korean Society of Economic and Environmental G 1998 자원환경지질 Vol.31 No.2

한국의 금은광화작용은 쥬라기 대보화성활동 (121~183 Ma) 및 백악기 불국사화성활동 (60~110 Ma)과 밀접한 연관성을 보이며, 이러한 열수광맥형 금은 광산에서 산출된 유비철석은 광물공생관계 또는 생성환경에 따라 현저한 조성 변화를 나타내고 있다. 쥬라기 금광단일형 광상에서 산출된 유비철석은 비교적 높은 As함량 (29.68~33.46 atomic %)으로 균질한 조성을 나타내며, 유비철석 지질온도계에 적용하면 생성온도 및 유황분압은 $370{\sim}450^{\circ}C$와 $10^{-8}{\sim}10^{-6}$이다. 또한 백악기 금은혼합형 광상과 은광단일형 광상의 유비철석을 쥬라기 광상에 비하여 상대적으로 심한 조성변화 (27.47~32.74 atomic %)를 보이며, $25{\sim}30^{\circ}C$ 및 $10^{-12}{\sim}10^{-10}$의 환경 조건하에서 정출된 것으로 추정된다. 한편, 금은광맥의 산출상태, 유비철석 지질온도계, 에렉트럼-섬아연석 지질온도계, 유체포유물 연구자료 및 화성암의 정체심도 등을 종합적으로 비교검토한 결과, 쥬라기 금광화작용 (Group IIA)은 심부조건 (약 4~5 kbar)에서 $300{\sim}500^{\circ}C$의 정출환경에서 진행되었지만, 백악기 금은광화작용 (Group III, IV, V)은 1 kbar 미만의 천부조건하에서 $170{\sim}370^{\circ}C$의 온도조건하에서 형성된 것으로 사료된다. The gold-silver mineralizations in Korea are closely related to Jurassic Daebo igneous activity (121 and 183 Ma) and Cretaceous Bulgugsa igneous activity (60 and 110 Ma). A compilation and re-evaluation of chemical data in arsenopyrite suggest that the As contents vary, reflecting different genetic environments or mineral assemblages. The gold-silver vein deposits from various mineralized area were investigated using arsenopyrite geothermometer. Arsenopyrites from the Jurassic Au-dominant deposits are distinct by high As contents (29.68~33.46 atomic %) with narrow variations, equivalent to a temperature range of $370{\sim}450^{\circ}C$ and a sulfur fugacity of about $10^{18}-10^{-6}$ atm. On the contrary, arsenopyrites from the Cretaceous Au-Ag and Ag-dominant deposits show a wider range in atomic % As composition of 27.47-32.74. They may have formed at temperatures of $250{\sim}350^{\circ}C$ and about $f_{S_2}=10^{-12}-10^{-10}$ atm. The data of arsenopyrite geothermometer, electrum-sphalerite geothermometer, fluid inclusions, vein morphology and emplacement depth of igneous rocks indicate that the gold mineralizations of Group IIA occurred at temperatures between 300 and $500^{\circ}C$ at depth of several tens km or more (about 4-5 kbar), and the gold-silver deposits of Groups III, IV and V were formed at a temperature range of about $170{\sim}370^{\circ}C$ under the shallow environment (<1 kbar).

Genetic Environments of Hydrothermal Vein Deposits in the Pacitan District, East Java, Indonesia

최선규,소칠섭,최상훈,한진균,Choi, Seon-Gyu,So, Chil-Sup,Choi, Sang-Hoon,Han, Jin-Kyun The Korean Society of Economic and Environmental G 1995 자원환경지질 Vol.28 No.2

