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오존 처리에 의해 산소 작용기가 도입된 활성탄소의 세슘 흡착 특성
채은선 ( Eunseon Chae ),민충기 ( Chung Gi Min ),임채훈 ( Chaehun Lim ),이영석 ( Young-seak Lee ) 한국공업화학회 2024 공업화학 Vol.35 No.1
세슘은 높은 수용성으로 인하여 인체에 쉽게 침투하여 암 또는 DNA의 변형을 유발하는 잠재적인 독성 오염물질이다. 본 연구에서는 활성탄소의 세슘 흡착 능력을 향상시키고자 오존 처리를 통하여 활성탄소 표면에 산소 작용기를 도입하였다. 오존 처리 시간의 증가에 따라 활성탄소 표면의 산소함량이 증가하였다. 이후 활성탄소와 세슘 사이의 정전기적 상호작용이 더욱 원활하게 이루어져 모든 시료의 세슘 이온 흡착 효율이 향상되었다. 특히 반응기 내부 오존 농도를 50000 ppm으로 하여 7 min 동안 오존 처리한 시료는 약 12%의 높은 산소 작용기 함량을 보이며 97.6%의 가장 높은 세슘 제거 효율을 보였다. 한편, 5 min 동안 처리된 시료는 7 min간 반응한 시료와 비교하여 0.3%의 근소한 세슘 제거율 차이를 보였으며, 이는 오존 기체의 반응 특성으로 인한 두 시료의 표면화학적 유사성에 기인한다. 그러나, 오존 처리된 활성탄소의 세슘 흡착 성능은 활성탄소의 비표면적 및 기공 구조도 중요하지만 표면에 도입된 산소 작용기 양이 주된 영향을 미치는 것으로 판단된다. Cesium is a potential toxic contaminant due to its high solubility, which allows it to easily penetrate the human body and potentially induce cancer or DNA mutations. In this study, oxygen functional groups were introduced on activated carbons (ACs) by ozone treatment to enhance the cesium adsorption capacity. As the ozone treatment time increased, the oxygen content on the ACs surface increased. Subsequently, the electrostatic interaction between ACs and cesium enhanced, resulting in higher cesium ion adsorption efficiency across all samples. In particular, the sample treated with ozone for 7 minutes at an internal ozone concentration of 50000 ppm had roughly 12% greater oxygen functional group content and the highest cesium removal effectiveness (97.6%). Meanwhile, samples treated for 5 minutes showed a 0.3% cesium removal rate difference compared to those treated for 7 minutes, which was caused by the surface chemical similarity of the two samples due to the reactive characteristics of ozone gas. However, the cesium adsorption performance of ozonated activated carbon seems to be mainly influenced by the amount of oxygen functional groups introduced to the surface, although the specific surface area and pore structure of the activated carbon are also important.
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가을 무(Raphanus sativus L.)두 줄 재배를 위한 적정 재식거리
강은선 ( Eunseon Kang ),하선미 ( Sunmi Ha ),정승룡 ( Seoungryong Cheong ),서명훈 ( Myeongwhoon Seo ),박수형 ( Suhyoung Park ),곽용범 ( Yongbum Kwack ),최근진 ( Keunjin Choi ),채원병 ( Wonbyoung Chae ) 한국환경농학회 2015 한국환경농학회지 Vol.34 No.3
BACKGROUND: Radish (Raphanus sativus L.) is cultivated worldwide and one of important vegetables in Korea where year-round production of radish is possible. Most of radishes in autumn are cultivated with double-row spacing except for Gangwon-do where sing-row spacing is predominant. However, no research has been conducted on double-row spacing in radish cultivation so far. This study was conducted to reveal the optimum double-row spacing in autumn cultivation of radish. METHODS AND RESULTS: Using top two popular autumn radish cultivars ‘S’ and ‘C’, seeds were sown in spacing between rows of 55×25, 45×25, 35×25 and 25×25 cm, and that within rows of 35×28, 35×25, 35×22 and 35×19 cm. Plants were harvested 58 days after sowing and leaf weight, length and number, and root weight, length sugar content and pithiness were investigated. In the spacing between rows, no significant difference was observed in leaf weight, length and number in both cultivars; however, 25 cm of spacing between rowssignificantly reduced the root length and weight in ‘S’ and ‘C’ cultivars, respectively. In spacing within rows, 28, 25 and 22 cm did not affect fresh root weight in both cultivars, producing appropriate radish roots of 1,500g on average. However, 19 cm of spacing within rows did not reduced fresh root weight in ‘S’ cultivar but did significantly in ‘C’ cultivar (1148.3 g). Sugar contents and pithiness of roots were also affected by spacing but its effect was very small and different between cultivars. CONCLUSION: It is suggested that optimum double-row spacing in autumn radish cultivation is 35 cm and 22 cm of spacing between and within rows, respectively, the spacing that did not reduce the yield and quality of radish roots in two popular autumn radish cultivars.
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