인도네시아 빠찌딴 광화대 동-아연 광상은 금 또는 연 광화작용을 수반하여 동부자바 Southern Mountain zone내 제3기 퇴적암류와 화산암류의 열극을 충진한 열수 석영 백상광체로 까시한(Kasihan), 점퐁(Jompong), 금뽈(Gempol) 지역에 밀집 분포한다. 주 광화시기의 광석광물로는 황철석, 황동석, 섬아연석, 방연석 등이 각 지역별로 특징적인 광석광물들과 공생관계로 보이며 산출한다. 즉 까시한 지역의 경우 초기 공생광물군으로써 황철석 자류철석 철함유량이 높은(약 20 mole % FeS) 섬아연석과 Au 함량이 매우높은 (91.4 to 94.0 atomic % Au) 에렉트럼 및 (Cu-)Pb-Bi계 유염광물 등이 산출하며, 점퐁지역은 황철석, 유비철석(29.5~30.3 atomic % As), 섬아연석 등이 공생관계를 보여주며 산출된다. 반면, 금뽈지역의 경우 황철석, 자철석, 적철석 등의 초기 산출이 특징적이다. 광석광물의 침전은 0.8~10.1 wt. % NaCl 상당염농도를 갖는 광화유체로부터 약 $350^{\circ}C$에서 약 $200^{\circ}C$에 걸쳐 진행되었으며, 까시한 및 점퐁지역의 경우 초기 광화유체의 비등현상과 이에 수반된 냉각 회석 작용에 기인한 광액 진화에 의하여, 금뽈지역의 경우 천수의 유입에 의한 냉각 희석작용이 우세하게 진행된 광액 진화에 기인하여 야기되었다. 광화유체의 비등현상 및 유체포유물 연구결과에 근거한 빠찌딴 광화대 주 광화시기의 압력조건은 약 (${\geq}95{\sim}255$ bars로, 까시한($\approx$ 140~255 bar) $\rightarrow$ 점퐁 ($\approx$ 120~170 bar) $\approx$ 금뽈 (${\geq}95$ bar)의 순으로 광화대내 지역별 상대적인 광화심도 차이가 확인된다. 광물공생관계를 이용한 열역학적 연구결과, 온도감소에 따른 유황분압의 변화와 산소분압 조건이 각 지역별로 상이함은 광화대내 각 지역별 열수계에서 상기 광화심도에 관련한 천수의 역할(water/rock 비등)차이에 기인된 결과로 해석된다. 유체내 산소 및 수소안정동위원소 연구결과, 이들 동위원소 값이 광화작용의 진행과 함께 점차 감소함은 상대적으로 낮은 water/rock 비 값은 갖는 환경하에서 동위원소 교환반응을 이뤄 평형상태에 이른 광화초기 열수계내에 광화작용의 진행과 함께 산화상태의 차갑고 동위원소적 교환반응이 적게 이뤄진 천수의 혼입이 점증하였음을 지시하며, 각 지역별 동위원소비 값의 차이는 광화심도에 관련된 water/rock비 및 동위원소 교환반응차 등에 의한 결과로 사료된다. The hydrothermal vein type deposits which comprise the Kasihan, Jompong and Gempol mineralized areas are primarily copper and zinc deposits, but they are also associated with lead and/or gold mineralization. The deposits occur within the Tertiary sedimentary and volcanic rocks in the Southern Mountain zone of the eastern Java island, Indonesia. Mineralization can be separated into two or three distinct stages (pre-and/or post- ore mineralization stages and main ore mineralization stage) which took place mainly along pre-existing fault breccia zones. The main phase of mineralization (the main ore stage) can be usually classified into three substages (early, middle and late) according to ore mineral assemblages, paragenesis, textures and their chemical compositions. Ore mineralogy and paragenesis of the three areas in the district are different from each other. Pyrite, pyrrhotite (/arsenopyrite), iron-rich (up to 20.5 mole % FeS) sphalerite and (Cu-)Pb-Bi sulfosalts are characteristic of the deposits in the Kasihan (/Jompong) area. On the other hand, pyrite + hematite + magnetite + iron-poor (2.7 to 3.6 mole % FeS) sphalerite assemblage is restricted to the Gempol area. Fluid inclusion data suggest that fluids of the main ore stage evolved from initial high temperatures (near $350^{\circ}C$) to later lower temperatures (near $200^{\circ}C$) with salinities ranging from 0.8 to 10.1 equiv. wt. percent NaCl. Each area represents a separate hydrothermal system: the mineralization at Kasihan and Jompong were largely due to early fluid boiling coupled with later cooling and dilution, whereas the mineralization at Gempol was mainly resulted from cooling and dilution by an influx of cooler meteoric waters. Fluid inclusion evidence of boiling indicates that pressures of ${\geq}95$ to 255 bars (${\geq}95$ bars for the Gempol area: $\approx$ 120 to 170 bars for the Jompong area: $\approx$ 140 to 255 bars for the Kasihan area) during portions of main ore stage mineralization. Equilibrium thermodynamic interpretation indicates that the evolution trends of the temperature versus fS2 variation of ore stage fluids in the Pacitan district follow two fashions: ore fluids at Kasihan and Jompong changed from the pyrite-pyrrhotite sulfidation stage towards pyritehematite- magnetite state, whereas those at Gempol evolved nearly along pyrite-hematite-magnetite reaction curve with decreasing temperature. The sulfur isotope compositions of sulfide minerals are consistent with an igneous source of sulfur with a ${\delta}^{34}S_{{\Sigma}s}$ value of about 3.3 per mil. The oxygen and hydrogen isotopic compositions of the fluids in each area indicate a progressive shift from the dominance of highly exchanged meteoric water at early hydrothermal systems towards an un- or less-exchanged meteoric water at later hydrothermal systems.

Magnetite and Scheelite-Bearing Skarns in Ulsan Mine, Korea

최선규,이마이 나오야,Choi, Seon-Gyu,Imai, Naoya The Korean Society of Economic and Environmental G 1993 자원환경지질 Vol.26 No.1

경상분지 남동부에 위치한 울산광산은 석회암을 교대한 전형적인 calcareous skarn강상으로 Fe W광화작용 이외에도 Cu, Pb, Zn, As, Bi, Ni, Co, Cr, Ag, Sn, In, Te, Sb 등이 수반되는 다금속광화작용의 특성을 보여주고 있다. 본 광상은 직립에 가까운 파이프상 광체로 산출되며, 자철석과 함께 북측의 혼펠스와의 경계부근에 회중석이 부분적으로 광염되어 있다. 본 광상의 스카른대는 석회암 및 혼펠스를 교대한 괴상 스카른과 양자를 각기 절단하는 맥상스카른으로 구분된다. 괴상스카른은 석회암 기원의 스카른이 주체를 이루며, 이러한 스카른대는 규회석 스카른, 석류석 스카른, 단사휘석-석류석 스카른, 단사휘석 스카른으로 분류되며, 부분적으로 스카른대 주변부를 따라 거정질 방해석대가 존재하고 있다. 스카른 진화과정은 초기스카른 및 후기스카른의 두 시기로 분류되며, 초기스카른은 prograde한 스카른 생성시기로 초기에는 규회석, Mg-rich 단사휘석, Al-rich garnet가 주로 정출되며 광석광물은 거의 불모한 시기이나, 초기스카른의 말기로 진행됨에 따라 자철석과 회중석이 정출된다. 그리고, 후기스카른의 전반기까지는 Fe-rich 단사휘석, Fe-rich garnet와 함께 자철석 회중석이 연속적으로 정출되었으나, 후기스카른의 중기부터는 Ni, Co, As, Cu, Zn, Fe, Bi 등의 황화광물이 정출되는 다금속광화 작용의 특정을 보인다. 또한, 최후기 열수작용시기에는 섬아연석과 방연석 등의 Base-metal 황화광물이 주로 정출되는 연 아연 광화작용의 양상을 나타낸다. 이러한 각 광화시기별 스카른 광물과 광석광물의 변화양상은 고온의 열수용액이 천부로 유출되는 과정에서 광화용액의 온도가 급격히 떨어진 결과 (telescope)에 기인된 것으로 사료된다. The Ulsan Fe-W deposit, which can be classified as a calcareous skarn deposit, is represented by ore pipe consisting principally of magnetite and lesser amounts of scheelite with minor sulphides, sulphosaits, arsenides, sulpharsenides, etc. At Ulsan mine, metasomatic processes of skarn growth may be divided broadly into two stages based on the paragenetic sequence of calc-silicate minerals and their chemical composition; early and late skarn stages. Early stage has started with the formation of highly calcic assemblages of wollastonite, diopsidic clinopyroxene and nearly pure grossular, which are followed by the formation of clinopyroxenes with salite to ferrosalite composition and grandite garnets with intermediate composition. Based on these calc-silicate assemblages, the temperatures of early skarn formations have been in the ranges of $550^{\circ}$ to $450^{\circ}$. The calc-silicate assemblages formed during the earlier half period of late skarn stage show the enrichment of notable iron and slight manganese, and the depletion of magnesium; clinopyroxenes are hedenbergitic, and grandite garnets are andraditic. The formation temperatures during this skarn stage are inferred to have been in the range of $430^{\circ}$ to $470^{\circ}C$ at low $X_{CO_2}$ by data from fluid inclusions of late andraditic garnets. The later half period of late skarn stage is characterized by the hydrous alteration of pre-existing minerals and the formation of hydrous silicates. The main iron-tungsten mineralization representing prominent deposition of magnetite immediately followed by minor scheelite impregnation has taken place at the middle of early skarn stage, while complex polymetallic mineralization has proceeded during and after the late skarn stage. Various metals and semimetals of Fe, Ni, Co, Cu, Zn, As, Mo, Ag, In, Sn, Sb, Te, Pb and Bi have been in various states such as native metal, sulphides, arsenides, sulphosaits, sulpharsenides and tellurides.

RF 스퍼터링을 이용하여 저온에서 SiO₂/Si 기판 위에 증착된 La_0.7Sr_0.3MnO₃ 박막의 구조 및 전기적 특성

최선규,하태정,유병곤,박영호,Choi, Sun-Gyu,Reddy, A. Sivasankar,Ha, Tae-Jung,Yu, Byoung-Gon,Park, Hyung-Ho 한국세라믹학회 2007 한국세라믹학회지 Vol.44 No.11

The $La_{0.7}Sr_{0.3}MnO_3$ was deposited on $SiO_2/Si$ substrate by RF magnetron sputtering. The oxygen gas flow rate was changed from 0 to 80 sccm and the substrate temperature was $350^{\circ}C$. The oxygen gas flow rate was changed to control the growth orientation and crystalline state of the film. Relatively high TCR (temperature coefficient of resistance) value (-2.33%/K) was obtained when comparing with the reported values of the films prepared by using high substrate anneal temperature. The decrease in the sheet resistance and TCR value were observed when grain size of the film increased with the increase of oxygen gas flow rate.

Petrochemical Study of the Gadaeri Granite in Ulsan Area, Kyeongsang Province

최선규,위수민,Choi, Seon-Gyu,Wee, Soo-Meen The Korean Society of Economic and Environmental G 1994 자원환경지질 Vol.27 No.5

울산지역에 분포하는 가대리 화강암체는 울산 철 텅그스텐 광화작용의 관계화성암으로서 전형적인 미문상조직을 보여주며, 칼크-알칼리 계열과 I-type화강암류의 지화학적 특성을 나타내고 있다. 가대리화강암은 물이 포화된 상태에서 0.5~2.0 kbar의 압력조건하에서 생성된 것으로 이는 천부에서의 분별결정에 기인된 것으로 화학성분의 분화는 대부분 알칼리 장석의 분별결정작용으로 이루어졌다. 경상분지 최남단에 분포하며 철광화작용과 관련된 미문상화강암체인 마산-김해 화강암체와 가대리화강암제는 미량성분의 화학조성을 비교해볼때 전혀다른 모마그마에서 분화되었음올 시사해준다. The Gadaeri granite near Ulsan mine is an oval-shape isolated granitic body, and is genetically related to the iron-tungsten mineralization. The Gadaeri granite exhibits calc-alkaline and I-type characteristics, and generally shows the micrographic texture which indicates the shallow depth of emplacement. Consideration of the stratigraphic thickness of Ulsan formation and minimum-melt compositions suggests that the bulk magma crystallized at pressure of 0.5~2.0 kbar under water saturated condition. The evolutionary trend observed in the studied rocks represents that feldspar fractional crystallization has been a major magmatic process at the Gadaeri granite pluton. Different chemical characteristics between the Gadaeri and the Masan-Kimhae granites cannot be explained by fractional crystallization or different degrees of partial melting, and it reflects that the magma source for Gadaeri granite was different from that of the Masan and Kimhae granites.

강원도 옥계 금광상에 관한 광물학적·지화학적 연구

최선규,최상훈,이현구,Choi, Seon-Gyu,Choi, Sang-Hoon,Lee, Hyun Koo 대한자원환경지질학회 1997 자원환경지질 Vol.30 No.1

Gold mineralization of the Ogkye gold mine was deposited mainly in quartz veins up to 150 cm wide which occupy fissures in Cambrian Pungchon limestone. Ore minerals are relatively simple as follows: pyrite, arsenopyrite, pyrrhotite, sphalerite, electrum and galena. On the basis of the Ag/Au ratio on ore grades, mode of occurrence and assoicated mineral assemblages, the Ogkye gold deposit can be classified as pyrite-type gold deposit (Group IIB). Fluid inclusion data indicate that ore minerals were deposited between $400^{\circ}$and $230^{\circ}C$ from relatively dilute fluids (0.2 to 7.3 wt.% eq. NaCl) containing $CO_2$. The ore mineralization resulted from a complex history of $CO_2$ effervescence and local concomitant boiling coupled with cooling and dilution of ore fluids. Gold deposition was likely a result of decrease of sulfur activity caused by sulfide deposition and/or $H_2S$ loss accompanying fluid unmixing. Sulfur isotope compositions of sulfide minerals (${\delta}^{34}S=3.5{\sim}5.9$‰) are consistent with ${\delta}^{34}S_{H_2S}$ value of 4.8 to 6.1‰, suggesting mainly an igneous source of sulfur partially mixed with wall-rock sulfur.

Contrasting Styles of Gold and Silver Mineralization in the Central and Southeastern Korea

최선규,최상훈,Choi, Seon-Gyu,Choi, Sang-Hoon The Korean Society of Economic and Environmental G 1995 자원환경지질 Vol.28 No.6

한반도 중부지역과 동남부지역에 분포하는 금-은 광상들의 광화작용은 쥐라기 중기로부터 백악기 말기에 걸쳐서 진행되었으며, 이들 광상은 유행별로 산출지역 및 산출시기에 연관된 지질학적 지화학적 생성환경의 차이를 나타내고 있다. 중부지역 금-은 광상은 북동-남서의 방향성을 갖고 산출분포하는 중생대 화강암류 및 주변 선캠브리아기 변성암류내에 분포하지만, 동남부지역 금-은 광상은 백악기 퇴적암 및 화산암류내에 주로 배태되고 있다. 이는 한반도 대표적인 화성활동인 쥐라지 대보화성활동 및 백악기 불국사 화성활동과 각각 밀접한 성인적 연관성을 시사하고 있다. 이러한 각 광상들의 광화작용 특성(광물공생관계, 조직, 구조 등)과 연대측정결과 및 지질학적 분포특성은 쥐라가 중기로부터 백악기 말기에 이르기까지 광상형성과 연관된 열수유체의 성인적 차이를 의미하고 있다. 즉, 쥐라기로부터 초기 백악기에는 금광단일형 광상의 광화작용이 우세하게 진행되었으나, 후기 백악기에 이르면서 금-은혼합형광상 및 은광단일형 광상의 광화작용이 우세하게 야기되었음을 알 수 있다. 쥐라기 금광단일형 광상들은 괴상의 맥상 산출특성 및 단순한 광석 광불 공생관계를 보여주는 단성광맥으로 높은 fineness 값을 나타내지만, 백악기 금-은혼합형 광상과 은광단일형 광상은 다양하고 복잡한 구조 및 조치특성 갖는 복성 광맥내에 함은황인 및 황화광물과 함은tellurides 및 자연은 등을 포함하는 등 상대적으로 복잡한 광석광물 공생과계를 보여준다. 한편 황화광물의 지질온도계와 유체포유물 연구의 결과등에 의하면 백악기 금-은혼합형 광상과 은광단일형 광상은 천부(<0.5 kb)에서 천수가 우세한 광화유체로부터 $200^{\circ}{\sim}350^{\circ}C$ 온도조건하에서 주된 광화작용이 진행되었지만, 쥐라기 금광단일형 광상은 마그마기원의 열수용액으로부터 고온$(300^{\circ}{\sim}500^{\circ}C)$ 및 고압$({\approx}4-5kb)$의 생성환경하에서 광화작용이 진행되었음을 시사한다. Two distinct precious-metal mineralizations actively occur at central and southeastern Korea which display consistent relationships among geologic, geochemical and genetic environments. A large number of preciousmetal vein deposits in the central Korea occur in or near Mesozoic granite batholiths elongated in a NE-SW direction. Whereas, gold and/or silver deposits in the southeastern Korea occur within Cretaceous volcanic and sedimentary rocks. However, most of the precious-metal deposits in the southeastern Korea show characteristics of the silver-rich deposits than the gold-rich deposits in the central Korea. Two epochs of main igneous activities are recognized: a) Jurassic Daebo igneous activity between 121 and 183 Ma, and b) Cretaceous Bulgugsa igneous activity between 60 and 110 Ma. Precious-metal mineralization took place between 158 and 71 Ma, coinciding with portions of the two magmatic activities. Contrasts in the style of mineralization, together with radiometric age data and differences in geologic settings reflect the genetically variable natures of hydrothermal activities from middle Jurassic to late Cretaceous time. The compilation and re-evaluation of these data suggest that the genetic types of hydrothermal precious-metal vein deposits in the central and southeastern Korea varied with time. The Jurassic and early Cretaceous mineralizations are characterized by the Au-dominant type, but tend to change to the Au-Ag and/or Ag-dominant types at late Cretaceous. The Jurassic Au-dominant deposits commonly show several characteristics; prominent associations with pegmatites, simple massive vein morphologies, high fmeness values in ore-concentrating parts, and a distinctively simple ore mineralogy such as Fe-rich sphalerite, galena, chalcopyrite, Au-rich electrum, pyrrhotite and/or pyrite. The Cretaceous precious-metal deposits are generally characterized by some- features such as complex vein morphologies, low to medium fmeness values in the ore concentrates, and abundance of ore minerals including Ag sulfosalts, Ag sulfides, Ag tellurides and native silver. Mineralogical and fluid inclusion studies indicate that the Jurassic Au-dominant deposits in the central area were formed at the high temperature (about $300^{\circ}$ to $500^{\circ}C$) and pressure (about 4 to 5 kbars), whereas mineralizations of the Cretaceous Au-Ag and Ag-dominant deposits were occurred at the low temperature (about $200^{\circ}$ to $350^{\circ}C$) and pressure (<0.5 kbars) from the ore fluids containing more amounts of less-evolved meteoric waters.